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ChemicalBook > Product Catalogue >Inorganic chemistry >Inorganic salts >Hydrides, nitrides, azides >Hydride >Lithium Aluminum Hydride

Lithium Aluminum Hydride

Lithium Aluminum Hydride Structure
  • ₹1796.95 - ₹172270.01
  • Product name: Lithium Aluminum Hydride
  • CAS: 16853-85-3
  • MF: LiAlH4
  • MW: 37.954298
  • EINECS:240-877-9
  • MDL Number:MFCD00011075
  • Synonyms:Lithium aluminium hydride,95%,powder;Aluminate(1-), tetrahydro-, lithium, (T-4)-;Aluminum lithium hydride;Lithium aluminum tetrahydride;Lithium tetrahydroaluminate(1-);lithiumaluminumhydride,ethereal ;LithiuM AluMiniuM Hydri;Lithium aluminum hydride ,94%
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  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ALFA India
  • SRL
  • ottokemi

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  • 10gm
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  • 25G
  • 50G
  • 4X25ML
  • 100G
  • 100ML
  • 100gm
  • 250G
  • 4X100ML
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  • ManufacturerSigma-Aldrich(India)
  • Product number62421
  • Product descriptionLithium aluminum hydride ≥97.0% (gas-volumetric), tablet (~0.5 g each)
  • Packaging10G
  • Price₹1796.95
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number62420
  • Product descriptionLithium aluminum hydride ≥97.0% (gas-volumetric)
  • Packaging10G
  • Price₹1959.33
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number199877
  • Product descriptionLithium aluminum hydride powder, reagent grade, 95%
  • Packaging10G
  • Price₹2262.43
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.0566A
  • Product descriptionLithium aluminium hydride (powder) for synthesis
  • Packaging10G
  • Price₹3100
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number212776
  • Product descriptionLithium aluminum hydride solution 1.0?M in THF
  • Packaging25ML
  • Price₹3821.23
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number323403
  • Product descriptionLithium aluminum hydride pellets, reagent grade, 95%
  • Packaging25G
  • Price₹4091.85
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number199877
  • Product descriptionLithium aluminum hydride powder, reagent grade, 95%
  • Packaging500G
  • Price₹47759.9
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number199877
  • Product descriptionLithium aluminum hydride powder, reagent grade, 95%
  • Packaging1KG
  • Price₹51689.38
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number703508
  • Product descriptionLithium aluminum hydride solution 2.3?M in 2-methyltetrahydrofuran
  • Packaging800ML
  • Price₹55824.53
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.14763
  • Product descriptionLithium aluminium hydride (powder) for synthesis
  • Packaging1KG
  • Price₹172270.01
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number686034
  • Product descriptionLithium aluminum hydride hydrogen-storage grade
  • Packaging10G
  • Price₹17071.03
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number212792
  • Product descriptionLithium aluminum hydride solution 1.0?M in diethyl ether
  • Packaging800ML
  • Price₹19214.38
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number212776
  • Product descriptionLithium aluminum hydride solution 1.0?M in THF
  • Packaging4X100ML
  • Price₹20188.63
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number62420
  • Product descriptionLithium aluminum hydride ≥97.0% (gas-volumetric)
  • Packaging250G
  • Price₹20729.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number212776
  • Product descriptionLithium aluminum hydride solution 1.0?M in THF
  • Packaging800ML
  • Price₹22115.48
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number593702
  • Product descriptionLithium aluminum hydride solution 2.0?M in THF
  • Packaging1L
  • Price₹45584.08
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 62421 Lithium aluminum hydride ≥97.0% (gas-volumetric), tablet (~0.5 g each) 10G ₹1796.95 2022-06-14 Buy
Sigma-Aldrich(India) 62420 Lithium aluminum hydride ≥97.0% (gas-volumetric) 10G ₹1959.33 2022-06-14 Buy
Sigma-Aldrich(India) 199877 Lithium aluminum hydride powder, reagent grade, 95% 10G ₹2262.43 2022-06-14 Buy
Sigma-Aldrich(India) 8.0566A Lithium aluminium hydride (powder) for synthesis 10G ₹3100 2022-06-14 Buy
Sigma-Aldrich(India) 212776 Lithium aluminum hydride solution 1.0?M in THF 25ML ₹3821.23 2022-06-14 Buy
Sigma-Aldrich(India) 323403 Lithium aluminum hydride pellets, reagent grade, 95% 25G ₹4091.85 2022-06-14 Buy
Sigma-Aldrich(India) 199877 Lithium aluminum hydride powder, reagent grade, 95% 500G ₹47759.9 2022-06-14 Buy
Sigma-Aldrich(India) 199877 Lithium aluminum hydride powder, reagent grade, 95% 1KG ₹51689.38 2022-06-14 Buy
Sigma-Aldrich(India) 703508 Lithium aluminum hydride solution 2.3?M in 2-methyltetrahydrofuran 800ML ₹55824.53 2022-06-14 Buy
Sigma-Aldrich(India) 8.14763 Lithium aluminium hydride (powder) for synthesis 1KG ₹172270.01 2022-06-14 Buy
Sigma-Aldrich(India) 686034 Lithium aluminum hydride hydrogen-storage grade 10G ₹17071.03 2022-06-14 Buy
Sigma-Aldrich(India) 212792 Lithium aluminum hydride solution 1.0?M in diethyl ether 800ML ₹19214.38 2022-06-14 Buy
Sigma-Aldrich(India) 212776 Lithium aluminum hydride solution 1.0?M in THF 4X100ML ₹20188.63 2022-06-14 Buy
Sigma-Aldrich(India) 62420 Lithium aluminum hydride ≥97.0% (gas-volumetric) 250G ₹20729.88 2022-06-14 Buy
Sigma-Aldrich(India) 212776 Lithium aluminum hydride solution 1.0?M in THF 800ML ₹22115.48 2022-06-14 Buy
Sigma-Aldrich(India) 593702 Lithium aluminum hydride solution 2.0?M in THF 1L ₹45584.08 2022-06-14 Buy

Properties

Melting point :125 °C (dec.)(lit.)
Boiling point :0°C
Density :0.97 g/mL at 20 °C
Flash point :99 °F
storage temp. :Store below +30°C.
solubility :reacts with H2O, ethanol; seth, tetrahydrofuran
form :tablets (~0.5 g each)
Specific Gravity :0.917
color :White to light gray
Odor :Odorless solid
Water Solubility :Reacts
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,350
Exposure limits :TLV-TWA 2 mg(Al)/m3 (ACGIH).
Stability :Stable. Reacts violently with water, liberating hydrogen. Incompatible with strong oxidizing agents, alcohols, acids.
CAS DataBase Reference :16853-85-3(CAS DataBase Reference)
NIST Chemistry Reference :Lithium tetrahydroaluminate(16853-85-3)
EPA Substance Registry System :Lithium aluminum hydride (16853-85-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Lithium aluminum hydride (LiAlH4) is a promising compound for hydrogen storage, with a high gravimetric and volumetric hydrogen density and a low decomposition temperature. Similar to other metastable hydrides, LiAlH4 does not form by direct hydrogenation at reasonable hydrogen pressures; therefore, there is considerable interest in developing new routes to regenerate the material from the dehydrogenated products LiH and Al. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

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