Phenoxyacetyl chloride
- CAS No.
- 701-99-5
- Chemical Name:
- Phenoxyacetyl chloride
- Synonyms
- SKL1266;AKOS BBS-00003927;Acyl chloride kind;Phenoxyacetyl chlori;phenoxy-acetylchlorid;PHENOXYACETYL CHLORIDE;LABOTEST-BB LT00643586;Acetylchloride,phenoxy-;Phenyloxyacetyl chloride;PhenoxyacetylChloride>
- CBNumber:
- CB0227245
- Molecular Formula:
- C8H7ClO2
- Molecular Weight:
- 170.59
- MOL File:
- 701-99-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 100-100.5 °C |
|---|---|
| Boiling point | 225-226 °C (lit.) |
| Density | 1.235 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 227 °F |
| storage temp. | Store at RT. |
| form | Liquid |
| color | Clear slightly yellow to brown |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| BRN | 607585 |
| CAS DataBase Reference | 701-99-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Acetyl chloride, phenoxy-(701-99-5) |
| EPA Substance Registry System | Acetyl chloride, phenoxy- (701-99-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314-H335 | |||||||||
| Precautionary statements | P261-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 14-34-36/37 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-19 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29189090 | |||||||||
| NFPA 704 |
|
Phenoxyacetyl chloride price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 158623 | Phenoxyacetyl chloride 98% | 701-99-5 | 10G | ₹1667.05 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 158623 | Phenoxyacetyl chloride 98% | 701-99-5 | 50G | ₹3723.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 158623 | Phenoxyacetyl chloride 98% | 701-99-5 | 250G | ₹13076.6 | 2022-06-14 | Buy |
| TCI Chemicals (India) | P0113 | Phenoxyacetyl Chloride min. 98.0 % | 701-99-5 | 25G | ₹1700 | 2022-05-26 | Buy |
| TCI Chemicals (India) | P0113 | Phenoxyacetyl Chloride min. 98.0 % | 701-99-5 | 500G | ₹18400 | 2022-05-26 | Buy |
Phenoxyacetyl chloride Chemical Properties,Uses,Production
Chemical Properties
Colorless to brown liquid
Uses
Acylation of D- and DL-WV with phenoxyacetyl chloride, followed by cleavage of the t-butyl ester,afforded the penultimate penicilloic acids. Phenoxyacetyl chloride was used in the synthesis of series of macrocyclic bis-β-lactams, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester, N-protected guanosine derivatives, useful in RNA synthesis, phenyloxyketene, for cycloaddition to imines leading to β-lactams. Treatment of iminophosphoranes with phenoxyacetyl chloride afforded respectively the trans- and cis-3-(acylamino)-p-lactams. By the oxidative addition of stannous fluoride to allyliodide, with 1, 2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallylester, which is in turn converted into 2-deoxy-D-ribose. The 4-disubstituted P-lactams (4a-c and 6a-b) were prepared through the reaction of N,N-diphenylhydrazones and N-methyl-N-phenylhydrazones of ketones with phenoxyacetyl chloride/Et3N in dichloromethane.
Purification Methods
If it has no OH band in the IR then distil it in a vacuum, taking precautions for the moisture-sensitive compound. If it contains free acid (due to hydrolysis, OH bands in the IR), then add an equal volume of redistilled SOCl2, reflux for 2-3hours, evaporate and distil the residue in a vacuum as before. The amide has m 101o. [McElvain & Carney J Am Chem Soc 68 2592 1946, Beilstein 6 III 613.]
Phenoxyacetyl chloride Preparation Products And Raw materials
Phenoxyacetyl chloride Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Allchem Lifescience Pvt. Ltd | +919867655500 | Gujarat, India | 971 | 58 | Inquiry |
| Innovassynth Technologies (I) Ltd. | +91-2192260100 +91-7208872197 | Maharashtra, India | 118 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| ALLCHEM LIFESCIENCE PVT. LTD | +91 957 472 2211 | New Delhi, India | 322 | 58 | Inquiry |
| APAC Sourcing Solutions Ltd. | 91-124-4007103 | Haryana, India | 61 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29825 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
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