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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P Structure
  • ₹6375.93 - ₹1671380
  • Product name: (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
  • CAS: 387868-06-6
  • MF: C46H32F12FeP210*
  • MW: 930.52
  • EINECS:
  • MDL Number:MFCD04112740
  • Synonyms:(R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluor;(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine,min.97%;(r)-1-{(r)-2-[2-(diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine;(r,r)-1-{1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl}-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to cas);(R)-(-)-1-[(R)-2-(2'DIPHENYLPHOSPHINOPHENYL)FERROCANYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE;(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLBIS[3,5-BIS-(TRIFLUOROMETHYL)PHENYL]PHOSPHINE;(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P;(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE
Price6 Properties Safety Information Description
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  • Sigma-Aldrich(India)

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  • 100MG
  • 500MG
  • 1G
  • 5G
  • 50G
  • 100G
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging100G
  • Price₹1671380
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging50G
  • Price₹994882.45
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging5G
  • Price₹261337.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging1G
  • Price₹52024.95
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging500MG
  • Price₹30461.55
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number65671
  • Product description(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97%
  • Packaging100MG
  • Price₹6375.93
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 100G ₹1671380 2022-06-14 Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 50G ₹994882.45 2022-06-14 Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 5G ₹261337.15 2022-06-14 Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 1G ₹52024.95 2022-06-14 Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 500MG ₹30461.55 2022-06-14 Buy
Sigma-Aldrich(India) 65671 (R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine ≥97% 100MG ₹6375.93 2022-06-14 Buy

Properties

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

Walphos SL-W001-1, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:
  • Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
  • Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

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