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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >Propylphosphonic anhydride

Propylphosphonic anhydride

Propylphosphonic anhydride Structure
  • ₹3606 - ₹384640
  • Product name: Propylphosphonic anhydride
  • CAS: 68957-94-8
  • MF: C9H21O6P3
  • MW: 318.18
  • EINECS:422-210-5
  • MDL Number:MFCD00006583
  • Synonyms:1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloroMethane;1-Propylphosphonic acid cyclic anhydride, 50 wt.% solution in ethyl acetate;1-Propylphosphonic anhydride solution, 50 wt. % in DMF;1-Propylphosphonic anhydride solution, 50 wt. % in ethyl acetate;2,4,6-tripropyl-1,3,5,2λ5,4λ5,6λ5-trioxatriphosphinane 2,4,6-trioxide;2,4,6-Tripropyl-1,3,5,2,4,6-trioxotriphosphorinane-2,4,6-trioxide (50% solution in Ethyl aceta;1-Propanephosphonic anhydride, in 50% DMF solution≥ 95%;2,4,6-Tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide solution
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Brand

  • ALFA India
  • Sigma-Aldrich(India)

Package

  • 8439422500
  • 10ML
  • 8439432500
  • 10g
  • 8439442500
  • 25ML
  • 50g
  • 50ML
  • 100ML
  • 250g
  • 500ML
  • 1kg
  • ManufacturerALFA India
  • Product numberALF-L11911-09
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate
  • Packaging10g
  • Price₹3606
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19271-09
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF
  • Packaging10g
  • Price₹3972
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H63583-09
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane
  • Packaging10g
  • Price₹4443
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H66967-18
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile
  • Packaging50g
  • Price₹4791
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H63583-18
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane
  • Packaging50g
  • Price₹4791
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19271-18
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF
  • Packaging50g
  • Price₹11560
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L11911-18
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate
  • Packaging50g
  • Price₹11910
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H63583-30
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane
  • Packaging250g
  • Price₹13577
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H66967-30
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile
  • Packaging250g
  • Price₹21226
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L11911-A1
  • Product description1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate
  • Packaging1kg
  • Price₹58000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number431303
  • Product descriptionPropylphosphonic anhydride solution ≥50?wt. % in ethyl acetate
  • Packaging10ML
  • Price₹4402.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.43942
  • Product descriptionPropanephosphonic acid anhydride (50% solution in ethyl acetate) for synthesis T3P
  • Packaging25ML
  • Price₹4540.01
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.43944
  • Product descriptionPropanephosphonic acid anhydride (50% solution in Dimethyl formamide) for synthesis T3P
  • Packaging25ML
  • Price₹4850
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.43943
  • Product descriptionPropanephosphonic acid anhydride (50% solution in 2-Methyltetrahydrofuran) for synthesis T3P
  • Packaging25ML
  • Price₹5660
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.43942
  • Product descriptionPropanephosphonic acid anhydride (50% solution in ethyl acetate) for synthesis T3P
  • Packaging50ML
  • Price₹7290
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.43944
  • Product descriptionPropanephosphonic acid anhydride (50% solution in Dimethyl formamide) for synthesis T3P
  • Packaging50ML
  • Price₹8449.99
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L11911-09 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate 10g ₹3606 2022-05-26 Buy
ALFA India ALF-L19271-09 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF 10g ₹3972 2022-05-26 Buy
ALFA India ALF-H63583-09 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane 10g ₹4443 2022-05-26 Buy
ALFA India ALF-H66967-18 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile 50g ₹4791 2022-05-26 Buy
ALFA India ALF-H63583-18 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane 50g ₹4791 2022-05-26 Buy
ALFA India ALF-L19271-18 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF 50g ₹11560 2022-05-26 Buy
ALFA India ALF-L11911-18 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate 50g ₹11910 2022-05-26 Buy
ALFA India ALF-H63583-30 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane 250g ₹13577 2022-05-26 Buy
ALFA India ALF-H66967-30 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile 250g ₹21226 2022-05-26 Buy
ALFA India ALF-L11911-A1 1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate 1kg ₹58000 2022-05-26 Buy
Sigma-Aldrich(India) 431303 Propylphosphonic anhydride solution ≥50?wt. % in ethyl acetate 10ML ₹4402.3 2022-06-14 Buy
Sigma-Aldrich(India) 8.43942 Propanephosphonic acid anhydride (50% solution in ethyl acetate) for synthesis T3P 25ML ₹4540.01 2022-06-14 Buy
Sigma-Aldrich(India) 8.43944 Propanephosphonic acid anhydride (50% solution in Dimethyl formamide) for synthesis T3P 25ML ₹4850 2022-06-14 Buy
Sigma-Aldrich(India) 8.43943 Propanephosphonic acid anhydride (50% solution in 2-Methyltetrahydrofuran) for synthesis T3P 25ML ₹5660 2022-06-14 Buy
Sigma-Aldrich(India) 8.43942 Propanephosphonic acid anhydride (50% solution in ethyl acetate) for synthesis T3P 50ML ₹7290 2022-06-14 Buy
Sigma-Aldrich(India) 8.43944 Propanephosphonic acid anhydride (50% solution in Dimethyl formamide) for synthesis T3P 50ML ₹8449.99 2022-06-14 Buy

Properties

Boiling point :65 °C
Density :1.069 g/mL at 25 °C
vapor pressure :0Pa at 25℃
refractive index :n20/D 1.418
Flash point :25 °F
storage temp. :Flammables area
solubility :Miscible with dioxane, terahydrofuran, dimethyl formamide, polar and aprotic organic solvents.
form :Solution
color :Clear yellow to brownish
Water Solubility :9.6g/L at 25℃
Sensitive :Moisture Sensitive
BRN :5079255
Exposure limits :ACGIH: TWA 20 ppm (Skin)
OSHA: TWA 40 ppm(70 mg/m3)
NIOSH: IDLH 137 ppm(25 mg/m3); TWA 20 ppm(34 mg/m3) Stability :Moisture Sensitive
LogP :0 at 25℃
CAS DataBase Reference :68957-94-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning GHS hazard pictograms P234, P390, P404
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P234 Keep only in original container.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

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