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Calcium hypophosphite

Calcium hypophosphite Structure
CAS No.
7789-79-9
Chemical Name:
Calcium hypophosphite
Synonyms
Nsc41872;Lime hypophosphite;CALCIUM PHOSPHINATE;CalClum hypophosphite;CALCIUM HYPOPHOSPHITE;Calcium hydrophosphite;Calcium bisphosphinate;Phosphinicacid,calciumsalt;Times of calcium phosphate;CALCIUMHYPOPHOSPHITE,PURIFIED
CBNumber:
CB2291738
Molecular Formula:
Ca(H2PO2)2
Molecular Weight:
170.05
MOL File:
7789-79-9.mol
Modify Date:
2024/5/29 16:45:47

Calcium hypophosphite Properties

Melting point decomposes [ALF93]
Boiling point 480℃[at 101 325 Pa]
Density 2.243[at 20℃]
solubility soluble in H2O; insoluble in ethanol
pka 12.6[at 20 ℃]
form white monoclinic crystals
color white monoclinic crystals, crystalline
Water Solubility Soluble in water. Practically insoluble in alcohol. Slightly soluble in glycerol
Sensitive Hygroscopic
Merck 14,1675
InChIKey XJPMAXXEWYLDCQ-UHFFFAOYSA-L
CAS DataBase Reference 7789-79-9(CAS DataBase Reference)
EPA Substance Registry System Calcium hypophosphite (7789-79-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H228
Precautionary statements  P240-P241-P280-P370+P378a-P210
Hazard Codes  F
Risk Statements  11
Safety Statements  7-15
RIDADR  UN 3180 4.1/PG 2
WGK Germany  3
TSCA  Yes
HazardClass  4.1
NFPA 704
2
2 1

Calcium hypophosphite price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
ottokemi C 1482 Calcium phosphinate 7789-79-9 500gm ₹1602 2022-05-26 Buy
ottokemi C 1482 Calcium phosphinate 7789-79-9 5kg ₹12006 2022-05-26 Buy
ottokemi C 1438 Calcium hypophosphite, 99% 7789-79-9 500gm ₹1602 2022-05-26 Buy
ottokemi C 1438 Calcium hypophosphite, 99% 7789-79-9 5kg ₹12006 2022-05-26 Buy
Product number Packaging Price Buy
C 1482 500gm ₹1602 Buy
C 1482 5kg ₹12006 Buy
C 1438 500gm ₹1602 Buy
C 1438 5kg ₹12006 Buy

Calcium hypophosphite Chemical Properties,Uses,Production

Description

Calcium hypophosphite has the molecular formula of Ca(H2PO2)2 and the molecular weight of 170.0631 g/mol. This salt can be prepared by the aqueous reaction of the carbonate or oxide with H3PO2:
CaO + 2H3PO2 ? Ca(H2PO2)2
The salt is soluble in water (20 g/100 ml at 20°C) so that the solution must be evaporated to obtain crystals. Ca(H2PO2)2 has the CAS number of 7789-79-9 and the density of 1.59 g/cm3. It is composed of white square monoclinic crystalswhich are water soluble. It is insoluble in alcohol or ether.When heated to about 305°C, it disproportionates, forming calcium phosphate and phosphine:
Ca(H2PO2)2 + heat ? CaHPO3 + PH3

Chemical Properties

white monoclinic, prismatic crystal(s) or granular powder(s); used as a corrosion inhibitor and in medicine [MER06] [HAW93]

Physical properties

Calcium hypophosphite is relatively soluble in water, and when added to a solution of sodium hypophosphite, forms a double salt. Crystals were obtained by slow evaporation of the solution to form dodecahedra with well-developed {110} faces. The crystal structure of CaNa(H2PO2)3 belongs to the cubic system with space group, P213, Z = 4 and a = 9.721?. The structure consists of two kinds of octahedral groups, one with a calcium atom and the other with a sodium atom. Each atom of the hypophosphite ions is coordinated to each one of the calcium and sodium atoms to form the octahedral. This structure is, in general, typical of the salts of hypophosphorous acid.
Calcium hypophosphite is readily available commercially since its main usage, both industrially and in Research, has proven to be as a source of hypophosphite anions to form other hypophosphites.

Uses

As corrosion inhibitor; in nickel plating. Pharmaceutic aid (retards oxidation of ferrous salts).

Calcium hypophosphite Preparation Products And Raw materials

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Calcium hypophosphite Spectrum

CALCIUM HYPOPHOSPHITE CALCIUM PHOSPHINATE CALCIUM HYPOPHOSPHITE EXTRA PURE, DAC Lime hypophosphite CALCIUM HYPOPHOSPHITE TECHNICAL Calcium hydrophosphite CALCIUMHYPOPHOSPHITE,PURIFIED Calcium bisphosphinate Nsc41872 CalClum hypophosphite Phosphinicacid,calciumsalt Phosphinic acid, calcium salt (2:1) Calcium hypophosphite ISO 9001:2015 REACH Times of calcium phosphate 7789-79-9 77789-79-9 CaH4P2O4 CaH2PO22 CaH2O4P2 HO2P CaH4O4P2 CaO2P Inorganic Salts Synthetic Reagents Inorganics