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ChemicalBook > Product Catalog >Organic Chemistry >Ethers and derivatives >Ethers, ether-alcohols, ether phenol derivatives >4,4'-Oxydianiline

4,4'-Oxydianiline

4,4'-Oxydianiline Structure
CAS No.
101-80-4
Chemical Name:
4,4'-Oxydianiline
Synonyms
ODA;Oxydianiline;BIS(4-AMINOPHENYL) ETHER;4,4-OXYDIANILINE;4,4-DIAMINODIPHENYL ETHER;ODC;Dadpe;4-AMINOPHENYL ETHER;Diaminodiphenyl ether;4,4'
CBNumber:
CB1689134
Molecular Formula:
C12H12N2O
Molecular Weight:
200.24
MOL File:
101-80-4.mol
MSDS File:
SDS
Modify Date:
2024/5/21 14:26:55
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4,4'-Oxydianiline Properties

Melting point 188-192 °C(lit.)
Boiling point 190 °C (0.1 mmHg)
Density 1.1131 (rough estimate)
vapor pressure 10 mm Hg ( 240 °C)
refractive index 1.6660 (estimate)
Flash point 426 °F
storage temp. Store below +30°C.
solubility DMSO (Slightly), Methanol (Slightly)
pka 5.49±0.10(Predicted)
form Solid
color White
Water Solubility Insoluble. <0.01 g/100 mL at 15 ºC
BRN 475735
Stability Stable. Combustible. Incompatible with strong oxidizing agents. Hygroscopic.
InChIKey HLBLWEWZXPIGSM-UHFFFAOYSA-N
LogP 0.72 at 20℃
CAS DataBase Reference 101-80-4(CAS DataBase Reference)
IARC 2B (Vol. 29, Sup 7) 1987
NIST Chemistry Reference Benzenamine, 4,4'-oxybis-(101-80-4)
EPA Substance Registry System 4,4'-Diaminodiphenyl ether (101-80-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H317-H340-H350-H361f-H410
Precautionary statements  P202-P273-P280-P301+P310-P302+P352+P312-P304+P340+P311
Hazard Codes  T,N
Risk Statements  45-46-23/24/25-51/53-62-36/37/38-22-50/53-43
Safety Statements  53-45-61-36/37-26-20-60
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  BY7900000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29222900
Toxicity LD50 orl-rat: 725 mg/kg HYSAAV 33,137,68
NFPA 704
0
3 0

4,4'-Oxydianiline price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 516805 4,4′-Oxydianiline 97% 101-80-4 100G ₹7534.2 2022-06-14 Buy
Sigma-Aldrich(India) 516805 4,4′-Oxydianiline 97% 101-80-4 500G ₹29335.75 2022-06-14 Buy
Sigma-Aldrich(India) 46117 4,4′-Oxydianiline analytical standard 101-80-4 250MG ₹5282.6 2022-06-14 Buy
ALFA India ALF-A16815-36 Bis(4-aminophenyl) ether, 98% 101-80-4 500g ₹15671 2022-05-26 Buy
ALFA India ALF-A16815-22 Bis(4-aminophenyl) ether, 98% 101-80-4 100g ₹7322 2022-05-26 Buy
Product number Packaging Price Buy
516805 100G ₹7534.2 Buy
516805 500G ₹29335.75 Buy
46117 250MG ₹5282.6 Buy
ALF-A16815-36 500g ₹15671 Buy
ALF-A16815-22 100g ₹7322 Buy

4,4'-Oxydianiline Chemical Properties,Uses,Production

Chemical Properties

Colorless crystalline

Uses

4,4＇-Oxydianiline has been used to produce polyimide resins.

Production Methods

4-Aminophenyl ether was produced in relatively large volume (on the order of 100,000–1,000,000 lb) in the 1970s but has since declined significantly. The compound is used primarily in the production of polyimide and polyesterimide resins. These resins are used in the manufacture of temperature- resistant products such as wire enamels, coatings, film, insulating varnishes, and flame-retardant fibers.

General Description

Odorless colorless crystals or an odorless fine, beige powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4,4'-Oxydianiline oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616(1960)].

Health Hazard

4-Aminophenyl ether is highly toxic to animals. There is suffi cient evidence as a carcinogenicity and has caused adenomas and carcinomas in the thyroid and liver of experimental rats.

Fire Hazard

4,4'-Oxydianiline is combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx

Potential Exposure

Intermediate in the manufacture of high-temperature-resistant, straight polyimide and poly (esterimide) resins capable of withstanding temperatures of Up to 480°C for short periods or 260°C for prolonged periods of time. Some p-phenylenediamine compounds have been used as rubber components, and DFG warns of danger of skin sensitization.

Carcinogenicity

4,4′-Oxydianiline is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Slowly hydrolyzes in water, releasing ammonia, and forming acetate salts. Decomposes at 265C releasing toxic oxides of nitrogen, sulfur, and carbon. Decomposed by strong ultraviolet light.

Waste Disposal

Incineration with provision for nitrogen oxides removal from flue gases.

4,4'-Oxydianiline Preparation Products And Raw materials

Raw materials

Ammonium hydroxide Sodium nitrite Ammonium chloride Sodium formate Hydrochloric acid
4-Nitrophenol Nitrobenzene EMULSIFIER Iron Potassium chloride
Activated carbon Sodium carbonate Citric acid
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Preparation Products

Polyimide film N,N'-(OXYDI-4,1-PHENYLENE)BISACETAMIDE 4,4'-DINITRODIPHENYL ETHER 4,4'-Oxydiphenol Acid Green 54

4,4'-Oxydianiline Suppliers

Global( 570)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Sadhana Nitro Chem Ltd +91-2268663300 +91-2268663300 Maharashtra, India 15 58 Inquiry
Shubham Specialty Products Pvt Ltd +91-2249733812 +91-9867728601 Mumbai, India 38 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Central Drug House(P) Ltd. 91-11-49404040 New Delhi, India 6160 58 Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd +91-172-5066494 Haryana, India 6773 58 Inquiry
Supplier Advantage
JSK Chemicals 58
Sadhana Nitro Chem Ltd 58
Shubham Specialty Products Pvt Ltd 58
TCI Chemicals (India) Pvt. Ltd. 58
CHEMSWORTH 30
CLEARSYNTH LABS LTD. 58
Otto Chemie Pvt. Ltd. 58
Alfa Aesar 58
Central Drug House(P) Ltd. 58
Pharmaffiliates Analytics and Synthetics P. Ltd 58

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4,4'-Oxydianiline purified by sublimation, 99% 4,4'-Diaminodiphenyl ether for synthesis BIO-FARMA BF003088 BIS(P-AMINOPHENYL)ETHER 4,4'-Oxybisbenzenamine 4,4'-OXYDIANILINE 4,4'-ODA 4,4'-DIAMINODIPHENYL ETHER 4,4'-DIAMINODIPHENYL OXIDE 4,4'-DIAMINOPHENYL ETHER 4,4'-DADPE 4,4'-DPE 4,4'-Diaminobiphenyl oxide 4,4'-Diaminophenyl oxide 4,4'-Oxybis[aniline] 4,4'-Oxydiphenylamine Aniline, 4,4'-oxydi- di(4-Aminophenyl) ether di-(4-aminophenyl)ether diaminodiphenylether Ether, 4,4'-diaminodiphenyl- ether,4,4’-diaminodiphenyl NCI-C50146 oxybis(4-aminobenzene) Oxybis[4-aminobenzene] Oxydi-p-phenylenediamine p,p’-diaminodiphenylether p,p’-oxybis(aniline) p,p’-oxydianiline p,p'-Diaminodiphenyl ether p,p'-Oxybis(aniline) p,p'-Oxydianiline p-Aminophenyl ether p-aminophenylether 4-(4-Aminophenoxy)phenylamine 4,4’-biaminodiphenylether 4,4’-diaminobiphenyloxide 4,4’-diaminophenyloxide 4,4’-oxybisaniline 4,4’-oxybis-benzenamin 4,4’-oxybis-Benzeneamine 4,4’-oxydi-anilin 4,4’-oxydiphenylamine 4,4'-diaminadiphenyl ether 4-(4-aminophenoxy)benzenamine 4,4'-OXYDIANILINE, SUBLIMED, 99% 4,4'-OXYDIANILINE, SUBLIMED, ZONE-REFINE D, 99+% 4,4-OXYDIANILINE OEKANAL, 250 MG 4,4'-DIAMINODIPHENYL ETHER, ZONE REFINED 4 4'-OXYDIANILINE 98+% 4 4'-OXYDIANILINE 99.5% TIMTEC-BB SBB003546 ZERENEX ZX004984 4,4'-Diaminodiphenyl Oxide 4,4'-Oxydianiline ODA)4,4′-DiaMinodiphe 4,4'-DiaMinodiphenyl ether (ODA) 4,4′-Oxydianiline Solution, 100ppm 4,4'-DiaiMinodiphenyl ether