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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Triisopropyl phosphite

Triisopropyl phosphite

Triisopropyl phosphite Structure
  • ₹3128.43 - ₹13920.95
  • Product name: Triisopropyl phosphite
  • CAS: 116-17-6
  • MF: C9H21O3P
  • MW: 208.24
  • EINECS:204-130-0
  • MDL Number:MFCD00008874
  • Synonyms:PHOSPHOROUS ACID TRIISOPROPYL ESTER;phosphorous acid tris(1-methylethyl) ester;Phosphorus isopropoxide;Phosphorus triisopropoxide;di-tert-butyl isopropyl phosphite;Phosphite isopropyl ester;Tris(propan-2-yl) phosphite;Triisopropyl phosphite,90%,tech.
2 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 100ML
  • 500ML
  • ManufacturerSigma-Aldrich(India)
  • Product numberT67806
  • Product descriptionTriisopropyl phosphite 95%
  • Packaging100ML
  • Price₹3128.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT67806
  • Product descriptionTriisopropyl phosphite 95%
  • Packaging500ML
  • Price₹13920.95
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) T67806 Triisopropyl phosphite 95% 100ML ₹3128.43 2022-06-14 Buy
Sigma-Aldrich(India) T67806 Triisopropyl phosphite 95% 500ML ₹13920.95 2022-06-14 Buy

Properties

Boiling point :63-64 °C11 mm Hg(lit.)
Density :0.844 g/mL at 25 °C(lit.)
vapor pressure :<2 mm Hg ( 20 °C)
refractive index :n20/D 1.411(lit.)
Flash point :154 °F
storage temp. :-20°C
form :Liquid
Specific Gravity :0.844
color :Clear
Water Solubility :Insoluble
Sensitive :Moisture Sensitive
BRN :1701528
LogP :2
CAS DataBase Reference :116-17-6(CAS DataBase Reference)
NIST Chemistry Reference :Phosphorous acid, tris(1-methylethyl) ester(116-17-6)
EPA Substance Registry System :Phosphorous acid, tris(1-methylethyl) ester (116-17-6)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
Precautionary statements:
P302+P352 IF ON SKIN: wash with plenty of soap and water.

Description

Triisopropyl phosphite can be used as a reactant:
  • With Ru-based indenylidene complexes to form 1st generation complexes for metathesis reactions.
  • In Perkow-type reaction to synthesize compounds containing polarized carbon-carbon double bonds.
  • For the synthesis of phosphonohydrazines by reacting with arylamines and isoamyl nitrite.

It can also be used as an alternative to triphenylphosphine in Mitsunobu reaction to facilitate the isolation of products.

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