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Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester

CAS No.: 69739-34-0

Chemical Name:: Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester

Synonyms: TBS-OTF;tbdms-otf;TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TERT-BUTYLDIMETHYLSILYL TRIFLATE;TBDMS TRIFLATE;TBS Triflate;tert-butyldimethylsilyl ester;TBMDS-OTF;t-Butyldimethylsilyl triflate;T-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE

CBNumber:: CB5192348

Molecular Formula:: C7H15F3O3SSi

Molecular Weight:: 264.34

MOL File:: 69739-34-0.mol

MSDS File:: SDS

Modify Date:: 2024/4/10 13:06:19

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Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Properties

Melting point	<0°C
Boiling point	65-67 °C12 mm Hg(lit.)
Density	1.151 g/mL at 25 °C(lit.)
refractive index	n20/D 1.385(lit.)
Flash point	98 °F
storage temp.	2-8°C
solubility	Slightly miscible with chloroform.
form	Fuming Liquid
Specific Gravity	1.151
color	Clear colorless to yellow
Water Solubility	DECOMPOSES
Sensitive	Moisture Sensitive
Hydrolytic Sensitivity	8: reacts rapidly with moisture, water, protic solvents
BRN	2370068
Stability	Moisture Sensitive
InChIKey	WLLIXJBWWFGEHT-UHFFFAOYSA-N
CAS DataBase Reference	69739-34-0(CAS DataBase Reference)
NIST Chemistry Reference	Tert-butyldimethylsilyl trifluoromethanesulfonate(69739-34-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS07

Signal word

Danger

Hazard statements

H226-H314-H335

Precautionary statements

P210-P233-P240-P280-P303+P361+P353-P305+P351+P338

Hazard Codes

C,F

Risk Statements

10-34-37

Safety Statements

26-36/37/39-45-25-16

RIDADR

UN 2920 8/PG 2

WGK Germany

10-21

Hazard Note

Flammable/Corrosive

TSCA

HazardClass

PackingGroup

III

HS Code

29310095

NFPA 704

	2
3		0

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester price More Price(13)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	226149	tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%	69739-34-0	1G	₹1634.58	2022-06-14	Buy
Sigma-Aldrich(India)	8.18313	tert-Butyldimethylsilyl trifluoromethanesulfonate for synthesis	69739-34-0	25ML	₹19930	2022-06-14	Buy
Sigma-Aldrich(India)	56563	tert-Butyldimethylsilyl trifluoromethanesulfonate for GC derivatization, LiChropur?, ≥98.0% (T)	69739-34-0	10ML	₹24616.05	2022-06-14	Buy
Sigma-Aldrich	226149	tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%	69739-34-0	5G	₹4546.5	2022-06-14	Buy
Sigma-Aldrich(India)	226149	tert-Butyldimethylsilyl trifluoromethanesulfonate reagent grade, 98%	69739-34-0	5G	₹4546.5	2022-06-14	Buy

Product number	Packaging	Price	Buy
226149	1G	₹1634.58	Buy
8.18313	25ML	₹19930	Buy
56563	10ML	₹24616.05	Buy
226149	5G	₹4546.5	Buy
226149	5G	₹4546.5	Buy

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow fuming liquid

Physical properties

bp 60°C/7 mmHg; colorless oil, d 1.151 g cm?3. Solubility: sol most organic solvents such as pentane, CH2Cl2, etc.

Uses

TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is a highly reactive silylating agent and lewis acid capable of converting primary, secondary and tertiary alcohols to their respectctive TBDMS. TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is also used to covert ketones and lactones into their enol silyl ethers.

Preparation

to 24 g (0.16 mol) of t-butyldimethylchlorosilane at 23°C under argon is added 14 mL (0.16 mol) of trifluoromethanesulfonic acid dropwise. The solution is heated at 60°C for 10 h, at which time no further hydrogen chloride evolves (removed through a bubbler). The resulting product is distilled under reduced pressure: 34 g (80% yield) of TBDMS triflate; bp 60°C/7 mmHg.

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Preparation Products And Raw materials

Raw materials

Heptane tert-Butyldimethylsilyl chloride Trifluoromethanesulfonic acid

Preparation Products

trans-3,4-Difluorocinnamic acid TERT-BUTYLDIMETHYLSILANOL (3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE 6-(4-{2-[3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methylene-cyclohexylidene]-ethylidene}-7a-methyl-octahydro-inden-1-yl)-2-methyl-heptan-2-ol 40-O-[2-(t-butyldimethylsilyl)oxy]ethyl rapamycin

(4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE Silane, (1,1-dimethylethyl)dimethyl[(1-methylene-2-propenyl)oxy]- ((1-(4-bromophenyl)hexyl)oxy)(tert-butyl)dimethylsilane(WXC06094) R-2-[[[(1,1-diMethylethyl)diMethylsilyl]oxy] diphenylMethyl]-Pyrrolidine

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Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Suppliers

Global( 426)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
SAGAR LIFE SCIENCES PVT LTD	+91-8770359041 +91-8770359041	Gujarat, India	79	58	Inquiry
ORGANO FINE CHEMICALS	+91-91-22-42128300 +91-2242128300	Mumbai, India	258	58	Inquiry
Vardhaman P Golechha	9704422000	Telangana, India	294	58	Inquiry
SURVIVAL TECHNOLOGIES LIMITED	+91 8108285261	Gujarat, India	294	58	Inquiry
GLP Pharma Standards	+91 9866074638	Hyderabad, India	1644	58	Inquiry
VGS SYNTHESIS PRIVATE LIMITED	+91-9866975588 +91-9866975588	Hyderabad, India	1818	58	Inquiry
Innovative Labs	+91-9885794886 +91-9885794886	Telangana, India	219	58	Inquiry
Covalent Incorporation	+91-9033666099 +91-9033666099	Gujarat, India	50	58	Inquiry
Azole Rasayanas India Private Limited	91-40-29707735	Hyderabad, India	684	58	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry

Supplier	Advantage
SAGAR LIFE SCIENCES PVT LTD	58
ORGANO FINE CHEMICALS	58
Vardhaman P Golechha	58
SURVIVAL TECHNOLOGIES LIMITED	58
GLP Pharma Standards	58
VGS SYNTHESIS PRIVATE LIMITED	58
Innovative Labs	58
Covalent Incorporation	58
Azole Rasayanas India Private Limited	58
CLEARSYNTH LABS LTD.	58

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Spectrum

Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester(69739-34-0)¹HNMR Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester(69739-34-0)Raman Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester(69739-34-0)FT-IR

69739-34-0(Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester)Related Search:

Trifluoromethanesulfonic acid TERT-BUTYL VINYL ETHER Butylated hydroxyanisole tert-Butyldimethylsilyl chloride tert-Butylchlorodiphenylsilane

TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE Trifluoromethanesulfonic anhydride Trifluoroacetic anhydride TERT-BUTYL PROPIOLATE Trifluoromethanesulfonic acid difluoromethyl ester

TERT-BUTYLMETHOXYPHENYLSILYL BROMIDE 2-Methyl-N-(thiophen-2-ylMethyl)propan-2-aMine tert-Butyldiphenylsilane tert-Butyl(3-fluorophenoxy)dimethylsilane Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester

ETHYLDIMETHYLSILANE T-BUTYLDIMETHYLSILANE Trifluoromethane

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Methanesulfonic acid, trifluoro-, (1,1-dimethylethyl)dimethylsilyl ester t-butyldimethylsilyltrifluormethansulfonate t-Butylmethylsilyl triflate TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester SILANE TBM2 TRIFLATE Silane TBM2 triflate, TBDMS triflate, Trifluoromethanesulfonic acid tert-butyldimethylsilylester (R)-4-isopropyl-5,5-diphenyloxazolidine-2-thione Methanesulfonic acid, trifluoro-, (1,1-diMethylethyl)diMethylsilyl ester (9CI) tert-ButyldiMethylsilyl trifluoroMethanesulfonate reagent grade, 98% Methanesulfonic acid, 1,1,1-trifluoro-, (1,1-dimethylethyl)dimethylsilyl ester tert-Butyldimethyl(trifluoromethylsulfonyloxy)silane tert-Butyldimethylsilyl trifluoromethanesulfonate,98% BUTYLDIMETHYLSILYLTRIFLUOROMETHANESULFONATE tert-Butyldimethylsilyl trifluoromethanesulphonateTBDMS triflate tert-Butyldimethylsilyl trifluoromethanesulphonate 97+% tert-ButyldiMethylsilyl trifluoroMethanesulfonate, 98% 5ML (1,1-DiMethylethyl)diMethylsilyl TrifluoroMethanesulfonate tert-ButyldiM TrifluoroMethanesulfonic Acid (1,1-DiMethylethyl)diMethylsilyl ester tert-Butyldimethylsilyl Triflate TBDMS Triflate Trifluoromethanesulfonic Acid tert-Butyldimethylsilyl Ester T-BUTYLDIMETHYLSILYLTRIFLUOROMETHANE-SULPHONATE TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULPHONATE TRIFLUOROMETHANESULFONIC ACID TERT-BUTYLDIMETHYLSILYL ESTER tert-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE 98% tert-Butyldimethylsilyl trifluoromethane tert-Butyldimethylsilyl trifluoromethanesulphonate 98% tert-Butyldimethylsilyltrifluoromethanesulphonate98% tert-Buthyldimethylsilyl trifluoromethane sulfonate TRIFLUOROMETHANESULFONIC ACID*T-BUTYLDIM ETHYLSILYL t-Butyldimethylsilyltrifluoromethanesulfonate,98% ert-Butyldimethylsilyl Trifluoromethanesulfonate tert-Butyldimethylsilyl trifluoromethanesulfonate 1,1,1-trifluoro-Methanesulfonic acid (1,1-dimethylethyl)dimethylsilyl ester tert-Butyldimethylsilyl trifluoromethanesulfonate, for synthesis Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester ISO 9001：2015 REACH tert-Butyldimethylsilyl Trifluoromethanesulfonate (TBDMS triflate) extrapure, 98% t-Butyldimethylsilyl triflate T-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE TBDMS TRIFLATE TBMDS-OTF TBS-OTF TERT-BUTYLDIMETHYLSILYL TRIFLATE TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE tbdms-otf tert-butyldimethylsilyl ester TBS Triflate (1,1-Dimethylethyl)dimethylsilyl 1,1,1-trifluoromethanesulfonate TERT-BUTYLDIMETHYLSILYL TRIFLUROMETHANESULFONATE(TBDMS-TRIFLATE) ter-Butyldimethylsilyltrifluoromethane sulfonate Everolimus Impurity 40 Tert-butyldimethylsilyl Trifluoromethanesulfonate (Rosuvastatin Intermediate) tert-butyldimethylsilyl trifluromethanesulfonate 69739-34-0 69739-37-0 C7H15F3O3SSi CH33SiCH32OSO2CF3 CH33CSiCH32SO3CF3 C7H15F3O3S4