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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Nitro compounds >Bromonitromethane

Bromonitromethane

Bromonitromethane Structure
  • ₹1603.6 - ₹5201.15
  • Product name: Bromonitromethane
  • CAS: 563-70-2
  • MF: CH2BrNO2
  • MW: 139.94
  • EINECS:209-258-0
  • MDL Number:MFCD00007401
  • Synonyms:BROMONITROMETHANE;Bromonitromethane, tech.;bromonitro-methan ;Methane, bromonitro-;nitrobromomethane ;Bromonitromethane, 90%,tech.;Nitromethyl bromide;BroMonitroMethane, tech., 90% 10GR
2 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 10G
  • ManufacturerSigma-Aldrich(India)
  • Product number255858
  • Product descriptionBromonitromethane technical grade, 90%
  • Packaging1G
  • Price₹1603.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number255858
  • Product descriptionBromonitromethane technical grade, 90%
  • Packaging10G
  • Price₹5201.15
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 255858 Bromonitromethane technical grade, 90% 1G ₹1603.6 2022-06-14 Buy
Sigma-Aldrich(India) 255858 Bromonitromethane technical grade, 90% 10G ₹5201.15 2022-06-14 Buy

Properties

Melting point :-28 °C
Boiling point :146-148 °C/750 mmHg (lit.)
Density :2.007 g/mL at 25 °C (lit.)
refractive index :1.485-1.495
Flash point :4°C
solubility :Chloroform (Soluble), DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Slig
pka :7.22±0.29(Predicted)
form :Liquid
color :Clear yellow
Stability :Light Sensitive, Volatile
CAS DataBase Reference :563-70-2(CAS DataBase Reference)
EPA Substance Registry System :Methane, bromonitro- (563-70-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Bromonitromethane has been used:in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesisin preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reactionin diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramolecular-alkylation strategy

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