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ChemicalBook > Product Catalogue >Catalyst and Auxiliary >Precious Metal Catalysts >Dess-Martin periodinane

Dess-Martin periodinane

Dess-Martin periodinane Structure
  • ₹280 - ₹167202.95
  • Product name: Dess-Martin periodinane
  • CAS: 87413-09-0
  • MF: C13H13IO8
  • MW: 424.14
  • EINECS:672-328-8
  • MDL Number:MFCD00130127
  • Synonyms:1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV;1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M;Dess-Martin periodinane solution;Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one;Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester;Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal;1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one;1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane)
18 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India
  • SRL

Package

  • 1G
  • 5ML
  • 5G
  • 25ML
  • 25G
  • 50G
  • 250G
  • 250ML
  • 1Gms
  • 5Gms
  • 25Gms
  • 100Gms
  • ManufacturerTCI Chemicals (India)
  • Product numberD2045
  • Product descriptionDess-Martin Periodinane
  • Packaging1G
  • Price₹3900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2045
  • Product descriptionDess-Martin Periodinane
  • Packaging5G
  • Price₹5500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD4477
  • Product descriptionDess-Martin Periodinane (8-12% in Dichloromethane)
  • Packaging25ML
  • Price₹10600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2045
  • Product descriptionDess-Martin Periodinane
  • Packaging25G
  • Price₹12100
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD4477
  • Product descriptionDess-Martin Periodinane (8-12% in Dichloromethane)
  • Packaging250ML
  • Price₹52300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number559873
  • Product descriptionDess-Martin periodinane solution 0.3?M in methylene chloride
  • Packaging5ML
  • Price₹3422.48
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274623
  • Product descriptionDess-Martin periodinane 97%
  • Packaging5G
  • Price₹12405.45
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number559873
  • Product descriptionDess-Martin periodinane solution 0.3?M in methylene chloride
  • Packaging25ML
  • Price₹16945.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274623
  • Product descriptionDess-Martin periodinane 97%
  • Packaging25G
  • Price₹49221.28
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274623
  • Product descriptionDess-Martin periodinane 97%
  • Packaging50G
  • Price₹73804.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274623
  • Product descriptionDess-Martin periodinane 97%
  • Packaging250G
  • Price₹167202.95
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15779-18
  • Product descriptionDess-Martin periodinane
  • Packaging50g
  • Price₹71460
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15779-06
  • Product descriptionDess-Martin periodinane
  • Packaging5g
  • Price₹12150
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15779-03
  • Product descriptionDess-Martin periodinane
  • Packaging1g
  • Price₹2478
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number43767
  • Product descriptionDess Martin Periodinane extrapure, 97%
  • Packaging1Gms
  • Price₹280
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number43767
  • Product descriptionDess Martin Periodinane extrapure, 97%
  • Packaging5Gms
  • Price₹650
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D2045 Dess-Martin Periodinane 1G ₹3900 2022-05-26 Buy
TCI Chemicals (India) D2045 Dess-Martin Periodinane 5G ₹5500 2022-05-26 Buy
TCI Chemicals (India) D4477 Dess-Martin Periodinane (8-12% in Dichloromethane) 25ML ₹10600 2022-05-26 Buy
TCI Chemicals (India) D2045 Dess-Martin Periodinane 25G ₹12100 2022-05-26 Buy
TCI Chemicals (India) D4477 Dess-Martin Periodinane (8-12% in Dichloromethane) 250ML ₹52300 2022-05-26 Buy
Sigma-Aldrich(India) 559873 Dess-Martin periodinane solution 0.3?M in methylene chloride 5ML ₹3422.48 2022-06-14 Buy
Sigma-Aldrich(India) 274623 Dess-Martin periodinane 97% 5G ₹12405.45 2022-06-14 Buy
Sigma-Aldrich(India) 559873 Dess-Martin periodinane solution 0.3?M in methylene chloride 25ML ₹16945.43 2022-06-14 Buy
Sigma-Aldrich(India) 274623 Dess-Martin periodinane 97% 25G ₹49221.28 2022-06-14 Buy
Sigma-Aldrich(India) 274623 Dess-Martin periodinane 97% 50G ₹73804.85 2022-06-14 Buy
Sigma-Aldrich(India) 274623 Dess-Martin periodinane 97% 250G ₹167202.95 2022-06-14 Buy
ALFA India ALF-L15779-18 Dess-Martin periodinane 50g ₹71460 2022-05-26 Buy
ALFA India ALF-L15779-06 Dess-Martin periodinane 5g ₹12150 2022-05-26 Buy
ALFA India ALF-L15779-03 Dess-Martin periodinane 1g ₹2478 2022-05-26 Buy
SRL 43767 Dess Martin Periodinane extrapure, 97% 1Gms ₹280 2022-05-26 Buy
SRL 43767 Dess Martin Periodinane extrapure, 97% 5Gms ₹650 2022-05-26 Buy

Properties

Melting point :130-133 °C (lit.)
Boiling point :40 °C
Density :1.369 g/mL at 25 °C
Flash point :>221 °F
storage temp. :-20°C
solubility :Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form :Liquid
color :Colorless to light yellow
Sensitive :Light Sensitive
Merck :14,2933
BRN :4548207
Stability :Light Sensitive
InChI :InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey :NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES :I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference :87413-09-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

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