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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Tetrabutylphosphonium bromide

Tetrabutylphosphonium bromide

Tetrabutylphosphonium bromide Structure
  • ₹2000 - ₹26542.9
  • Product name: Tetrabutylphosphonium bromide
  • CAS: 3115-68-2
  • MF: C16H36BrP
  • MW: 339.33
  • EINECS:221-487-8
  • MDL Number:MFCD00011853
  • Synonyms:Tertabutylphosphoriun bromide;tetrabutyl-phosphoniubromide ;Tetra-N-butylphosphoniumbromide99%;TributylphosphoniuM broMide;TetrabutylphosphoniuM broMide, 98% 25GR;TetrabutylphosphoniuM broMid;PhosphoniuM,tetrabutyl-, broMide (1:1);P4,4,4,4Br
5 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 25G
  • 100G
  • 500G
  • ManufacturerTCI Chemicals (India)
  • Product numberT1124
  • Product descriptionTetrabutylphosphonium Bromide
  • Packaging25G
  • Price₹2000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1124
  • Product descriptionTetrabutylphosphonium Bromide
  • Packaging100G
  • Price₹3800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1124
  • Product descriptionTetrabutylphosphonium Bromide
  • Packaging500G
  • Price₹17300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number189138
  • Product descriptionTetrabutylphosphonium bromide 98%
  • Packaging100G
  • Price₹7209.45
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number189138
  • Product descriptionTetrabutylphosphonium bromide 98%
  • Packaging500G
  • Price₹26542.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T1124 Tetrabutylphosphonium Bromide 25G ₹2000 2022-05-26 Buy
TCI Chemicals (India) T1124 Tetrabutylphosphonium Bromide 100G ₹3800 2022-05-26 Buy
TCI Chemicals (India) T1124 Tetrabutylphosphonium Bromide 500G ₹17300 2022-05-26 Buy
Sigma-Aldrich(India) 189138 Tetrabutylphosphonium bromide 98% 100G ₹7209.45 2022-06-14 Buy
Sigma-Aldrich(India) 189138 Tetrabutylphosphonium bromide 98% 500G ₹26542.9 2022-06-14 Buy

Properties

Melting point :100-103 °C(lit.)
Density :1.8[at 20℃]
vapor pressure :0.018Pa at 25℃
Flash point :290 °C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :crystal
color :white
Water Solubility :ca 70 g/100 mL
Sensitive :Hygroscopic
BRN :4160474
Stability :hygroscopic
InChIKey :JRMUNVKIHCOMHV-UHFFFAOYSA-M
LogP :-0.44 at 23℃
CAS DataBase Reference :3115-68-2(CAS DataBase Reference)
NIST Chemistry Reference :Phosphonium bromide, tetrabutyl(3115-68-2)
EPA Substance Registry System :Phosphonium, tetrabutyl-, bromide (3115-68-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning GHS hazard pictograms P234, P390, P404
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Tetrabutylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and -keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.

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