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Lithium borohydride
Lithium borohydride
- CAS:
- 16949-15-8
- MF:
- BH4Li
- MW:
- 21.78
Properties
- Melting point:
- 280 °C
- Boiling point:
- 66°C/760mmHg
- Density
- 0.896 g/mL at 25 °C
- Flash point:
- −1 °F
- storage temp.
- water-free area
- solubility
- Soluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol.
- form
- Powder
- color
- White
- Specific Gravity
- 0.66
- explosive limit
- 4.00-75.60%(V)
- Water Solubility
- soluble H2O above pH 7, ether, tetrahydrofuran, aliphatic amines [MER06]
- Sensitive
- Air & Moisture Sensitive
- Merck
- 14,5525
Safety Information
- Symbol(GHS)
GHS02,GHS05,GHS06
- Signal word
- Danger
- Hazard statements
- H260-H301-H314
- Precautionary statements
- P231+P232-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
- Hazard Codes
- F,T,C,Xn,F+
- Risk Statements
- 14/15-23/24/25-34-20/21/22-11-40-36/37/38-19-67-66-22-12
- Safety Statements
- 26-36/37/39-43-45-36/37-16
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 2
- RTECS
- ED2725000
- F
- 10-21
- TSCA
- Yes
- HS Code
- 2850 00 20
- HazardClass
- 4.3
- PackingGroup
- I
Use
Lithium borohydride is a strong reducing agent. Is easily ignited and burns vigorously once ignited. Reacts on contact with water or acids to form hydrogen gas and corrosive products. Reaction with limited amounts of water or moisture may cause ignition after a delay [Gaylord, 1965, p. 22].
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