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[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Structure
  • ₹4360
  • Product name: [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
  • CAS: 18498-01-6
  • MF: C26H26Cl2CoP2
  • MW: 530.27
  • EINECS:
  • MDL Number:MFCD00134173
  • Synonyms:1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97%;1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2;Dichloro[ethylenebis[diphenylphosphine]]cobalt;[1,2-BIs(diphenylphosphino);ethane]dichlorocobalt(II);(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt;[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II);[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number360147
  • Product description[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II)
  • Packaging1G
  • Price₹4360
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 360147 [1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II) 1G ₹4360 2022-06-14 Buy

Properties

Melting point :260 °C (dec.)(lit.)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :green
Water Solubility :Insoluble in water.
Sensitive :Hygroscopic

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning GHS hazard pictograms P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions.

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