3-Bromofuran

3-Bromofuran Structure
CAS No.
22037-28-1
Chemical Name:
3-Bromofuran
Synonyms
3-bromofurane;Furan, 3-bromo-;3-BROMOFURAN;b-Bromofuran;β-BroMofuran;BROMOFURANE-3;3-Bromofuran99%;BETA-BROMOFURAN;3-Furyl broMide;3-Bromofuran 97%
CBNumber:
CB0329248
Molecular Formula:
C4H3BrO
Molecular Weight:
146.97
MOL File:
22037-28-1.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02

3-Bromofuran Properties

Melting point 131.5-132 °C
Boiling point 103 °C (lit.)
Density 1.635 g/mL at 25 °C (lit.)
refractive index n20/D 1.496(lit.)
Flash point 38 °F
storage temp. -20°C
solubility Chloroform, Ethyl Acetate
form Liquid
color Clear yellow to orange to brown
Water Solubility Soluble in chloroform, ethyl acetate. Insoluble in water.
BRN 105337
InChI InChI=1S/C4H3BrO/c5-4-1-2-6-3-4/h1-3H
InChIKey LXWLEQZDXOQZGW-UHFFFAOYSA-N
SMILES O1C=CC(Br)=C1
CAS DataBase Reference 22037-28-1(CAS DataBase Reference)
NIST Chemistry Reference Furan, 3-bromo-(22037-28-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  16-23-24/25-37/39-26-33-29-7/9
RIDADR  UN 1993 3/PG 2
WGK Germany  3
10
Hazard Note  Highly Flammable/Irritant
HazardClass  3
PackingGroup  II
HS Code  29321900
NFPA 704
3
2 0

3-Bromofuran price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 176524 3-Bromofuran 97% 22037-28-1 2.5G ₹5280 2022-06-14 Buy
Sigma-Aldrich(India) 176524 3-Bromofuran 97% 22037-28-1 10G ₹15050 2022-06-14 Buy
ALFA India ALF-B23543-14 3-Bromofuran, 97%, stab. with 0.5% calcium carbonate 22037-28-1 25g ₹36535 2022-05-26 Buy
ALFA India ALF-B23543-06 3-Bromofuran, 97%, stab. with 0.5% calcium carbonate 22037-28-1 5g ₹9293 2022-05-26 Buy
ALFA India ALF-B23543-03 3-Bromofuran, 97%, stab. with 0.5% calcium carbonate 22037-28-1 1g ₹2025 2022-05-26 Buy
Product number Packaging Price Buy
176524 2.5G ₹5280 Buy
176524 10G ₹15050 Buy
ALF-B23543-14 25g ₹36535 Buy
ALF-B23543-06 5g ₹9293 Buy
ALF-B23543-03 1g ₹2025 Buy

3-Bromofuran Chemical Properties,Uses,Production

Chemical Properties

3-Bromofuran is a colorless to light yellow liquid having a boiling point similar to that of water (102.5-102.6 °C), but with density significantly higher (1.6606 g/cm3 at 20 °C).It is colorless when it is pure; however, the color can be light yellow when minor impurities are present. It is usaually stablized by calcium carbonate. It was used in the preparation of 2-substituted 3-furfurals. It was also used in the synthesis of 5,6-dehydronorcantharidins. 3-bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.

Uses

3-Bromofuran is heterocyclic building block used in organic synthesis. 3-Bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.

Purification Methods

Purify 3-bromofuran by two steam distillations and dry it over fresh CaO. It can be dried over Na metal (no obvious reaction) and fractionated. It is not very soluble in H2O but is soluble in organic solvents. When freshly distilled, it is a clear oil, but darkens on standing and eventually resinifies. It can be stored for long periods by covering the oil with an alkaline solution of hydroquinone and is redistilled when required. It forms a characteristic maleic anhydride adduct, m 131.5-132o. [Shepard et al. J Am Chem Soc 52 2083 1930, Huhes & Johnson J Am Chem Soc 53 737 1931, adduct: van Campen & Johnson J Am Chem Soc 55 430 1933, Beilstein 17/1 V 295.]

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3-BroMofuran, stabilized with Cu(0.1%), Furan (0.5%) & NaHCO3 (0.4%), 95% 3-Bromofuran 97% 3-BROMOFURAN BUTTPARK 98\57-04 BETA-BROMOFURAN 3-Bromofuran, GC 97% 3-BROMOFURAN , STABILIZED WITH 0.5% CALCIUM CARBONATE 3-BROMOFURAN, 97%, STAB. WITH 0.5% CALCIUM CARBONATE TIMTEC-BB SBB004098 3-Bromofuran99% Furan, 3-bromo- (6CI,8CI,9CI) BROMOFURANE-3 3-Bromofuran, stabilized, 98% b-Bromofuran 3-Bromofuran,98%,stabilized 3-Bromofuran, Stab. With 0.5% Calcium Carbonate 3-BroMofuran, stabilized, 98% 2.5ML 3-Furyl broMide β-BroMofuran 3-Bromofuran > 3-bromofurane Furan, 3-bromo- 3-Bromofuran, 95% 22037-28-1 Br1C4H3O1 HALOGEN Furans Heterocyclic Building Blocks Building Blocks Furans, Benzofurans & Dihydrobenzofurans Heterocycles Building Blocks FuransHeterocyclic Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks Furans Furans, Benzofurans & Dihydrobenzofurans Halides Furan&Benzofuran Heterocyclic Compounds HALIDE