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Triisopropyl phosphite

Triisopropyl phosphite Structure
CAS No.
116-17-6
Chemical Name:
Triisopropyl phosphite
Synonyms
TRIISOPROPYL PHOS;Isopropyl phosphite;Triisopropyl phosphi;TRISOPROPYL PHOSHITE;tri-2-propylphosphite;tri-isopropylphosphit;TRI-I-PROPYLPHOSPHITE;Tri-2-propyl phosphite;TRIISOPROPYL PHOSPHITE;Triisopropoxyphosphine
CBNumber:
CB6674045
Molecular Formula:
C9H21O3P
Molecular Weight:
208.24
MOL File:
116-17-6.mol
MSDS File:
SDS
Modify Date:
2024/5/26 16:20:14

Triisopropyl phosphite Properties

Boiling point 63-64 °C11 mm Hg(lit.)
Density 0.844 g/mL at 25 °C(lit.)
vapor pressure <2 mm Hg ( 20 °C)
refractive index n20/D 1.411(lit.)
Flash point 154 °F
storage temp. -20°C
form Liquid
Specific Gravity 0.844
color Clear
Water Solubility Insoluble
Sensitive Moisture Sensitive
BRN 1701528
LogP 2
CAS DataBase Reference 116-17-6(CAS DataBase Reference)
NIST Chemistry Reference Phosphorous acid, tris(1-methylethyl) ester(116-17-6)
EPA Substance Registry System Phosphorous acid, tris(1-methylethyl) ester (116-17-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H301-H315
Precautionary statements  P301+P310+P330-P302+P352
Hazard Codes  T,F
Risk Statements  25-38-68
Safety Statements  37-46-45-36/37
RIDADR  UN 3278 6.1/PG 3
WGK Germany  3
RTECS  TH2800000
1-10
Hazard Note  Toxic/Flammable/Moisture Sensitive/
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29209090
NFPA 704
2
2 0

Triisopropyl phosphite price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T67806 Triisopropyl phosphite 95% 116-17-6 100ML ₹3128.43 2022-06-14 Buy
Sigma-Aldrich(India) T67806 Triisopropyl phosphite 95% 116-17-6 500ML ₹13920.95 2022-06-14 Buy
Product number Packaging Price Buy
T67806 100ML ₹3128.43 Buy
T67806 500ML ₹13920.95 Buy

Triisopropyl phosphite Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid; characteristic odor. Miscible with most common organic solvents; insoluble in water; hydrolyzes slowly in water; exposure to air should be minimum; high thermal stability. Combustible.

Uses

Triisopropyl phosphite can be used as a reactant:

  • With Ru-based indenylidene complexes to form 1st generation complexes for metathesis reactions.
  • In Perkow-type reaction to synthesize compounds containing polarized carbon-carbon double bonds.
  • For the synthesis of phosphonohydrazines by reacting with arylamines and isoamyl nitrite.

It can also be used as an alternative to triphenylphosphine in Mitsunobu reaction to facilitate the isolation of products.

Purification Methods

Distil it from sodium, under vacuum, through a column packed with glass helices. (This removes any dialkyl phosphonate.) [Ford-Moore & Williams J Chem Soc 1465 1947, Arbuzov Chem Ber 38 1171 1905, see Verkade & Coskren in Organo Phosphorus Compound (Kosolapoff & Maier eds) Wiley Vol 2 pp 1-187 1972, Beilstein 1 IV 1476.]

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PHOSPHOROUS ACID TRIISOPROPYL ESTER phosphorous acid tris(1-methylethyl) ester Phosphorus isopropoxide Phosphorus triisopropoxide di-tert-butyl isopropyl phosphite Phosphite isopropyl ester Tris(propan-2-yl) phosphite Triisopropyl phosphite,90%,tech. Triisopropyl phosphite,96% TRIISOPROPYL PHOS Triisopropyl phosphi Isopropyl phosphite Tri-iso-propylphosphite, min.94% Tri(prop-2-yl) phosphite Isopropyl phosphite, ((C3H7O)3P) Isopropyl phosphite, tri- isopropylphosphite((c3h7o)3p) Tri-2-propyl phosphite tri-2-propylphosphite tri-isopropylphosphit Triisopropyl phosphite tech. TRISOPROPYL PHOSHITE Triisopropyl phosphite, 90+% Triisopropylphosphite, 95+% TRIISOPROPYL PHOSPHITE TRI-ISO-PROPYL PHOSPHONATE Triisopropoxyphosphine TRI-I-PROPYLPHOSPHITE Tri-i-propylphosphite,min.94% TRIISOPROPYLPHOSPHITE,TECHNICAL Tripropan-2-yl phosphite Tri-i-propylphosphite, min. 94% Phosphorous acid triisopropyl Medronic acid impurity A CRS Triisopropyl Phosphate Acid Medronic Acid EP Impurity A 116-17-6 C9H21O3P CH32CHO3P Building Blocks Phosphorus Compounds Organic Phosphates/Phosphites Organic Building Blocks organophosphorus compound Building Blocks Chemical Synthesis Organic Building Blocks Organic Phosphates/Phosphites Phosphorus Compounds Organic Building Blocks Organic Phosphates/Phosphites Phosphorus Compounds