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(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE

(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE Structure
  • ₹8600 - ₹23400
  • Product name: (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
  • CAS: 102308-32-7
  • MF: C11H19NO4
  • MW: 229.27
  • EINECS:
  • MDL Number:MFCD00209557
  • Synonyms:(4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde;(S)-Garner aldehyde;1,1-DIMETHYLETHYL-(S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINE CARBOXYLATE;(S)-4-FORMYL-2,2-DIMETHYL-OXAZOLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER;(S)-(-)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE;(S)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE;(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE;TERT-BUTYL (S)-(-)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberB1759
  • Product description(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine min. 95.0 %
  • Packaging1G
  • Price₹8600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1759
  • Product description(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine min. 95.0 %
  • Packaging5G
  • Price₹23400
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number432741
  • Product description(S)-(−)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde 95%
  • Packaging1G
  • Price₹15793.68
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B1759 (S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine min. 95.0 % 1G ₹8600 2022-05-26 Buy
TCI Chemicals (India) B1759 (S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine min. 95.0 % 5G ₹23400 2022-05-26 Buy
Sigma-Aldrich(India) 432741 (S)-(−)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde 95% 1G ₹15793.68 2022-06-14 Buy

Properties

alpha :D -91.7° (c = 1.34 in CHCl3)
Boiling point :83-88 °C1 mm Hg(lit.)
Density :1.06 g/mL at 25 °C(lit.)
refractive index :n20/D 1.445(lit.)
Flash point :226 °F
storage temp. :Inert atmosphere,2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
pka :-3.26±0.60(Predicted)
form :Oil
color :Clear colorless to yellow
optical activity :[α]20/D 90°, c = 1 in chloroform
Water Solubility :Slightly soluble in water.
Sensitive :Air Sensitive
BRN :3591324
CAS DataBase Reference :102308-32-7(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

It is used to prepare γ-aminophosphonates (N-arylamide phosphonates as subtype-selective sphingosine 1-phosphate receptor agonists and antagonists. It is also used to synthesize N-sulfonylated propargylglycine derivatives as metalloproteinase inhibitors. Also widely utilized in the asymmetric synthesis of natural products.

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