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Diethyl ethoxymethylenemalonate

Diethyl ethoxymethylenemalonate

CAS:
87-13-8
MF:
C10H16O5
MW:
216.23

Properties

Melting point:
-33°C
Boiling point:
279-283 °C(lit.)
Density 
1.080 g/mL at 20 °C(lit.)
vapor pressure 
<0.1 hPa
refractive index 
n20/D 1.463
Flash point:
311 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Liquid
color 
Clear colorless to light yellow
Water Solubility 
insoluble
BRN 
880058
InChIKey
LTMHNWPUDSTBKD-UHFFFAOYSA-N
LogP
1.5-2.1 at pH7

Safety Information

Symbol(GHS) 

GHS07,GHS09
Signal word 
Warning
Hazard statements 
H302-H315-H317-H319-H410
Precautionary statements 
P261-P273-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes 
Xn
Risk Statements 
22-36/37/38-42/43
Safety Statements 
26-36/37/39-27-24/25
WGK Germany 
1
RTECS 
OO1100000
Autoignition Temperature
215 °C
TSCA 
Yes
HS Code 
29189090
Toxicity
LD50 orally in Rabbit: 925 mg/kg LD50 dermal Rat > 2000 mg/kg

Use

Likely impurity is diethyl diethoxymethylene malonate which is difficult to separate from diethyl ethoxymethylene malonate by distillation, and it is necessary to follow the course of the distillation by the change in refractive index instead of boiling point. After a low boiling fraction is collected, there is obtained an intermediate fraction (n 20 1.414—1.458), the size of which depends on the amount of the diethoxymethylene compound. This fraction is fractionated through a 5inch Vigreux column (p 11) at low pressure avoiding interruption in heating. Fraction b 108-110o/0.25mm is ca 10o lower than the submitters' fraction (b 97.2o/0.25mm, n D 1.4612—1.4623) [Org Synth Coll Vol III 395 1955, Fuson et al. J Org Chem 11 197 1946, Duff & Kendal J Chem Soc 893 1948]. [Beilstein 3 IV 1192.]

43 India supplier list of "Diethyl ethoxymethylenemalonate "

  • Product Name:Diethyl ethoxymethylenemalonate
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:Diethyl Ethoxymethylenemalonate
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Hyderabad,INDIA
  • Product Name:Diethyl ethoxy methylen emalonate (DEME)
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Hyderabad,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Telangana,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate, 98%
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Gujarat,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Hyderabad,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Telangana,INDIA
  • Product Name:Diethylethoxymethylenemalonate
  • Products Intro:Brand:sigma aldrich | Product Number:D94208 | Purity:99%
  • Company Type: Trader
  • Country/Region: Bangalore,INDIA
  • Product Name:Diethyl ethoxymethylenemalonate 98%
  • Products Intro:Brand:Glrinnovations | OriginalID:GLR19.156754
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA

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