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Benzyl chloroformate

Benzyl chloroformate

CAS:
501-53-1
MF:
C8H7ClO2
MW:
170.59

Properties

Melting point:
-20 °C
Boiling point:
103 °C20 mm Hg(lit.)
Density 
1.212 g/mL at 20 °C
vapor density 
1 (vs air)
vapor pressure 
1.39 psi ( 20 °C)
refractive index 
n20/D 1.519(lit.)
Flash point:
197 °F
storage temp. 
Store at +2°C to +8°C.
solubility 
Miscible with ether, acetone and benzene.
form 
Solution
color 
slightly yellow to slightly pink
Odor
Irritating; sharp, penetrating.
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Merck 
14,1801
Exposure limits
ACGIH: TWA 1 ppm
OSHA: TWA 1 ppm(5 mg/m3)
NIOSH: IDLH 10 ppm; Ceiling 1 ppm(5 mg/m3)
Stability:
Stable. Incompatible with water, oxidizing agents. Combustible.

Safety Information

Symbol(GHS) 

GHS05,GHS07,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H314-H335-H350-H410
Precautionary statements 
P201-P261-P273-P280-P305+P351+P338-P310
Hazard Codes 
T,C,N,F
Risk Statements 
45-20-34-48/22-50/53-67-65-63-48/20-11-43-37-23
Safety Statements 
53-26-36/37/39-45-60-61-62-46-36/37
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
RTECS 
LQ5860000
19
Autoignition Temperature
590 °C
TSCA 
Yes
HS Code 
2915 90 70
HazardClass 
8
PackingGroup 
I
Toxicity
LD50 orally in Rabbit: 3000 mg/kg

Use

Benzyl chloroformate decomposes slowly in water forming benzyl alcohol, HCl, and CO2. Gives off HCl fumes in moist air. Reacts with bases, both organic and inorganic. Attacks many metals especially in humid atmosphere [Handling Chemicals Safely 1980. p. 476]. Catalytic impurity incidents involving the iron catalyzed decomposition of benzoyl chloroformate have caused several explosions. The iron presumably comes from corrosion of steel storage tanks [Loss Prev. Bull., 1975, (003), 2]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

32 India supplier list of "Benzyl chloroformate"

  • Product Name:Benzyl chloroformate, 50% in toluene
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Reagent
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg And 1MT
  • Company Type: Manufacturer
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Manufacturer
  • Country/Region: INDIA
  • Product Name:Benzylchloroformate
  • Products Intro:Brand:sigma aldrich | Product Number:8.14688 | Purity:(stabilised)forsynthesis
  • Company Type: Trader
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate, 50% in toluene
  • Products Intro:Brand:Glrinnovations | OriginalID:ASB1060
  • Company Type: Trader
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Company Type: Trader
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Company Type: Trader
  • Country/Region: INDIA
  • Product Name:Benzyl chloroformate
  • Company Type: Trader
  • Country/Region: INDIA

Benzyl chloroformate Related Search:

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