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(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine

(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Structure
  • ₹3500 - ₹41920
  • Product name: (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
  • CAS: 68737-65-5
  • MF: C8H18N2
  • MW: 142.24
  • EINECS:
  • MDL Number:MFCD00671527
  • Synonyms:(1R,2R)-(-)-1,2-BIS(METHYLAMINO)CYCLOHEXANE;(1R,2R)-1,2-BIS(METHYLAMINO)CYCLOHEXANE;(1R,2R)-(-)-N,N'-DIMETHYLCYCLOHEXANE-1,2-DIAMINE;(1R,2R)-N,N'-DIMETHYL-1,2-CYCLOHEXANEDIAMINE;trans-1,2-Bis(methylamino)cyclohexane, (R,R)-(-)-N,Nμ-Dimethyl-1,2-diaminocyclohexane;(R,R)-(-)-N,N'-Dimethyl-1,2-cyclohexandiamine;(R,R)-1,2-Bis(methylamino)cyclohexane.;N,N'-Dimethyl-cyclohexane-1,2-diamine
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberD2459
  • Product description(1R,2R)-(-)-N,N'-Dimethylcyclohexane-1,2-diamine min. 94.0 %
  • Packaging100MG
  • Price₹3500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2459
  • Product description(1R,2R)-(-)-N,N'-Dimethylcyclohexane-1,2-diamine min. 94.0 %
  • Packaging1G
  • Price₹15800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number671274
  • Product description(R,R)-(−)-N,N′-Dimethyl-1,2-cyclohexanediamine ≥97.0% (GC)
  • Packaging1G
  • Price₹41920
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D2459 (1R,2R)-(-)-N,N'-Dimethylcyclohexane-1,2-diamine min. 94.0 % 100MG ₹3500 2022-05-26 Buy
TCI Chemicals (India) D2459 (1R,2R)-(-)-N,N'-Dimethylcyclohexane-1,2-diamine min. 94.0 % 1G ₹15800 2022-05-26 Buy
Sigma-Aldrich(India) 671274 (R,R)-(−)-N,N′-Dimethyl-1,2-cyclohexanediamine ≥97.0% (GC) 1G ₹41920 2022-06-14 Buy

Properties

Melting point :39-44 °C
alpha :-145 º (c=4.47 in chloroform)
Boiling point :249.85°C (rough estimate)
Density :0.902
refractive index :-140 ° (C=4, CHCl3)
Flash point :74 °C
storage temp. :2-8°C
pka :11.04±0.40(Predicted)
form :Low Melting Solid
color :White to light yellow
optical activity :[α]/D -145±5°, c = 4.47 in chloroform
InChIKey :JRHPOFJADXHYBR-HTQZYQBOSA-N
CAS DataBase Reference :68737-65-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(R,R)-(?)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:
  • As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
  • In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.
  • To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.


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