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Hydrogen fluoride

Hydrogen fluoride

CAS:
7664-39-3
MF:
FH
MW:
20.01

Properties

Melting point:
-35°C
Boiling point:
105°C
Density 
1.15 g/mL at 25 °C(lit.)
vapor density 
1.27 (vs air)
vapor pressure 
25 mm Hg ( 20 °C)
Flash point:
112°C
storage temp. 
Store at +5°C to +30°C.
solubility 
very soluble in H2O, ethanol; soluble in ethyl ether
pka
3.17(at 25℃)
form 
Liquid, Double Sub-Boiling Quartz Distillation
Specific Gravity
1.15
PH
3.27(1 mM solution);2.65(10 mM solution);2.12(100 mM solution)
PH Range
1
Odor
Acrid, irritating odor
Water Solubility 
soluble
Sensitive 
Hygroscopic
Merck 
14,4790
Exposure limits
Ceiling limit 3 ppm (~2.5 mg/m3) as F (ACGIH); TWA 3 ppm (MSHA and OSHA).
Dielectric constant
17.0(-73℃)
Stability:
Stable. Hygroscopic. Incompatible with glass, alkali metals, light metals, alkaline earth metals
LogP
0.1 at 20℃

Safety Information

Symbol(GHS) 

GHS05,GHS06
Signal word 
Danger
Hazard statements 
H300+H310+H330-H314
Precautionary statements 
P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+,C,T,Xn
Risk Statements 
26/27/28-35-36/37/38-20/21/22
Safety Statements 
26-36/37/39-45-7/9-36/37-28-36
OEB
B
OEL
TWA: 3 ppm (2.5 mg/m3), Ceiling: 6 ppm (5 mg/m3) [15-minute]
RIDADR 
UN 1790 8/PG 2
WGK Germany 
2
RTECS 
MW7875000
Hazard Note 
Corrosive
TSCA 
Yes
DOT Classification
8, Hazard Zone C (Corrosive material)
HazardClass 
8
PackingGroup 
II
HS Code 
28111100
Toxicity
LC50 (15 min.) in rats, guinea pigs: 2689, 4327 ppm (Rosenholtz)
IDLA
30 ppm

Use

Hydrogen fluoride is the most important compound of fluorine. Anhydrous hydrogen fluoride is used in the production of most fluorine-containing chemicals. It is used in the production of refrigerants, herbicides, pharmaceuticals, high-octane gasoline, aluminum, plastics, electrical components, and fluorescent light bulbs. Aqueous hydrofluoric acid is used in stainless steel pickling, glass etching, metalcoatings, exotic metal extraction, and quartz purification(Hance et al. 1997).The most important use of hydrogen fluoride is in the production of fluorocarbon chemicals, including hydrofluorocarbons, hydrofluorochlorocarbons, and fluoropolymers; 60% of production is used for this purpose. Demand for hydrogen fluoride for fluorocarbons, broadly used as refrigerants, is increasing as a nonchlorinated alternative to ozone-depleting chlorofluorocarbons.(Production of fluorocarbons uses more hydrogen fluoride than production of chlorofluorocarbons.) The next most important uses of hydrogen fluoride are:chemical derivatives,18%; aluminum manufacturing,6%; stainless steel pickling,5%; petroleum alkylation catalysts, 4%; and uranium chemicals production,3%.Miscellaneous other uses include glassetching, herbicides, and rare metals(CMR 2002).

45 India supplier list of "Hydrogen fluoride"

  • Product Name:Hydrofluoric acid, 40%
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Gujarat,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg And 1MT
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Tamil Nadu,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:Anhydrous Hydrofluoric Acid
  • Products Intro:Purity: 99% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Trader
  • Country/Region: Gujarat,INDIA
  • Product Name:HYDROFLUORIC ACID 48% AR,ACS
  • Products Intro:Purity: 48.00% | Package: 1LT;2.5LT;5LT;500ML
  • Company Type: Reagent
  • Country/Region: Maharashtra,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Manufacturer
  • Country/Region: Maharashtra,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Reagent
  • Country/Region: Tamil Nadu,INDIA
  • Product Name:Hydrofluoric acid
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg
  • Company Type: Reagent
  • Country/Region: West Bengal,INDIA

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