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ChemicalBook > Product Catalogue >Catalyst and Auxiliary >Antioxidant >4,4'-Methylenedianiline

4,4'-Methylenedianiline

4,4'-Methylenedianiline Structure
  • ₹1916.03 - ₹16042.65
  • Product name: 4,4'-Methylenedianiline
  • CAS: 101-77-9
  • MF: C13H14N2
  • MW: 198.26
  • EINECS:202-974-4
  • MDL Number:MFCD00007914
  • Synonyms:Di-(4-aminophenyl)methane;bis(p-aminophenyl)methane;ZERENEX ZX004995;P,P'-METHYLENEDIANILINE;P,P'-DIAMINODIPHENYLMETHANE;4,4-Diaminodiphenylmethane~MDA;4,4′-Metylene dianiline;4,4'-METHYLENEDIANILINE
11 prices
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Brand

  • Sigma-Aldrich
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 50MG
  • 250MG
  • 25G
  • 50G
  • 250G
  • 500gm
  • 500G
  • 1KG
  • ManufacturerSigma-Aldrich
  • Product number31640
  • Product description4,4′-Diaminodiphenylmethane analytical standard
  • Packaging250MG
  • Price₹9926.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number18139
  • Product description4,4′-Diaminodiphenylmethane certified reference material, TraceCERT?
  • Packaging50MG
  • Price₹16042.65
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM0220
  • Product description4,4'-Diaminodiphenylmethane min. 97.0 %
  • Packaging25G
  • Price₹2000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM0220
  • Product description4,4'-Diaminodiphenylmethane min. 97.0 %
  • Packaging500G
  • Price₹3500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number32950
  • Product description4,4′-Diaminodiphenylmethane ≥97.0% (GC)
  • Packaging50G
  • Price₹1916.03
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number32950
  • Product description4,4′-Diaminodiphenylmethane ≥97.0% (GC)
  • Packaging250G
  • Price₹2911.93
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number32950
  • Product description4,4′-Diaminodiphenylmethane ≥97.0% (GC)
  • Packaging1KG
  • Price₹9753.33
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number31640
  • Product description4,4′-Diaminodiphenylmethane analytical standard
  • Packaging250MG
  • Price₹9926.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number18139
  • Product description4,4′-Diaminodiphenylmethane certified reference material, TraceCERT?
  • Packaging50MG
  • Price₹16042.65
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number D 1376
  • Product description4,4'-Diaminodiphenylmethane 98%
  • Packaging500gm
  • Price₹3195
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 1377
  • Product description4,4'-Diaminodiphenylmethane 99%
  • Packaging500gm
  • Price₹4005
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 31640 4,4′-Diaminodiphenylmethane analytical standard 250MG ₹9926.53 2022-06-14 Buy
Sigma-Aldrich 18139 4,4′-Diaminodiphenylmethane certified reference material, TraceCERT? 50MG ₹16042.65 2022-06-14 Buy
TCI Chemicals (India) M0220 4,4'-Diaminodiphenylmethane min. 97.0 % 25G ₹2000 2022-05-26 Buy
TCI Chemicals (India) M0220 4,4'-Diaminodiphenylmethane min. 97.0 % 500G ₹3500 2022-05-26 Buy
Sigma-Aldrich(India) 32950 4,4′-Diaminodiphenylmethane ≥97.0% (GC) 50G ₹1916.03 2022-06-14 Buy
Sigma-Aldrich(India) 32950 4,4′-Diaminodiphenylmethane ≥97.0% (GC) 250G ₹2911.93 2022-06-14 Buy
Sigma-Aldrich(India) 32950 4,4′-Diaminodiphenylmethane ≥97.0% (GC) 1KG ₹9753.33 2022-06-14 Buy
Sigma-Aldrich(India) 31640 4,4′-Diaminodiphenylmethane analytical standard 250MG ₹9926.53 2022-06-14 Buy
Sigma-Aldrich(India) 18139 4,4′-Diaminodiphenylmethane certified reference material, TraceCERT? 50MG ₹16042.65 2022-06-14 Buy
ottokemi D 1376 4,4'-Diaminodiphenylmethane 98% 500gm ₹3195 2022-05-26 Buy
ottokemi D 1377 4,4'-Diaminodiphenylmethane 99% 500gm ₹4005 2022-05-26 Buy

Properties

Melting point :89-91 °C(lit.)
Boiling point :242 °C2 mm Hg(lit.)
Density :1.15
vapor pressure :0Pa at 25℃
refractive index :1.5014 (estimate)
Flash point :430 °F
solubility :water: soluble
pka :5.32±0.25(Predicted)
color :White to Light yellow
Water Solubility :Slightly soluble. <0.1 g/100 mL at 19 ºC
Merck :14,2980
BRN :474706
Exposure limits :ACGIH: TWA 0.1 ppm (Skin)
OSHA: STEL 100 ppb LogP :1.55 at 25℃
CAS DataBase Reference :101-77-9(CAS DataBase Reference)
IARC :2B (Vol. 39, Sup 7) 1987
NIST Chemistry Reference :Benzenamine, 4,4'-methylenebis-(101-77-9)
EPA Substance Registry System :4,4'-Methylenedianiline (101-77-9)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.

Description

4,4'-Diaminodiphenylmethane is used as an intermediate for the preparation of 4,4-methylenediphenyldiisocyanate, 4,4'-methylenebis(cyclohexaneamine). It is also used in the preparation of polyurethane foams. Further, it is used as hardeners in epoxy resins and adhesives. In addition to this, it is used in the manufacturing of high-performance polymers.

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