Aniline hydrochloride
- CAS No.
- 142-04-1
- Chemical Name:
- Aniline hydrochloride
- Synonyms
- C.I. 76001;usafek-442;ANILINE HCL;Aniline salt;sulanilinova;chloridanilinu;anilinechloride;Anilinechlofide;Benzenamine HCl;Anilinhydrochlorid
- CBNumber:
- CB2173166
- Molecular Formula:
- C6H8ClN
- Molecular Weight:
- 129.59
- MOL File:
- 142-04-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/1 18:08:31
| Melting point | 196-198 °C(lit.) |
|---|---|
| Boiling point | 245 °C |
| Density | 1.2215 |
| vapor density | 4.46 (vs air) |
| refractive index | 1.5330 (estimate) |
| Flash point | 380 °F |
| storage temp. | Store below +30°C. |
| solubility | 1070g/l |
| form | Powder |
| color | White to pale yellow-cream |
| Water Solubility | 1070 g/L (25 ºC) |
| Sensitive | Hygroscopic |
| Merck | 14,659 |
| BRN | 3593823 |
| Stability | Stable. Incompatible with strong oxidizing agents, strong acids. |
| CAS DataBase Reference | 142-04-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenamine, hydrochloride(142-04-1) |
| IARC | 2A (Vol. 127) |
| EPA Substance Registry System | Aniline hydrochloride (142-04-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311+H331-H317-H318-H341-H351-H372-H400 | |||||||||
| Precautionary statements | P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338 | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 23/24/25-40-41-43-48/23/24/25-50-68 | |||||||||
| Safety Statements | 26-27-36/37/39-45-61-63-46 | |||||||||
| RIDADR | UN 1548 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | CY0875000 | |||||||||
| F | 3-9 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29214100 | |||||||||
| Toxicity | LD50 orally in Rabbit: 840 mg/kg | |||||||||
| NFPA 704 |
|
Aniline hydrochloride price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | A8524 | Aniline hydrochloride ≥99% | 142-04-1 | 5G | ₹8032.15 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | A8524 | Aniline hydrochloride ≥99% | 142-04-1 | 50G | ₹8530.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.20099 | Anilinium chloride for synthesis | 142-04-1 | 250G | ₹6920.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.20099 | Anilinium chloride for synthesis | 142-04-1 | 1KG | ₹17560 | 2022-06-14 | Buy |
| ALFA India | ALF-A13024-36 | Aniline hydrochloride, 99% | 142-04-1 | 500g | ₹3846 | 2022-05-26 | Buy |
Aniline hydrochloride Chemical Properties,Uses,Production
Description
Aniline (hydrochloride) (Item No. 21963) is an analytical reference standard that is structurally categorized as a synthetic intermediate. It is used to make the imine derivative of NPP as part of the synthesis of fentanyl (Item Nos. 14719 | ISO60197 ) and its derivatives. This product is intended for research and forensic applications.
Chemical Properties
Aniline hydrochloride, a white to greenishcrystalline solid that meltsat 198°C and boils at 245 °C;soluble in water,alcohol, and chloroform; used in making dyes and in printing. Also known as anilinechloride,anilinesalt.
Uses
Aniline hydrochloride was used in the preparation of polyaniline coated poly(styrene-co-styrene sulfonate) nanoparticles. It was used to study the induction of Nei-like DNA glycosylases (NEIL1/2)-mediated base excision repair(BER) in rat spleen and 8-oxoguanine glycosylase 1-mediated BER due to aniline exposure. It is used in printing inks, clothing marking inks, paints and paint removers. It is also used as a stove polisher and shoe polisher, as well as in the synthesis of dyes, crayons and antioxidants.
General Description
A white to greenish colored crystalline solid. Toxic by ingestion and a skin and eye irritant. May emit toxic aniline and chloride fumes under exposure to high temperatures or flame. Used to make dyes and printing ink.
Air & Water Reactions
Aniline hydrochloride is sensitive to air and light (darkens). Soluble in water and denser than water.
Reactivity Profile
Aniline hydrochloride is incompatible with oxidizing materials.
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Safety Profile
Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic effects. Human mutation data reported. A skin and eye irritant. Combustible when exposed to heat or flame. When heated to decomposition or on contact with acid or acid fumes, it emits highly toxic fumes of aniline and chlorine compounds. Reacts explosively with aniline at 240℃/7.6 bar. Can react vigorously with oxidizing materials. To fight fire, use water, CO2, water mist or spray, dry chemical. See also ANILINE.
Potential Exposure
Aniline is widely used as an intermediate in the synthesis of dyestuffs. It is also used in the manufacture of rubber accelerators and antioxidants, pharmaceuticals, marking inks; tetryl, optical whitening agents; photographic developers; resins, varnishes, perfumes, shoe polishes, and many organic chemicals.
Shipping
UN1547 Aniline, Hazard Class: 6.1; Labels: 6.1- Poisonous materials. UN1548 Aniline hydrochloride, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods
Purification is as for aniline HBr above. [Beilstein 12 IV 232.]
Incompatibilities
May form explosive mixture with air. Unless inhibited (usually methanol), aniline is readily able to polymerize. Fires and explosions may result from contact with halogens, strong acids; oxidizers, strong base organic anhydrides; acetic anhydride, isocyanates, aldehydes, sodium peroxide. Strong reaction with toluene diisocyanate. Reacts with alkali metals and alkali earth metals. Attacks some plastics, rubber and coatings; copper and copper alloys.
Waste Disposal
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration with provision for nitrogen oxides removal from flue gases by scrubber, catalytic or thermal device.
Aniline hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
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| Shree Sidhdhanath Industries | +91-9427163341 +91-9427163341 | Gujarat, India | 21 | 58 | Inquiry |
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| VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2096 | 58 | Inquiry |
| Chemicea Pharmaceuticals Pvt Ltd | +91-9881765045/+91-8796656135 | Pune, India | 825 | 58 | Inquiry |
| Pharma Affiliates | 172-5066494 | Haryana, India | 6761 | 58 | Inquiry |
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