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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Azide >2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzene-sulfonyl azide Structure
  • ₹2600 - ₹20056.4
  • Product name: 2,4,6-Triisopropylbenzene-sulfonyl azide
  • CAS: 36982-84-0
  • MF: C15H23N3O2S
  • MW: 309.43
  • EINECS:
  • MDL Number:MFCD00859286
  • Synonyms:2,4,6-Triisopropylbenzenesulphonylazide ;Trisyl azide;2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water;2,4,6-Triisopropylbenzenesulfonyl azide ,90% [stab. With ca 10% water];2,4,6-Triisopropylbenzenesulfonic acid azide;2,4,6-Triisopropylbe;2,4,6-Triisopropylp henylsulfonyl azide;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide
5 prices
Selected condition:

Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 5g
  • 25G
  • ManufacturerALFA India
  • Product numberALF-L19383-03
  • Product description2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water
  • Packaging1g
  • Price₹3888
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19383-06
  • Product description2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water
  • Packaging5g
  • Price₹12594
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT3434
  • Product description2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)
  • Packaging1G
  • Price₹2600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT3434
  • Product description2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)
  • Packaging5G
  • Price₹7800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number778443
  • Product description2,4,6-Triisopropylbenzenesulfonyl azide solution 10%±2% in toluene, ≥98% (HPLC)
  • Packaging25G
  • Price₹20056.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L19383-03 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water 1g ₹3888 2022-05-26 Buy
ALFA India ALF-L19383-06 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water 5g ₹12594 2022-05-26 Buy
TCI Chemicals (India) T3434 2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis) 1G ₹2600 2022-05-26 Buy
TCI Chemicals (India) T3434 2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis) 5G ₹7800 2022-05-26 Buy
Sigma-Aldrich(India) 778443 2,4,6-Triisopropylbenzenesulfonyl azide solution 10%±2% in toluene, ≥98% (HPLC) 25G ₹20056.4 2022-06-14 Buy

Properties

Melting point :39-44 °C
refractive index :n20/D1.499
Flash point :4℃
storage temp. :2-8°C
solubility :Chloroform (Slightly), Ethyl Acetate (Slightly)
form :Solid
color :White to Off-White
Water Solubility :Insoluble in water.
BRN :2391566
InChIKey :AEMWUHCKKDPRSK-UHFFFAOYSA-N
CAS DataBase Reference :36982-84-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273 Avoid release to the environment.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.

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