Potassium chloroplatinate
- CAS No.
- 16921-30-5
- Chemical Name:
- Potassium chloroplatinate
- Synonyms
- POTASSIUM HEXACHLOROPLATINATE;POTASSIUM CHLOROPLATINATE (IV);POTASSIUM HEXACHLOROPLATINATE(IV);atinate;Potassium hexachL;HexachloroplatinuM;Potassium chloroplat;Potassium chlorplatinate;platinicpotassiumchloride;POTASSIUM CHLOROPLATINATE
- CBNumber:
- CB8752907
- Molecular Formula:
- Cl6KPt-
- Molecular Weight:
- 446.88
- MOL File:
- 16921-30-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/6 16:32:36
| Melting point | 250 °C (dec.)(lit.) |
|---|---|
| Density | 3.499 |
| vapor pressure | 0Pa at 20℃ |
| refractive index | ^=1.825 |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | 50g/l |
| form | Powder/Solid |
| Specific Gravity | 3.5 |
| color | Yellow-Orange |
| Water Solubility | 50 g/L (95 ºC) |
| Sensitive | Hygroscopic |
| Merck | 14,7636 |
| Solubility Product Constant (Ksp) | pKsp: 5.13 |
| Exposure limits |
ACGIH: TWA 0.002 mg/m3 NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 |
| Stability | Stable. Incompatible with acids, interhalogen compounds, strong oxidizing agents. |
| CAS DataBase Reference | 16921-30-5(CAS DataBase Reference) |
| EPA Substance Registry System | Platinate(2-), hexachloro-, dipotassium, (OC-6-11)- (16921-30-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H290-H301-H317-H318-H334-H372-H410 | |||||||||
| Precautionary statements | P234-P273-P280-P301+P310-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 25-41-42/43 | |||||||||
| Safety Statements | 22-26-36/37/39-45 | |||||||||
| RIDADR | UN 3290 6.1/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | TP1650000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2843 90 90 | |||||||||
| HazardClass | 6.1 | |||||||||
| Toxicity | LD50 orally in Rabbit: 195 mg/kg | |||||||||
| NFPA 704 |
|
Potassium chloroplatinate price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 520861 | Potassium hexachloroplatinate(IV) ≥99.9% trace metals basis | 16921-30-5 | 1G | ₹11988 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 520861 | Potassium hexachloroplatinate(IV) ≥99.9% trace metals basis | 16921-30-5 | 5G | ₹31956.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 379859 | Potassium hexachloroplatinate(IV) ≥99.99% trace metals basis | 16921-30-5 | 1G | ₹12676.2 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 206067 | Potassium hexachloroplatinate(IV) reagent grade, 98% | 16921-30-5 | 1G | ₹12831.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 379859 | Potassium hexachloroplatinate(IV) ≥99.99% trace metals basis | 16921-30-5 | 5G | ₹28760.1 | 2022-06-14 | Buy |
Potassium chloroplatinate Chemical Properties,Uses,Production
Chemical Properties
Potassium chloroplatinate, also known as potassium hexachloroplatinate(IV), is an inorganic compound with the formula K2PtCl6. It is an orange to yellow crystalline solid that is insoluble in water. Potassium hexachloroplatinate(IV) is used for the determination of potassium by gravimetric analysis. It is also used to prepare potassium tetrchloroplatinate by reduction using hydrazine dihydrochloride. Further, it is used in photography.
Uses
Potassium chloroplatinate is a red colored crystal that is soluble in water but less soluble in alcohol. Potassium chloroplatinate is produced by a complicated treatment of the reducing of platinum chloride with sulfurous gas and adding potassium chloride. It was used primarily in the platinum printing process, but also for toning silver prints.
Preparation
It is formed by reaction of soluble potassium salt solution and chloroplatinic acid.
General Description
Potassium hexachloroplatinate (K2PtCl6) is a source material for the preparation of platinum based compounds. It can be used in the preparation of platinum colloids by its reduction in an aqueous solution.
Hazard
Toxic by ingestion and inhalation.
Safety Profile
Mutation data reported. Human systemic effects by intradermal route: dermatitis. When heated to decomposition it emits toxic fumes of K2O and Cl-. Used as a catalyst for carbonylation of alkynes. See also PLATINUM COMPOUNDS.
Purification Methods
It crystallises from water (20mL/g) between 100o and 0o. Its solubility in H2O is 0.7% at 0o, 1.12% at 20o, 2.16% at 50o and 5.13% at 100o. [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1571 1965.]
Potassium chloroplatinate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Vineeth Precious Catalysts Pvt Ltd | +91-9049600004 +91-9049600004 | Mumbai, India | 29 | 58 | Inquiry |
| Dhara Industries | +91-9322395199 +91-9322395199 | Mumbai, India | 190 | 58 | Inquiry |
| Metal Chem India | +91-8999856889 +91-9011882000 | Maharashtra, India | 46 | 58 | Inquiry |
| Modicon Private Limited | +91-2222825465 +91-2222825464 | Maharashtra, India | 18 | 58 | Inquiry |
| Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
| Scientific OEM | +91-22- 2343 7546 / 2341 3094 | New Delhi, India | 1996 | 38 | Inquiry |
| ALPHA CHEMIKA | +91-22-22061123 +91-22-66382501 | Mumbai, India | 1681 | 43 | Inquiry |
| Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4317 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| JSK Chemicals | 58 |
| Vineeth Precious Catalysts Pvt Ltd | 58 |
| Dhara Industries | 58 |
| Metal Chem India | 58 |
| Modicon Private Limited | 58 |
| Evans Fine Chem | 58 |
| Scientific OEM | 38 |
| ALPHA CHEMIKA | 43 |
| Sisco Research Laboratories Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
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