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ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Boric acid >4-Formylphenylboronic acid

4-Formylphenylboronic acid

4-Formylphenylboronic acid Structure
CAS No.
87199-17-5
Chemical Name:
4-Formylphenylboronic acid
Synonyms
FPBA;4-FORMYLBENZENEBORONIC ACID;AKOS BRN-0111;TIMTEC-BB SBB004077;RARECHEM AH PB 0193;4-Formylphenylboroni;4-Formylboronic acid;4-BORONOBENZALDEHYDE;Metoprolol Impurity 34;4-Formylpenylboronic Acid
CBNumber:
CB1491072
Molecular Formula:
C7H7BO3
Molecular Weight:
149.94
MOL File:
87199-17-5.mol
MSDS File:
SDS
Modify Date:
2024/4/28 15:15:04
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4-Formylphenylboronic acid Properties

Melting point 237-242 °C (lit.)
Boiling point 347.6±44.0 °C(Predicted)
Density 1.24±0.1 g/cm3(Predicted)
vapor pressure 0Pa at 25℃
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility <10g/l
form Liquid
pka 7.34±0.10(Predicted)
color Clear colorless to yellow-orange
PH 5.5 (1g/l, H2O, 20℃)
Water Solubility Slightly Soluble in water.
Sensitive Air Sensitive
BRN 3030770
InChIKey VXWBQOJISHAKKM-UHFFFAOYSA-N
LogP 1.36 at 20℃
CAS DataBase Reference 87199-17-5(CAS DataBase Reference)
EPA Substance Registry System Boronic acid, (4-formylphenyl)- (87199-17-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P362+P364
Hazard Codes  C,Xi
Risk Statements  34-36/37/38
Safety Statements  22-26-36/37/39-45-37/39-36
RIDADR  UN 1759 8/PG 3
WGK Germany  3
F  10
Hazard Note  Irritant
TSCA  T
HazardClass  IRRITANT, AIR SENSITIVE
HS Code  29163990
NFPA 704
0
2 0

4-Formylphenylboronic acid price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 431966 4-Formylphenylboronic acid ≥95.0% 87199-17-5 1G ₹2170 2022-06-14 Buy
Sigma-Aldrich(India) 431966 4-Formylphenylboronic acid ≥95.0% 87199-17-5 5G ₹7761.53 2022-06-14 Buy
Sigma-Aldrich(India) 431966 4-Formylphenylboronic acid ≥95.0% 87199-17-5 25G ₹18930 2022-06-14 Buy
ALFA India ALF-B25199-14 4-Formylbenzeneboronic acid, 97% 87199-17-5 25g ₹28791 2022-05-26 Buy
ALFA India ALF-B25199-06 4-Formylbenzeneboronic acid, 97% 87199-17-5 5g ₹6209 2022-05-26 Buy
Product number Packaging Price Buy
431966 1G ₹2170 Buy
431966 5G ₹7761.53 Buy
431966 25G ₹18930 Buy
ALF-B25199-14 25g ₹28791 Buy
ALF-B25199-06 5g ₹6209 Buy

4-Formylphenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions and it can be used as a reagent for:

  • Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.
  • Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.
  • Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
  • Triethylamine-catalyzed three-component Hantzsch condensations.
  • Copper-catalyzed nitrations.
  • Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.
  • Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.
  • Palladium-catalyzed aerobic oxidative cross-coupling reactions.
  • The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.
  • The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.
  • The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.
  • A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.

Synthesis

Potassium phenyltrifluoroborate (184 mg, 1.00 mmol) was added to a solution of iron trichloride (185 mg, 1.10 mmol) in 3 mL of 1:1 THF/water. The mixture was stirred at room temperature for 30 min. The reaction mixture was then passed through a short column containing neutral absorption alumina. The alumina was then washed with a mixture of ethyl acetate/hexanes (2:1) to obtain 4-Formylphenylboronic acid (105 mg, 86%). [The boronic acid products can also be isolated by simple extraction techniques.]

4-Formylphenylboronic acid Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid Toluene Tetrahydrofuran Ethylene glycol 4-Bromobenzaldehyde
n-Butyllithium
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Preparation Products

3-THIOPHEN-2-YL-BENZALDEHYDE 1,3,5-Tris(p-formylphenyl)benzene (2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene 3,4'-DIHYDROXYFLAVONE 4-(2-Cyanophenyl)benzaldehyde
4-AMINOMETHYLPHENYLBORONIC ACID, PINACOL ESTER, HCL 4-((N-BOC-AMINO)METHYL)PHENYLBORONIC ACID 4-(2-PHENYLETH-1-YNYL)BENZALDEHYDE Des-N-(methoxycarbonyl)-L-tert-leucine Bis-Boc Atazanavir URMC-099
(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol
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4-Formylphenylboronic acid Suppliers

Global( 529)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TRC FINE CHEMS +91-7400278327 +91-8097105248 Mumbai, India 73 58 Inquiry
SPD CHEMICALS +91-7075800742 +91-7075800742 Hyderabad, India 214 58 Inquiry
REDDY N REDDY PHARMACEUTICALS +91-9848096759 +91-9848096759 Hyderabad, India 1989 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Malladi Drugs AND Pharmaceuticals Limited +91-9004653310 +91-9003056437 Tamil Nadu, India 69 58 Inquiry
Rivashaa Agrotech Biopharma Pvt. Ltd. +91-26463395 +91-7926462688 Gujarat, India 1615 58 Inquiry
Dr R R Organics +91-9666306440 +91-9666306440 Telangana, India 267 58 Inquiry
Denisco Chemicals Pvt Ltd +91-9989050751 Telangana, India 249 58 Inquiry
Prabhat Chemiorganics Limited +91-2240861600 +91-2240861600 Maharashtra, India 86 58 Inquiry
Reddy N Reddy Pharmaceuticals +91 (40) 2307-5686 / +91 98480-96759 / +91 98481-96759 New Delhi, India 254 0 Inquiry
Supplier Advantage
TRC FINE CHEMS 58
SPD CHEMICALS 58
REDDY N REDDY PHARMACEUTICALS 58
JSK Chemicals 58
Malladi Drugs AND Pharmaceuticals Limited 58
Rivashaa Agrotech Biopharma Pvt. Ltd. 58
Dr R R Organics 58
Denisco Chemicals Pvt Ltd 58
Prabhat Chemiorganics Limited 58
Reddy N Reddy Pharmaceuticals 0

4-Formylphenylboronic acid Spectrum

4-Formylphenylboronic acid(87199-17-5)1HNMR4-Formylphenylboronic acid(87199-17-5)IR

87199-17-5(4-Formylphenylboronic acid)Related Search:

4-Tolylboronic acid Phenethylboronic acid 4-Hydroxyphenylboronic acid Phenylboronic acid 4-Aminophenylboronic acid
Benzaldehyde 4-(Methylthio)phenylboronic acid 2-CHLORO-5-FORMYLPHENYLBORONIC ACID 2-Boronobenzaldehyde~2-Formylphenylboronic acid,2-FORMYLPHENYLBORONIC ACID 5-CHLORO-2-FORMYLPHENYLBORONIC ACID
4-ETHOXY-3-FORMYLPHENYLBORONIC ACID 4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID, NEOPENTYL GLYCOL CYCLIC ESTER 4-(N,N-DIMETHYLAMINOCARBONYL)PHENYLBORONIC ACID 4-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID
4-FORMYLPHENYLBORONIC ACID PROPANEDIOL-1,3 CYCLIC ESTER 4-(N,O-DIMETHYLHYDROXYLAMINOCARBONYL)PHENYLBORONIC ACID 4-Carbamoylphenylboronic acid
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RARECHEM AH PB 0193 TIMTEC-BB SBB004077 P-FORMYLPHENYLBORONIC ACID AKOS BRN-0111 4-FORMYLPHENYLBORONIC ACID 4-BORONOBENZALDEHYDE 4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde 4-Formylboronic acid 4-Formylphenylboronic acid ,97% 4-Formylphenylboronic acid,4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde 4-Formylphenylboroni 4-ForMylphenylboronic acid, 97% 1GR Benzeneboronic acid, p-forMyl- (6CI,7CI) 4-ForMylphenylboronic acid >=95.0% 4-Formylphenylboronic acid 4-(Dihydroxyboryl)benzaldehyde p-Formylbenzeneboronic acid (4-methanoylphenyl)boronic acid Boronic acid, (4-formylphenyl)- 4-(dihydroxyboryl)benzaldehyde BENZALDEHYDE-4-BORONIC ACID 4-Boronobenzaldehyde~4-Formylphenylboronic acid 4-Formylpenylboronic Acid Boronic acid, (4-formylphenyl)- (9CI) 4-Formylbenzeneboronicacid,97% 4-Formylphenylboronic acid(FPBA) 2,4-DINITROTOLUENE,1X1ML, ACN 1000UG/ML PARAFORMYLPHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID, 98+% 4-Formylphenlboronic acid 4-Formylphenylboronic Acid (contains varying amounts of Anhydride) Boronic acid, B-(4-formylphenyl)- 4-Formylphenylboronic Acid extrapure, 95% 4-FORMYLBENZENEBORONIC ACID FPBA 4-Formylphenylboronic acid (4-FPBA) Metoprolol Impurity 34 87199-17-5 87199-17-2 Boronic Acids B (Classes of Boron Compounds) BORONIC ACID Boronic Acids and Derivatives Aryl Organometallic Reagents Substituted Boronic Acids Boron, Nitrile, Thio,& TM-Cpds Carbonyl Compounds ALDEHYDE Aldehydes blocks BoronicAcids Boronic Acid series Aryl Organoborons B (Classes of Boron Compounds) CHIRAL CHEMICALS Boronic Acids & Esters Boronic Acid