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TRIS(2-AMINOETHYL)AMINE

CAS No.: 4097-89-6

Chemical Name:: TRIS(2-AMINOETHYL)AMINE

Synonyms: TREN;TAEA;tri(2-aminoethyl)amine;tris(aminoethyl)amine;trenhp;Tris(2-aminoethyL;Tris(2-aMinoethyl)a;Trientine Impurity 5;Triaminotriethyl-amine;N1,N1-Bis(2-aminoethyl)

CBNumber:: CB0235693

Molecular Formula:: C6H18N4

Molecular Weight:: 146.23

MOL File:: 4097-89-6.mol

MSDS File:: SDS

Modify Date:: 2023/8/15 17:37:19

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TRIS(2-AMINOETHYL)AMINE Properties

Melting point	-16 °C
Boiling point	114 °C/15 mmHg (lit.)
Density	0.976 g/mL at 20 °C (lit.)
vapor density	5 (vs air)
vapor pressure	0.02 mm Hg ( 20 °C)
refractive index	n20/D 1.497(lit.)
Flash point	>230 °F
storage temp.	2-8°C
solubility	Chloroform (Sparingly), DMSO (Slightly)
form	saline suspension
pka	10.00±0.10(Predicted)
color	Clear yellow
Specific Gravity	0.977
Water Solubility	Miscible with water.
Sensitive	Hygroscopic
BRN	1739626
Stability	Stable. Hygroscopic. Absorbs carbon dioxide from the air. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference	4097-89-6(CAS DataBase Reference)
EPA Substance Registry System	1,2-Ethanediamine, N,N-bis(2-aminoethyl)- (4097-89-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS06

Signal word

Danger

Hazard statements

H301-H310-H314

Precautionary statements

P270-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338

Hazard Codes

T,Xi

Risk Statements

22-24-34-36/37/38-10

Safety Statements

26-36/37/39-45-16

RIDADR

UN 2922 8/PG 2

WGK Germany

RTECS

KH8587082

3-10-23

TSCA

Yes

HazardClass

6.1

PackingGroup

HS Code

29211990

Toxicity

mouse,LD50,oral,1800mg/kg (1800mg/kg),LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIAGASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA","Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 223, 1999.

NFPA 704

	1
4		1

TRIS(2-AMINOETHYL)AMINE price More Price(6)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	225630	Tris(2-aminoethyl)amine 96%	4097-89-6	10ML	₹2219.13	2022-06-14	Buy
Sigma-Aldrich(India)	225630	Tris(2-aminoethyl)amine 96%	4097-89-6	100ML	₹14516.33	2022-06-14	Buy
TCI Chemicals (India)	T1243	Tris(2-aminoethyl)amine min. 98.0 %	4097-89-6	5ML	₹1800	2022-05-26	Buy
TCI Chemicals (India)	T1243	Tris(2-aminoethyl)amine min. 98.0 %	4097-89-6	25ML	₹5400	2022-05-26	Buy
TCI Chemicals (India)	T1243	Tris(2-aminoethyl)amine min. 98.0 %	4097-89-6	100ML	₹15300	2022-05-26	Buy

Product number	Packaging	Price	Buy
225630	10ML	₹2219.13	Buy
225630	100ML	₹14516.33	Buy
T1243	5ML	₹1800	Buy
T1243	25ML	₹5400	Buy
T1243	100ML	₹15300	Buy

TRIS(2-AMINOETHYL)AMINE Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

Tris(2-aminoethyl)amine is a tetradentate chelating ligand and forms stable complexes with transition metals. It is also used as a carbon dioxide absorbent. Further, it acts as a reagent for cleavage of the fluorenylmethyloxycarbonyl (Fmoc) group in peptide synthesis. It reacts with aryl isocyanates and isothiocyanates to give tris-urea and -thiourea derivatives.

General Description

Tris(2-aminoethyl)amine (TREN) is a water soluble tripodal ligand that is majorly used in co-ordination chemistry. It has three aminoethylgroups that attach with the surface atoms to provide a scaffold assembly.

Hazard

A poison by ingestion and skin contact.

Safety Profile

A poison by ingestion and skin contact. When heated to decomposition it emits toxic vapors of NOx.

Purification Methods

For a separation from a mixture containing 62% TRIEN, see entry under triethylenetetramine. Also purify it by conversion to the hydrochloride (see below), recrystallise it and regenerate the free base [Xie & Hendrickson J Am Chem Soc 109 6981 1987]. [Beilstein 4 H 256, 4 II 695, 4 III 545, 4 IV 1250.]

TRIS(2-AMINOETHYL)AMINE Preparation Products And Raw materials

Raw materials

Congo Red Sodium hypochlorite Ammonium hydroxide Acrylamide 1,2-Dichloroethane

Hydrochloric acid Methanol Sodium hydroxide TRIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE

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Preparation Products

Tri(2-Fmoc-aminoethyl) amine

TRIS(2-AMINOETHYL)AMINE Suppliers

Global( 193)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Otto Chemie Pvt. Ltd.	+91 9820041841	Mumbai, India	5873	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
SynZeal Research Pvt Ltd	+1 226-802-2078	Gujarat, India	6522	58	Inquiry
Pharmaffiliates Analytics & Synthetics (P) Ltd.	91-172-5066494	Haryana, India	631	58	Inquiry
Clearsynth Labs	91-22-45045900	Maharashtra, India	3889	58	Inquiry
Blocksynth Pharmaceutical Technology Co.,Ltd	0086-19817745290; +8619817745290	China	5660	58	Inquiry
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	China	29798	60	Inquiry
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	China	21667	55	Inquiry

Supplier	Advantage
CLEARSYNTH LABS LTD.	58
TCI Chemicals (India) Pvt. Ltd.	58
Otto Chemie Pvt. Ltd.	58
Alfa Aesar	58
SynZeal Research Pvt Ltd	58
Pharmaffiliates Analytics & Synthetics (P) Ltd.	58
Clearsynth Labs	58
Blocksynth Pharmaceutical Technology Co.,Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55

TRIS(2-AMINOETHYL)AMINE Spectrum

TRIS(2-AMINOETHYL)AMINE(4097-89-6)MS TRIS(2-AMINOETHYL)AMINE(4097-89-6)¹HNMR TRIS(2-AMINOETHYL)AMINE(4097-89-6)¹³CNMR TRIS(2-AMINOETHYL)AMINE(4097-89-6)IR1 TRIS(2-AMINOETHYL)AMINE(4097-89-6)Raman

4097-89-6(TRIS(2-AMINOETHYL)AMINE)Related Search:

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2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE CYCLEN-GLYOXAL TRIS(2-AMINOETHYL)AMINE TRIS(2-AMINOETHYL)AMINE POLYMER-BOUND,TRIS(2-AMINOETHYL)AMINE, POLYMER-SUPPORTED Ethylenediamine

TRIS(2-(ISOPROPYLAMINO)ETHYL)AMINE DOTA-D-PHE-CYS-TYR-D-TRP-LYS-THR-CYS-THR-OL (DISULFIDE BRIDGE: 2-7) 2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane DOTA-D-PHE-CYS-TYR-D-TRP-LYS-THR-CYS-THR-OH (DISULFIDE BRIDGE: 2-7) TRIS(2-DIMETHYLAMINOETHYL)AMINE

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tris(beta-aminoethyl)amine 2,2',2''-Triaminotriethylamine,97%TREN 2,2'',2 -TRIAMINOTRIETHYLAMINE TREN 2,2μ,2μμ-Nitrilotriethylamine, 2,2μ,2μμ-Triaminotriethylamine, TAEA 2,2',2''-Nitrilotris(ethane-1-amine) 2,2',2''-Nitrilotrisethanamine Tris(2-aminoethyl)amine ,95% Tris(2-aMinoethyl)aMine, 96% 100ML Tris(2-aMinoethyl)aMine, 96% 5ML Tris(2-aminoethyl)amine,96% Tris(2-aMinoethyl)a Tris(2-aMinoethyl)aMine 96% N1,N1-Bis(2-aminoethyl) TRIS(2-AMINOETHYL)AMINE 2,2',2''-TRIAMINOTRIETHYLAMINE 2,2',2''-NITRILOTRIETHYLAMINE N1,N1-Bis-(2-amino-ethyl)-ethane-1,2-diamine nitrilotris(ethylamine) trenhp Triaminotriethyl-amine 2,2’,2’’-nitrilotris(ethylamine) 2,2’,2’’-triaminotris(ethylamine) 4-(2-Aminoethyl)diethylene triamine 4-(2-aminoethyl)-diethylenetriamin 4-(2-Aminoethyl)diethylenetriamine beta,beta’,beta’’-triaminotriethylamine 2,2',2''-Triaminotriethylamine, min. 98% TREN Tris(2-aminoethyL 1,2-Ethanediamine, N1,N1-bis(2-aminoethyl)- Trientine Impurity 5 Tris(2-aminoethyl)amine, 98+%, tris(aminoethyl)amine TAEA TREN tri(2-aminoethyl)amine 4097-89-6 C6H18N4 NCH2CH2NH23 NH2CH2CH23N Building Blocks Nitrogen Compounds Organic Building Blocks Polyamines