Vinylene carbonate
- CAS No.
- 872-36-6
- Chemical Name:
- Vinylene carbonate
- Synonyms
- 1,3-DIOXOL-2-ONE;vinyl carbonate;Vinylene carbote;The ethylene carbonate;Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT;1,3-Dioxo-2-one;WITH HYDROQUINONE;Vinylene carbonat;VINYLENE CARBONATE;2H-1,3-dioxol-2-one
- CBNumber:
- CB9119200
- Molecular Formula:
- C3H2O3
- Molecular Weight:
- 86.05
- MOL File:
- 872-36-6.mol
- Modify Date:
- 2024/7/24 13:33:21
| Melting point | 19-22 °C(lit.) |
|---|---|
| Boiling point | 162 °C(lit.) |
| Density | 1.360 g/mL at 20 °C |
| vapor pressure | 3.35hPa at 25℃ |
| refractive index |
n |
| Flash point | 163 °F |
| storage temp. | 2-8°C |
| solubility | 11.5 g/100 mL |
| form | Liquid |
| color | Colorless to pale yellow |
| Specific Gravity | 1.355 |
| Water Solubility | 11.5 g/100 mL |
| Sensitive | Moisture Sensitive |
| BRN | 105683 |
| InChIKey | VAYTZRYEBVHVLE-UHFFFAOYSA-N |
| LogP | -0.36 at 20℃ |
| CAS DataBase Reference | 872-36-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 1,3-Dioxol-2-one(872-36-6) |
| EPA Substance Registry System | 1,3-Dioxol-2-one (872-36-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H311-H315-H317-H318-H373-H411 | |||||||||
| Precautionary statements | P273-P280-P301+P312+P330-P302+P352+P312-P305+P351+P338+P310-P314 | |||||||||
| Hazard Codes | Xi,N,T | |||||||||
| Risk Statements | 43-36-51/53-48/22-41-38-24-22 | |||||||||
| Safety Statements | 37/39-26-24-61-45-36/37/39 | |||||||||
| RIDADR | UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | FG3325000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29209090 | |||||||||
| NFPA 704 |
|
Vinylene carbonate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | V2607 | Vinylene carbonate contains ≤2% BHT as stabilizer, 97% | 872-36-6 | 5G | ₹13260.63 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | V2607 | Vinylene carbonate contains ≤2% BHT as stabilizer, 97% | 872-36-6 | 25G | ₹32821.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 901595 | Vinylene carbonate solution 1.0?M in ethyl acetate | 872-36-6 | 25ML | ₹18436.05 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 901595 | Vinylene carbonate solution 1.0?M in ethyl acetate | 872-36-6 | 100ML | ₹38851.65 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 809977 | Vinylene carbonate 99.5%, acid <200 ppm, H2O <100 ppm | 872-36-6 | 25G | ₹43646.4 | 2022-06-14 | Buy |
Vinylene carbonate Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.
Application
Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.
Preparation
Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).
General Description
This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.
Purification Methods
Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]
Vinylene carbonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| EAST STAR BIOTECH (SUZHOU) CO., LTD. | +8617706846989 | China | 48 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21669 | 55 | Inquiry |
| changzhou huayang technology co., ltd | +8615250961469 | China | 9827 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | China | 12456 | 58 | Inquiry |
| Dorne Chemical Technology co. LTD | +86-86-13583358881 +8618560316533 | China | 3146 | 58 | Inquiry |
| Hebei Guanlang Biotechnology Co,.LTD | +86-19930503253; +8619930503252 | China | 5832 | 58 | Inquiry |
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | China | 10978 | 58 | Inquiry |
Related articles
- The application of vinylene carbonate in Li-ion batteries
- The vinylene carbonate (VC) is a cyclic, reactive, unsaturated carbonate ester.
- Aug 26，2022
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