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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic aluminum >Diisobutylaluminium hydride

Diisobutylaluminium hydride

Diisobutylaluminium hydride Structure
  • ₹2002 - ₹40344.78
  • Product name: Diisobutylaluminium hydride
  • CAS: 1191-15-7
  • MF: C8H19Al
  • MW: 142.22
  • EINECS:214-729-9
  • MDL Number:MFCD00008928
  • Synonyms:Diisobutylaluminium hydride, 1.1M solution in cyclohexane, AcroSeal;Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal;Diisobutylaluminium hydride, 1.0M solution in heptane, AcroSeal;DIISOBUTYLALUMINUM HYDRIDE: 20% (CA. 1M) SOLUTION IN TOLUENE;DIISOBUYTL AMUMINIUM HYDRIDE;Diisobutylaluminum hydride,reagent grade;DiisobutylaluMiniuM hydride, 1.1M solution in cyclohexane, AcroSeal 800ML;DiisobutylaluMiniuM hydride, 1M solution in hexane, AcroSeal 400ML
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  • Sigma-Aldrich(India)
  • ALFA India
  • ottokemi

Package

  • 50mL
  • 100mL
  • 4X25ML
  • 250mL
  • 400mL
  • 800ML
  • 1L
  • ManufacturerSigma-Aldrich(India)
  • Product number214949
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in cyclohexane
  • Packaging800ML
  • Price₹32280.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number214981
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in THF
  • Packaging800ML
  • Price₹34282.78
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number215007
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in toluene
  • Packaging800ML
  • Price₹40344.78
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042589-K2
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane
  • Packaging1L
  • Price₹20990
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042588-AK
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane
  • Packaging250mL
  • Price₹7454
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-042589-AK
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane
  • Packaging250mL
  • Price₹6922
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-L14718-AE
  • Product descriptionDiisobutylaluminum hydride, 1M solution in toluene
  • Packaging100mL
  • Price₹6111
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042588-AD
  • Product descriptionDiisobutylaluminum hydride, 25% w/w in hexane
  • Packaging50mL
  • Price₹2347
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042589-AD
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane
  • Packaging50mL
  • Price₹2336
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-042593-AD
  • Product descriptionDiisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging50mL
  • Price₹2002
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number214949
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in cyclohexane
  • Packaging100ML
  • Price₹7025.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number214981
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in THF
  • Packaging100ML
  • Price₹7090.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number214981
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in THF
  • Packaging4X25ML
  • Price₹8584.23
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number215007
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in toluene
  • Packaging100ML
  • Price₹8649.18
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number215007
  • Product descriptionDiisobutylaluminum hydride solution 1.0?M in toluene
  • Packaging4X25ML
  • Price₹9590.95
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number D 1897
  • Product descriptionDiisobutylaluminium hydride solution 20 wt. % in toluene
  • Packaging400mL
  • Price₹20619
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 214949 Diisobutylaluminum hydride solution 1.0?M in cyclohexane 800ML ₹32280.15 2022-06-14 Buy
Sigma-Aldrich(India) 214981 Diisobutylaluminum hydride solution 1.0?M in THF 800ML ₹34282.78 2022-06-14 Buy
Sigma-Aldrich(India) 215007 Diisobutylaluminum hydride solution 1.0?M in toluene 800ML ₹40344.78 2022-06-14 Buy
ALFA India ALF-042589-K2 Diisobutylaluminum hydride, 1M solution in hexane 1L ₹20990 2022-05-26 Buy
ALFA India ALF-042588-AK Diisobutylaluminum hydride, 25% w/w in hexane 250mL ₹7454 2022-05-26 Buy
ALFA India ALF-042589-AK Diisobutylaluminum hydride, 1M solution in hexane 250mL ₹6922 2022-05-26 Buy
ALFA India ALF-L14718-AE Diisobutylaluminum hydride, 1M solution in toluene 100mL ₹6111 2022-05-26 Buy
ALFA India ALF-042588-AD Diisobutylaluminum hydride, 25% w/w in hexane 50mL ₹2347 2022-05-26 Buy
ALFA India ALF-042589-AD Diisobutylaluminum hydride, 1M solution in hexane 50mL ₹2336 2022-05-26 Buy
ALFA India ALF-042593-AD Diisobutylaluminum hydride, 1M solution in hexane, packaged under Argon in resealable ChemSeal™ bottles 50mL ₹2002 2022-05-26 Buy
Sigma-Aldrich(India) 214949 Diisobutylaluminum hydride solution 1.0?M in cyclohexane 100ML ₹7025.43 2022-06-14 Buy
Sigma-Aldrich(India) 214981 Diisobutylaluminum hydride solution 1.0?M in THF 100ML ₹7090.38 2022-06-14 Buy
Sigma-Aldrich(India) 214981 Diisobutylaluminum hydride solution 1.0?M in THF 4X25ML ₹8584.23 2022-06-14 Buy
Sigma-Aldrich(India) 215007 Diisobutylaluminum hydride solution 1.0?M in toluene 100ML ₹8649.18 2022-06-14 Buy
Sigma-Aldrich(India) 215007 Diisobutylaluminum hydride solution 1.0?M in toluene 4X25ML ₹9590.95 2022-06-14 Buy
ottokemi D 1897 Diisobutylaluminium hydride solution 20 wt. % in toluene 400mL ₹20619 2022-05-26 Buy

Properties

Melting point :-70 °C
Boiling point :65 °C
Density :1.23 g/mL at 25 °C
vapor pressure :13.3Pa at 90℃
Flash point :40 °F
storage temp. :2-8°C
solubility :Miscible with organic solvents.
form :Solution
color :Clear
Specific Gravity :0.860
Water Solubility :vigorous reaction
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Sensitive :Air Sensitive/Heat Sensitive
BRN :4123663
Exposure limits :ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) InChIKey :AZWXAPCAJCYGIA-UHFFFAOYSA-N
LogP :4.22
CAS DataBase Reference :1191-15-7(CAS DataBase Reference)
NIST Chemistry Reference :Diisobutylaluminum hydride(1191-15-7)
EPA Substance Registry System :Diisobutylaluminum hydride (1191-15-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378 In case of fire: Use … for extinction.

Description

Reducing agentDiisobutylaluminum hydride, 1M solution in hexane is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-debenzylation and ring opening of perbenzylated furanosides. It is involved in the in situ generation of HZrCpCl by reacting with ZrCpCl. It is useful in organic synthesis for a variety of reductions, including converting esters and nitriles to aldehydes. Also, used in the reduction of alpha-beta unsaturated esters to their corresponding allylic alcohols.

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