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Bromochloromethane

Bromochloromethane

CAS:
74-97-5
MF:
CH2BrCl
MW:
129.38

Properties

Melting point:
−88 °C(lit.)
Boiling point:
68 °C(lit.)
Density 
1.991 g/mL at 25 °C(lit.)
vapor density 
4.5 (vs air)
vapor pressure 
117 mm Hg ( 20 °C)
refractive index 
n20/D 1.482(lit.)
Flash point:
11 °C
storage temp. 
2-8°C
solubility 
Soluble in acetone, alcohol, benzene, ether (Weast, 1986), and many other solvents, particularly chlorinated hydrocarbons.
Specific Gravity
1.991
Water Solubility 
9 g/L (20 ºC)
BRN 
1730801
Henry's Law Constant
(x 10-3 atm?m3/mol): 1.44 at 25 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits
NIOSH REL: TWA 200 ppm (1,050 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 200 ppm; ACGIH TLV: TWA 200 ppm (adopted)
Dielectric constant
7.8(Ambient)
Stability:
Stable, but may discolour in light. Incompatible with aluminium, magnesium, zinc, calcium, strong oxidizing agents.
LogP
1.410

Safety Information

Symbol(GHS) 

GHS05,GHS07
Signal word 
Danger
Hazard statements 
H315-H318-H332-H335-H420
Precautionary statements 
P261-P280-P305+P351+P338
Hazard Codes 
Xi,N,Xn,T,F
Risk Statements 
37/38-41-59-36/37/38-20-39/23/24/25-23/24/25-11-36/38
Safety Statements 
26-39-59-37/39-45-36/37-16-7
RIDADR 
UN 1887 6.1/PG 3
OEB
A
OEL
TWA: 200 ppm (1050 mg/m3)
WGK Germany 
2
RTECS 
PA5250000
Hazard Note 
Irritant
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29034980
Toxicity
LC50 (inhalation) for mice 15,850 mg/m3/8-h, rats 28,800 ppm/15-min (quoted, RTECS, 1985). Acute oral LD50 for rats 5,000 mg/kg, mice 4,300 mg/kg (quoted, RTECS, 1985).
IDLA
2,000 ppm

Use

UN1887 Bromochloromethane, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

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