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Phosphonitrilic chloride trimer

Phosphonitrilic chloride trimer Structure
CAS No.
940-71-6
Chemical Name:
Phosphonitrilic chloride trimer
Synonyms
HEXACHLOROCYCLOTRIPHOSPHAZENE;PNC;PPZ;Hexachlorocyclophosphazene;N3P3Cl6;Hexachlorophosphazene;2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine;HCCTP;Phosphor;hexachlorotriphosphazene
CBNumber:
CB9200546
Molecular Formula:
Cl6N3P3
Molecular Weight:
347.66
MOL File:
940-71-6.mol
MSDS File:
SDS
Modify Date:
2024/5/22 11:23:49

Phosphonitrilic chloride trimer Properties

Melting point 112-115 °C(lit.)
Boiling point 127 °C (13 mmHg)
Density 1.98 g/mL at 25 °C(lit.)
Water Solubility Insoluble in water
solubility reacts with H2O
form crystal
pka -12.98±0.10(Predicted)
Specific Gravity 1.98
color white
Sensitive Moisture Sensitive
CAS DataBase Reference 940-71-6(CAS DataBase Reference)
NIST Chemistry Reference 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro-(940-71-6)
EPA Substance Registry System 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro- (940-71-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  14-34-20/21/22
Safety Statements  26-36/37/39-45-7/8-41
RIDADR  UN 3260 8/PG 2
WGK Germany  3
21
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28530090
NFPA 704
0
3 0
W

Phosphonitrilic chloride trimer price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 481947 Phosphonitrilic chloride trimer 99.95% trace metals basis 940-71-6 5G ₹3951.13 2022-06-14 Buy
Sigma-Aldrich(India) 481947 Phosphonitrilic chloride trimer 99.95% trace metals basis 940-71-6 25G ₹13650.33 2022-06-14 Buy
Sigma-Aldrich 230286 Phosphonitrilic chloride trimer 99% 940-71-6 25G ₹6408.4 2022-06-14 Buy
Sigma-Aldrich(India) 230286 Phosphonitrilic chloride trimer 99% 940-71-6 25G ₹6408.4 2022-06-14 Buy
Sigma-Aldrich 230286 Phosphonitrilic chloride trimer 99% 940-71-6 100G ₹12838.45 2022-06-14 Buy
Product number Packaging Price Buy
481947 5G ₹3951.13 Buy
481947 25G ₹13650.33 Buy
230286 25G ₹6408.4 Buy
230286 25G ₹6408.4 Buy
230286 100G ₹12838.45 Buy

Phosphonitrilic chloride trimer Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

Reagent for the synthesis of ″dandelion″ (spherical) dendrimers. Ring-opening polymerization, ligand and/or ligand precursor for transition metals, and the study of P-Cl bond substitution reactions are among the interesting uses for this product.

Preparation

Hexachlorocyclotriphosphazene (PNCl2)3 (mp114 ℃, bp 256℃), which is produced on an industrial scale as the starting material for the manufacture of organosubstituted polyphosphazenes. It forms an almost planar six-membered ring with equal P?N bond lengths.

Purification Methods

Purify it by zone melting, by crystallisation from pet.ether, n-hexane or *benzene, and by sublimation. [van der Huizen et al. J Chem Soc, Dalton Trans 1311 1986, Meirovitch et al. J Phys Chem 88 1522 1984, Alcock et al. J Am Chem Soc 106 5561 1984; Winter & van de Grampel J Chem Soc, Dalton Trans 1269 1986.] Phosphoric acid [7664 -38 -2] M 98.0, m 42.3o, pK 1 2.15, pK 2 7.21, pK 3 12.37. Pyrophosphate can be removed from phosphoric acid by diluting with distilled H2O and refluxing overnight. By cooling to 11o and seeding with crystals obtained by cooling a few millilitres in a Dry-ice/acetone bath, 85% orthophosphoric acid crystallises as H3PO4.H2O. The crystals are collected on a sintered glass filter. [Weber & King Inorg Synth I 101 1939.]

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AKOS BBS-00002918 1,3,5-TRIAZA-2,4,6-TRIPHOSPHORIN-2,2,4,4,6,6-HEXACHLORIDE 1,3,5,2,4,6-TRIAZATRIPHOSPHORINE-2,2,4,4,6,6-HEXACHLORIDE 1,3,5,2,4,6-TRIAZATRIPHOSPHORINE,2,2,4,4,6,6-HEXACHLORO-2,2,4,4,6,6-HEXAHYDRO- 2,2,4,4,6,6-HEXACHLORO-1,3,5,2LAMBDA5,4LAMBDA5,6LAMBDA5-TRIAZATRIPHOSPHININE AURORA KA-1096 CYCLIC PHOSPHONITRILIC CHLORIDE TRIMER CYCLOPHOSPHAZENE DICHLORIDE TRIMER Hexchlorophosphazene PHOSPHONITRILIC CHLORIDE, TRIMER, 99.99+ %, RESUBLIMED 1,3,5-Triaza-2,4,6-triphosphorine-2,2,4,4,6,6-hexachloride Phosphonitrilicchloridetrimer,98% Phosphonitrilicchloridetrimer,98.5% PHOSPHONITRILIC CHLORIDE TRIMER PNC Hexachlorcyclotriphosphazen [N3P3Cl6] Hexachloro hexachlorocyclotriphosphazene PHOSPHONITRILE CHLORIDE TRIMER 80% PHOSPHONITRILE CHLORIDE TRIMER 99.5% 2,2,4,4,6,6-Hexahydro-2,2,4,4,6,6-hexachloro-1,3,5,2,4,6-triazatriphosphorine Hexachlorcyclotriphosphazen 1,3,5,2,4,6-Triazatriphosphorine-2,2,4,4,6,6-hexachloride, 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride, Hexachlorocyclotriphosphazene PHOSPHORUS NITRILE DICHLORIDE TRIMER PHOSPHONITRILIC CHLORIDE TRIMER OTAVA-BB BB7110952524 Phosphonitrilic chloride trimer,1,3,5,2,4,6-Triazatriphosphorine-2,2,4,4,6,6-hexachloride, 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride, Hexachlorocyclotriphosphazene osphonitrile chloride triMer Phosphonitrilic chloride trimer, 2,2,4,4,6,6-Hexachloro-1,3,5-triazatriphosphinine Phosphonitrilic chloride triMer, 98% 5GR Hexachlorocyclotriphosphazene Cyclic Phosphonitrilic Chloride Trimer Phosphonitrilic chloride triMer 99% Phosphonitrilic chloride trimer 99.95% trace metals basis 1,3,5,2,4,6-Triazatriphosphorine-2,2,4,4,6,6-hexachloride 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride Hexachlorocyclotriphosphazene Cyclic Phosphonitrilic Chloride Trimer Hexachlorotriphosphazene 1,3,5,2,4,6-Triazatriphosphorine, hexachloro- 2,2,4,4,6,6-Hexachloro-2,2,4,4,6,6-hexahydro-1,3,5,2,4,6-triazatriphosphorine 2,2,4,4,6,6-Hexachloro-2λ5,4λ5,6λ5-cyclotriphosphaza-1,3,5-triene 2,2,4,4,6,6-Hexachlorocyclotriphosphazatriene Cyclophosphonitrilic chloride trimer Hexachloro Hexachlorocyclophosphazatriene Hexachlorocyclotriphosphazatriene Hexachlorotriphosphonitrile phosohonitrilicchloridetrimer Phosphonitrile chloride, cyclic trimer Phosphonitrilic chloride cyclic trimer Phosphononitrilic chloride trimer Triphosphonitrile chloride Triphosphonitrilic chloride Hexachlorocyclo triphosphonitrile liulvhjansanlinjin hexachloro-1,3,5,2$l^{5},4$l^{5},6$l^{5}-triazatriphosphinine Hexachlorocyclotriphosphazene 99% Phosphonitrilic Chloride Trimer > 2λ5,4λ5,6λ5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro- Phosphonitrilic chloride trimer,0.98 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2 PPZ hexachlorotriphosphazene HEXACHLOROCYCLOTRIPHOSPHAZENE