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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Di-tert-butylchlorophosphane

Di-tert-butylchlorophosphane

Di-tert-butylchlorophosphane Structure
  • ₹5200 - ₹56300.83
  • Product name: Di-tert-butylchlorophosphane
  • CAS: 13716-10-4
  • MF: C8H18ClP
  • MW: 180.66
  • EINECS:237-266-4
  • MDL Number:MFCD00008815
  • Synonyms:AURORA KA-1319;Bis(1,1-dimethylethyl)-phosphinous chloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-T-BUTYLPHOSPHINOUS CHLORIDE;DI-TERT-BUTYLPHOSPHORUS CHLORIDE;DI-TERT-BUTYLCHLOROPHOSPHANE;(tert-C4H9)2PCl;Di-tert-Butylphosphinous chloride
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • 100G
  • ManufacturerTCI Chemicals (India)
  • Product numberD3632
  • Product descriptionDi-tert-butylchlorophosphine min. 95.0 %
  • Packaging5G
  • Price₹5200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD3632
  • Product descriptionDi-tert-butylchlorophosphine min. 95.0 %
  • Packaging25G
  • Price₹16300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number301558
  • Product descriptionDi-tert-butylchlorophosphine 96%
  • Packaging5G
  • Price₹8800.73
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number301558
  • Product descriptionDi-tert-butylchlorophosphine 96%
  • Packaging25G
  • Price₹21563.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number301558
  • Product descriptionDi-tert-butylchlorophosphine 96%
  • Packaging100G
  • Price₹56300.83
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D3632 Di-tert-butylchlorophosphine min. 95.0 % 5G ₹5200 2022-05-26 Buy
TCI Chemicals (India) D3632 Di-tert-butylchlorophosphine min. 95.0 % 25G ₹16300 2022-05-26 Buy
Sigma-Aldrich(India) 301558 Di-tert-butylchlorophosphine 96% 5G ₹8800.73 2022-06-14 Buy
Sigma-Aldrich(India) 301558 Di-tert-butylchlorophosphine 96% 25G ₹21563.4 2022-06-14 Buy
Sigma-Aldrich(India) 301558 Di-tert-butylchlorophosphine 96% 100G ₹56300.83 2022-06-14 Buy

Properties

Melting point :2-3°C
Boiling point :48 °C/3 mmHg (lit.)
Density :0.951 g/mL at 25 °C (lit.)
refractive index :n20/D 1.482(lit.)
Flash point :142 °F
solubility :Miscible with terahydrofuran.
form :Liquid
Specific Gravity :0.951
color :Clear colorless
Sensitive :Air & Moisture Sensitive
InChIKey :MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference :13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference :Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.

Description

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

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