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ChemicalBook > Product Catalogue >Organic Chemistry >Organosulfur compounds >Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Structure
  • ₹1600 - ₹24616.05
  • Product name: Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester
  • CAS: 69739-34-0
  • MF: C7H15F3O3SSi
  • MW: 264.34
  • EINECS:274-102-0
  • MDL Number:MFCD00000405
  • Synonyms:Methanesulfonic acid, trifluoro-, (1,1-dimethylethyl)dimethylsilyl ester;t-butyldimethylsilyltrifluormethansulfonate ;t-Butylmethylsilyl triflate;TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester;SILANE TBM2 TRIFLATE;Silane TBM2 triflate, TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester;(R)-4-isopropyl-5,5-diphenyloxazolidine-2-thione;Methanesulfonic acid, trifluoro-, (1,1-diMethylethyl)diMethylsilyl ester (9CI)
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  • Sigma-Aldrich
  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • SRL

Package

  • 1G
  • 5ml
  • 5G
  • 10ML
  • 25g
  • 25ML
  • 100mL
  • ManufacturerSigma-Aldrich
  • Product number226149
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%
  • Packaging5G
  • Price₹4546.5
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A12174-06
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate, 98%
  • Packaging5g
  • Price₹2873
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A12174-14
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate, 98%
  • Packaging25g
  • Price₹10386
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1525
  • Product descriptiontert-Butyldimethylsilyl Trifluoromethanesulfonate
  • Packaging5G
  • Price₹3500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1525
  • Product descriptiontert-Butyldimethylsilyl Trifluoromethanesulfonate
  • Packaging25G
  • Price₹9100
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number226149
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%
  • Packaging1G
  • Price₹1634.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number226149
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%
  • Packaging5G
  • Price₹4546.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number226149
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%
  • Packaging25G
  • Price₹16064.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.18313
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate for synthesis
  • Packaging25ML
  • Price₹19930
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number56563
  • Product descriptiontert-Butyldimethylsilyl trifluoromethanesulfonate for GC derivatization, LiChropur?, ≥98.0% (T)
  • Packaging10ML
  • Price₹24616.05
  • Updated2022-06-14
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  • ManufacturerSRL
  • Product number52573
  • Product descriptiontert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98%
  • Packaging5ml
  • Price₹1600
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number52573
  • Product descriptiontert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98%
  • Packaging25mL
  • Price₹6820
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number52573
  • Product descriptiontert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98%
  • Packaging100mL
  • Price₹19090
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 226149 tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98% 5G ₹4546.5 2022-06-14 Buy
ALFA India ALF-A12174-06 tert-Butyldimethylsilyl trifluoromethanesulfonate, 98% 5g ₹2873 2022-05-26 Buy
ALFA India ALF-A12174-14 tert-Butyldimethylsilyl trifluoromethanesulfonate, 98% 25g ₹10386 2022-05-26 Buy
TCI Chemicals (India) T1525 tert-Butyldimethylsilyl Trifluoromethanesulfonate 5G ₹3500 2022-05-26 Buy
TCI Chemicals (India) T1525 tert-Butyldimethylsilyl Trifluoromethanesulfonate 25G ₹9100 2022-05-26 Buy
Sigma-Aldrich(India) 226149 tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98% 1G ₹1634.58 2022-06-14 Buy
Sigma-Aldrich(India) 226149 tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98% 5G ₹4546.5 2022-06-14 Buy
Sigma-Aldrich(India) 226149 tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98% 25G ₹16064.3 2022-06-14 Buy
Sigma-Aldrich(India) 8.18313 tert-Butyldimethylsilyl trifluoromethanesulfonate for synthesis 25ML ₹19930 2022-06-14 Buy
Sigma-Aldrich(India) 56563 tert-Butyldimethylsilyl trifluoromethanesulfonate for GC derivatization, LiChropur?, ≥98.0% (T) 10ML ₹24616.05 2022-06-14 Buy
SRL 52573 tert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98% 5ml ₹1600 2022-05-26 Buy
SRL 52573 tert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98% 25mL ₹6820 2022-05-26 Buy
SRL 52573 tert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98% 100mL ₹19090 2022-05-26 Buy

Properties

Melting point :<0°C
Boiling point :65-67 °C12 mm Hg(lit.)
Density :1.151 g/mL at 25 °C(lit.)
refractive index :n20/D 1.385(lit.)
Flash point :98 °F
storage temp. :2-8°C
solubility :Slightly miscible with chloroform.
form :Fuming Liquid
Specific Gravity :1.151
color :Clear colorless to yellow
Water Solubility :DECOMPOSES
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :2370068
Stability :Moisture Sensitive
InChIKey :WLLIXJBWWFGEHT-UHFFFAOYSA-N
CAS DataBase Reference :69739-34-0(CAS DataBase Reference)
NIST Chemistry Reference :Tert-butyldimethylsilyl trifluoromethanesulfonate(69739-34-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

tert-Butyldimethylsilyl trifluoromethanesulfonate is involved in the introduction of a bulky tert-butyl dimethylsilyl group onto a cis-bis(alkenyl)oxirane used in Cope rearrangement. It is associated with a thiolane and promotes the chalcogenide-Morita-Baylis-Hillman reaction. Further, it is used as a highly reactive silylating agent. In addition to this, it is used to prepare enol silyl ethers by reacting with ketones and lactones.

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