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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic zinc >Diethylzinc

Diethylzinc

Diethylzinc Structure
  • ₹4130 - ₹59007.08
  • Product name: Diethylzinc
  • CAS: 557-20-0
  • MF: C4H10Zn
  • MW: 123.51
  • EINECS:209-161-3
  • MDL Number:MFCD00009021
  • Synonyms:(C2H5)2Zn;ZINCDIETHYL;Zinc ethide;ZINC ETHYL;DIETHYLZINC, CYLINDER WITH 100 G;DIETHYLZINC SOLUTION, IN TOLUENE (1.1 M);DIETHYLZINC, 15 WT. % (1.1M) SOLUTION IN TOLUENE;DIETHYLZINC SOLUTION, ~1 M SOLUTION IN H EXANE
11 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 25g
  • 100ML
  • 100g
  • 500ML
  • 800G
  • 800ML
  • ManufacturerALFA India
  • Product numberALF-089038-14
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes
  • Packaging25g
  • Price₹4130
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-089038-22
  • Product descriptionDiethylzinc, nominally 15% w/w in hexanes
  • Packaging100g
  • Price₹11358
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-039564-22
  • Product descriptionDiethylzinc, 96%
  • Packaging100g
  • Price₹13438
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD3214
  • Product descriptionDiethylzinc (ca. 15% in Hexane, ca. 1mol/L)
  • Packaging100ML
  • Price₹10600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD3214
  • Product descriptionDiethylzinc (ca. 15% in Hexane, ca. 1mol/L)
  • Packaging500ML
  • Price₹20500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number296112
  • Product descriptionDiethylzinc solution 1.0?M in hexanes
  • Packaging100ML
  • Price₹14624.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number406023
  • Product descriptionDiethylzinc solution 1.0?M in heptane
  • Packaging100ML
  • Price₹18359.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number406023
  • Product descriptionDiethylzinc solution 1.0?M in heptane
  • Packaging800ML
  • Price₹19290.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number220809
  • Product descriptionDiethylzinc solution 15?wt. % in toluene
  • Packaging100G
  • Price₹26012.48
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number296112
  • Product descriptionDiethylzinc solution 1.0?M in hexanes
  • Packaging800ML
  • Price₹42109.25
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number220809
  • Product descriptionDiethylzinc solution 15?wt. % in toluene
  • Packaging800G
  • Price₹59007.08
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-089038-14 Diethylzinc, nominally 15% w/w in hexanes 25g ₹4130 2022-05-26 Buy
ALFA India ALF-089038-22 Diethylzinc, nominally 15% w/w in hexanes 100g ₹11358 2022-05-26 Buy
ALFA India ALF-039564-22 Diethylzinc, 96% 100g ₹13438 2022-05-26 Buy
TCI Chemicals (India) D3214 Diethylzinc (ca. 15% in Hexane, ca. 1mol/L) 100ML ₹10600 2022-05-26 Buy
TCI Chemicals (India) D3214 Diethylzinc (ca. 15% in Hexane, ca. 1mol/L) 500ML ₹20500 2022-05-26 Buy
Sigma-Aldrich(India) 296112 Diethylzinc solution 1.0?M in hexanes 100ML ₹14624.58 2022-06-14 Buy
Sigma-Aldrich(India) 406023 Diethylzinc solution 1.0?M in heptane 100ML ₹18359.2 2022-06-14 Buy
Sigma-Aldrich(India) 406023 Diethylzinc solution 1.0?M in heptane 800ML ₹19290.15 2022-06-14 Buy
Sigma-Aldrich(India) 220809 Diethylzinc solution 15?wt. % in toluene 100G ₹26012.48 2022-06-14 Buy
Sigma-Aldrich(India) 296112 Diethylzinc solution 1.0?M in hexanes 800ML ₹42109.25 2022-06-14 Buy
Sigma-Aldrich(India) 220809 Diethylzinc solution 15?wt. % in toluene 800G ₹59007.08 2022-06-14 Buy

Properties

Melting point :−28 °C(lit.)
Boiling point :98 °C
Density :1.205 g/mL at 25 °C(lit.)
vapor pressure :16hPa at 20℃
refractive index :n20/D 1.498(lit.)
Flash point :45 °F
storage temp. :0-6°C
solubility :reacts with H2O; msc ethyl ether,petroleum ether, benzene
form :Solution
Specific Gravity :0.740
color :Slightly turbid light brown-gray
Water Solubility :REACTS VIOLENTLY
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,3131
BRN :3587207
Dielectric constant :2.5(20℃)
CAS DataBase Reference :557-20-0(CAS DataBase Reference)
NIST Chemistry Reference :Diethylzinc(557-20-0)
EPA Substance Registry System :Zinc, diethyl- (557-20-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

It is used in organic synthesis as a source of the ethyl carbanion in addition reactions to carbonyl groups. It is commonly used in combination with diiodomethane as a Simmons-Smith reagent to convert alkenes into cyclopropyl groups. Employed together with a Rh (I) catalyst to prepare α-trifluoromethyl ketones from α,β-unsaturated ketones. Also used a catalyst, an aerospace fuel, and a deacidification agent in paper manufacturing.

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