DIISOPROPYLCHLOROSILANE
- CAS No.
- 2227-29-4
- Chemical Name:
- DIISOPROPYLCHLOROSILANE
- Synonyms
- CHLORODIISOPROPYLSILANE;Diisopropylsilyl chloride;DK677;DK220;DIISOPROPYLCHLOROSILANE;Chlorodiisopropylsilane >chlorobis(propan-2-yl)silane;chloro-di(propan-2-yl)silicon;Silane, chlorobis(1-methylethyl)-;chloro(2,3-dimethylbutan-2-yl)silicon
- CBNumber:
- CB9249415
- Molecular Formula:
- C6H15ClSi
- Molecular Weight:
- 150.72
- MOL File:
- 2227-29-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/8 17:06:38
| Boiling point | 58-60 °C50 mm Hg(lit.) |
|---|---|
| Density | 0.883 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 72 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | generally sol organic solvents; reacts with alcohols, ammonia,and water. |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.883 |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 2231355 |
| CAS DataBase Reference | 2227-29-4(CAS DataBase Reference) |
| EPA Substance Registry System | Silane, chlorobis(1-methylethyl)- (2227-29-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H314 | |||||||||
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 10-34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2986 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
DIISOPROPYLCHLOROSILANE price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 375896 | Chlorodiisopropylsilane 97% | 2227-29-4 | 5G | ₹7425.95 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 375896 | Chlorodiisopropylsilane 97% | 2227-29-4 | 5G | ₹7425.95 | 2022-06-14 | Buy |
| Sigma-Aldrich | 375896 | Chlorodiisopropylsilane 97% | 2227-29-4 | 25G | ₹28740.38 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 375896 | Chlorodiisopropylsilane 97% | 2227-29-4 | 25G | ₹28740.38 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C1492 | Chlorodiisopropylsilane min. 95.0 % | 2227-29-4 | 5ML | ₹7200 | 2022-05-26 | Buy |
DIISOPROPYLCHLOROSILANE Chemical Properties,Uses,Production
Physical properties
bp 150–153°C,bp 54–55°C/45 mmHg; d 0.872 gmL?1
Uses
Intramolecular
hydrosilylation is also possible within β-diisopropylsilyloxy
esters (13), constituting an exceptionally mild method for reducing
ester groups to the aldehyde oxidation level (eq 4).The derivatives
(13) may be synthesized from β-hydroxy esters (12) as described
above for the analogous ketones. Treatment with fluoride
ions (but not Lewis acids) induces hydride transfer to give
alkoxysiladioxanes (14) in excellent yields (≥95%). Although
usually performed in dichloromethane, the hydrosilylation may
also be accomplished with ethyl acetate as solvent, providing
strong evidence for intramolecularity.
Preparation
obtained by reaction of trichlorosilane with isopropylmagnesium chloride;the original yield of 45% may be raised to 70–80% by employing conc hydrochloric acid to quench the reaction.
Purification Methods
Impurities can be readily detected by 1H NMR. Purify it by fractional distillation [Gilman & Clark J Am Chem Soc 69 1499 1947, Allen et al. J Chem Soc 3668 1957].
DIISOPROPYLCHLOROSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 126)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16209 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21675 | 55 | Inquiry |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9338 | 55 | Inquiry |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 32760 | 60 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29826 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| WinWin Chemical CO., Limited | +86-0577-64498589 +8615325081899 | China | 14198 | 58 | Inquiry |
2227-29-4(DIISOPROPYLCHLOROSILANE)Related Search:
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Dichloromethane
N-OCTYLDIISOPROPYLCHLOROSILANE
DI-TERT-BUTYLDICHLOROSILANE
1,3-DICHLORO-1,1,3,3-TETRAISOPROPYLDISILOXANE
DIISOPROPYLCHLOROSILANE
Triisopropylsilyl chloride
1,1,3,3-TETRACYCLOPENTYLDICHLORODISILOXANE
DI-TERT-BUTYLCHLOROSILANE
3-CYANOPROPYLDIISOPROPYLCHLOROSILANE
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Silane, chlorobis(1-methylethyl)-
DIISOPROPYLCHLOROSILANE
chloro(2,3-dimethylbutan-2-yl)silicon
chloro-di(propan-2-yl)silicon
Chlorodiisopropylsilane >
chlorobis(propan-2-yl)silane
C6H15ClSi DIISOPROPYLCHLOROSILANE 2227-29-4
CHLORODIISOPROPYLSILANE
Diisopropylsilyl chloride
DK220
DK677
2227-29-4
CH32CH2SiHCl
Silicon-Based
Synthetic Reagents
Protection and Derivatization
Protecting and Derivatizing Reagents
Monochlorosilanes
Reduction
Si-H Compounds
Si (Classes of Silicon Compounds)
Silicon Compounds (for Synthesis)
Si-Cl Compounds
Pharmaceutical Intermediates
Monochlorosilanes
Reduction
Si (Classes of Silicon Compounds)
Si-Cl Compounds
Si-H Compounds
Silicon Compounds (for Synthesis)
Synthetic Organic Chemistry