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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Bis-(triphenylphosphino)-cuprous borohydride

Bis-(triphenylphosphino)-cuprous borohydride

Bis-(triphenylphosphino)-cuprous borohydride Structure
  • ₹2500
  • Product name: Bis-(triphenylphosphino)-cuprous borohydride
  • CAS: 16903-61-0
  • MF: 2C18H15P.Cu.BH4
  • MW: 602.97
  • EINECS:240-951-0
  • MDL Number:MFCD00013219
  • Synonyms:Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD;Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE;BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE;BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE;bis-(triphenylphosphino)-cuprous borohydride;Copper bis(trimethylphosphine)(tetrahydroborate)
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Selected condition:

Brand

  • TCI Chemicals (India)

Package

  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberB1139
  • Product descriptionBis(triphenylphosphine)copper Tetrahydroborate
  • Packaging5G
  • Price₹2500
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B1139 Bis(triphenylphosphine)copper Tetrahydroborate 5G ₹2500 2022-05-26 Buy

Properties

Melting point :164 °C (dec.)(lit.)
storage temp. :Store below +30°C.
form :powder to crystal
color :White to Almost white
Sensitive :Moisture Sensitive
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 CAS DataBase Reference :16903-61-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes.

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