Ethyl 2-chloropropionate
- CAS No.
- 535-13-7
- Chemical Name:
- Ethyl 2-chloropropionate
- Synonyms
- Ethyl 2-chloropropanoate;NSC-522671;oropropionate;2-Chloropropio;UNII:LXW30UR82C;Ethyl 2-chloropropio;3-Nitrosalicyclic Acid;ethyl2-chloropropanoate;ETHYL 2-CHLOROPROPIONATE;Ethyl a-Chloropropionate
- CBNumber:
- CB9130182
- Molecular Formula:
- C5H9ClO2
- Molecular Weight:
- 136.58
- MOL File:
- 535-13-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/21 22:41:43
| Boiling point | 146-149 °C (lit.) |
|---|---|
| Density | 1.072 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 101 °F |
| storage temp. | Flammables area |
| solubility | alcohol: miscible |
| form | clear liquid |
| color | Colorless to Light yellow |
| Specific Gravity | 1.085 (20/4℃) |
| Water Solubility | immiscible |
| Merck | 14,3785 |
| BRN | 773906 |
| Dielectric constant | 10.1 |
| LogP | 1.382 (est) |
| CAS DataBase Reference | 535-13-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Ethyl 2-chloropropionate(535-13-7) |
| EPA Substance Registry System | Ethyl-2-chloropropionate (535-13-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 10-36/37/38 | |||||||||
| Safety Statements | 26-36-37/39-16 | |||||||||
| RIDADR | UN 2935 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29159000 | |||||||||
| NFPA 704 |
|
Ethyl 2-chloropropionate price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 192414 | Ethyl 2-chloropropionate 97% | 535-13-7 | 25ML | ₹1948.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 192414 | Ethyl 2-chloropropionate 97% | 535-13-7 | 1L | ₹15533.88 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C0790 | Ethyl 2-Chloropropionate min. 97.0 % | 535-13-7 | 25ML | ₹3800 | 2022-05-26 | Buy |
| TCI Chemicals (India) | C0790 | Ethyl 2-Chloropropionate min. 97.0 % | 535-13-7 | 100ML | ₹11700 | 2022-05-26 | Buy |
| ottokemi | E 1435 | Ethyl-2-chloro propionate 95% | 535-13-7 | 100mL | ₹8604 | 2022-05-26 | Buy |
Ethyl 2-chloropropionate Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Ethyl 2-chloropropionate was used as initiator during the synthesis of poly(2-(diethylamino)ethyl methacrylate) and poly(N-isopropylacrylamide) via atom transfer radical polymerization. It was also used in the synthesis of end-functionalized poly(N-isopropylacrylamide) with pyrenyl group.
General Description
A clear colorless liquid with a pungent odor. Flash point of 100°F. Denser than water and insoluble in water. Vapors are heavier than air.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Ethyl 2-chloropropionate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health Hazard
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Potential Exposure
This material is used in organic synthesis.
Shipping
UN2935 Ethyl 2-chloropropionate, Hazard Class: 3; Labels: 3-Flammable liquid.
Incompatibilities
Flammable liquid; forms explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and reducing agents. Esters are generally incompatible with nitrates. Moisture may cause hydrolysis or other forms of decomposition. Esters react with acids releasing heat in addition to alcohols and acids. Contact with caustic solutions generate heat. Contact with esters with alkali metals and hydrides releases flammable hydrogen.
Ethyl 2-chloropropionate Preparation Products And Raw materials
Raw materials
Preparation Products
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