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ChemicalBook > Product Catalogue >Organic Chemistry >Inorganic acid Esters >Triethyl phosphite

Triethyl phosphite

Triethyl phosphite Structure
  • ₹1948.5 - ₹7166.15
  • Product name: Triethyl phosphite
  • CAS: 122-52-1
  • MF: C6H15O3P
  • MW: 166.16
  • EINECS:204-552-5
  • MDL Number:MFCD00009084
  • Synonyms:triethyl phosphite94%;Phosphorous acid triethyl;TRIETHYL PHOSPHITE HP;(C2H5O)3P;Ethyl phosphite, (EtO)3P;fosforyntrojetylowy ;Phosphorus ether;Triethoxyphosphine
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Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 5ML
  • 100ML
  • 250ML
  • 500ML
  • 1L
  • ManufacturerSigma-Aldrich(India)
  • Product numberT61204
  • Product descriptionTriethyl phosphite 98%
  • Packaging100ML
  • Price₹1948.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT61204
  • Product descriptionTriethyl phosphite 98%
  • Packaging5ML
  • Price₹1948.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.00549
  • Product descriptionTriethylphosphite for synthesis
  • Packaging100ML
  • Price₹2430
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.00549
  • Product descriptionTriethylphosphite for synthesis
  • Packaging500ML
  • Price₹6280
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT61204
  • Product descriptionTriethyl phosphite 98%
  • Packaging500ML
  • Price₹6992.95
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT61204
  • Product descriptionTriethyl phosphite 98%
  • Packaging1L
  • Price₹7166.15
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number T 2125
  • Product descriptionTriethyl phosphite 98%
  • Packaging250ML
  • Price₹2691
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 2125
  • Product descriptionTriethyl phosphite 98%
  • Packaging500mL
  • Price₹5103
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) T61204 Triethyl phosphite 98% 100ML ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) T61204 Triethyl phosphite 98% 5ML ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 8.00549 Triethylphosphite for synthesis 100ML ₹2430 2022-06-14 Buy
Sigma-Aldrich(India) 8.00549 Triethylphosphite for synthesis 500ML ₹6280 2022-06-14 Buy
Sigma-Aldrich(India) T61204 Triethyl phosphite 98% 500ML ₹6992.95 2022-06-14 Buy
Sigma-Aldrich(India) T61204 Triethyl phosphite 98% 1L ₹7166.15 2022-06-14 Buy
ottokemi T 2125 Triethyl phosphite 98% 250ML ₹2691 2022-05-26 Buy
ottokemi T 2125 Triethyl phosphite 98% 500mL ₹5103 2022-05-26 Buy

Properties

Melting point :-112°C
Boiling point :65 °C
Density :0.969 g/mL at 25 °C(lit.)
vapor pressure :<6 hPa (20 °C)
refractive index :n20/D 1.413(lit.)
Flash point :130 °F
storage temp. :Flammables area
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :liquid
color :colorless
Specific Gravity :0.969
Odor :characteristic, obnoxious, phosphiteodor
explosive limit :3.75-42.5%(V)
Water Solubility :slightly soluble
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
BRN :956578
Dielectric constant :10.9(65℃)
Stability :Air Sensitive, Moisture Sensitive
CAS DataBase Reference :122-52-1(CAS DataBase Reference)
NIST Chemistry Reference :Phosphorous acid, triethyl ester(122-52-1)
EPA Substance Registry System :Triethyl phosphite (122-52-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Description

Triethyl phosphite is used as a ligand in organometallic chemistry and as a reagent in organic synthesis. It is used as reference to phosphoric acid standard in P NMR spectroscopy. It acts as a reducing agent to prepare 2-phenylindazole from o-nitrobenzylidineaniline as well as reacts with electrophiles to get phosphonates. It forms a stable complex with copper(I) iodide. It finds application in a modified Staudinger reaction for the alkyl bromide to an amine through the azide. Further, it is also used in the preparation of 3-phenyl-2-substituted indoles by reacting with beta-nitro styrenes.

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