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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Ionic Liquids >1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride  Structure
  • ₹5700 - ₹21390.2
  • Product name: 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
  • CAS: 141556-45-8
  • MF: C21H25ClN2
  • MW: 340.89
  • EINECS:
  • MDL Number:MFCD02684541
  • Synonyms:1,3-DIMESITYLIMIDAZOLIUM CHLORIDE;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;1,3-(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;N,N'-(2,4,6-TRIMETHYLPHENYL)DIHYDROIMADAZOLIUM CHLORIDE;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLI&;1,3-Bis(2,4,6-trimethylphenyl)imidazoliumchloride,min.95%;1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-1H-IMIDAZOLIUM CHLORIDE;1,3-Bis-(2,4,6-trimethyl-phenyl)-3H-imidazol-1-ium chloride
6 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberD3446
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging1G
  • Price₹5700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD3446
  • Product description1,3-Dimesitylimidazolium Chloride
  • Packaging5G
  • Price₹12500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number574066
  • Product description1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
  • Packaging1G
  • Price₹7328.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number574066
  • Product description1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
  • Packaging5G
  • Price₹21390.2
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27535-06
  • Product description1,3-Dimesitylimidazolium chloride, 96%
  • Packaging5g
  • Price₹15397
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H27535-03
  • Product description1,3-Dimesitylimidazolium chloride, 96%
  • Packaging1g
  • Price₹5700
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D3446 1,3-Dimesitylimidazolium Chloride 1G ₹5700 2022-05-26 Buy
TCI Chemicals (India) D3446 1,3-Dimesitylimidazolium Chloride 5G ₹12500 2022-05-26 Buy
Sigma-Aldrich(India) 574066 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride 1G ₹7328.53 2022-06-14 Buy
Sigma-Aldrich(India) 574066 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride 5G ₹21390.2 2022-06-14 Buy
ALFA India ALF-H27535-06 1,3-Dimesitylimidazolium chloride, 96% 5g ₹15397 2022-05-26 Buy
ALFA India ALF-H27535-03 1,3-Dimesitylimidazolium chloride, 96% 1g ₹5700 2022-05-26 Buy

Properties

Melting point :>300 °C (lit.)
Boiling point :499.2°C (rough estimate)
Density :1.0279 (rough estimate)
refractive index :1.5940 (estimate)
storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
form :Powder
color :Off-white to beige
Water Solubility :Slightly soluble in water.
InChIKey :OTOSIXGMLYKKOW-UHFFFAOYSA-M
CAS DataBase Reference :141556-45-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides.

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