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Nickel(II) oxide

Nickel(II) oxide Structure
CAS No.
1313-99-1
Chemical Name:
Nickel(II) oxide
Synonyms
NICKEL MONOXIDE;bunsenite;C.I. 77777;(II) oxide;OXIDICNICKEL;Nickel 0xide;nickd monoxide;CATALYST R1-10;A nickel oxide;mononickeloxide
CBNumber:
CB2358284
Molecular Formula:
NiO
Molecular Weight:
74.69
MOL File:
1313-99-1.mol
MSDS File:
SDS
Modify Date:
2024/5/28 19:59:05

Nickel(II) oxide Properties

Melting point 1960 °C
Density 6.67 g/mL at 25 °C(lit.)
solubility insoluble in H2O; soluble in acid solutions
form Powder/Solid
Specific Gravity 6.67
color green
Water Solubility insoluble
Merck 14,6512
Exposure limits ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability Stable. Incompatible with strong acids.
InChI InChI=1S/Ni.O
InChIKey GNRSAWUEBMWBQH-UHFFFAOYSA-N
SMILES O=[Ni]
CAS DataBase Reference 1313-99-1(CAS DataBase Reference)
EPA Substance Registry System Nickel(II) oxide (1313-99-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H350i-H372-H413
Precautionary statements  P202-P260-P273-P280-P302+P352-P308+P313
Hazard Codes  T,Xi
Risk Statements  49-43-53-48/23-36/37
Safety Statements  53-45-61-36/37-26
RIDADR  3288
WGK Germany  1
RTECS  QR8400000
TSCA  Yes
HS Code  28254000
NFPA 704
0
3 0

Nickel(II) oxide price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 637130 Nickel(II) oxide nanopowder, <50?nm particle size (TEM), 99.8% trace metals basis 1313-99-1 25G ₹4900 2022-06-14 Buy
Sigma-Aldrich(India) 921602 NiO nanoparticle ink solution 2.5?wt. %, viscosity 1.3?cP 1313-99-1 10ML ₹10684.28 2022-06-14 Buy
Sigma-Aldrich(India) 637130 Nickel(II) oxide nanopowder, <50?nm particle size (TEM), 99.8% trace metals basis 1313-99-1 100G ₹12410 2022-06-14 Buy
Sigma-Aldrich(India) 774545 Nickel(II) oxide nanowires, diam. × L ~20?nm × 10?μm 1313-99-1 500MG ₹18260 2022-06-14 Buy
Sigma-Aldrich(India) 637130 Nickel(II) oxide nanopowder, <50?nm particle size (TEM), 99.8% trace metals basis 1313-99-1 250G ₹23330 2022-06-14 Buy
Product number Packaging Price Buy
637130 25G ₹4900 Buy
921602 10ML ₹10684.28 Buy
637130 100G ₹12410 Buy
774545 500MG ₹18260 Buy
637130 250G ₹23330 Buy

Nickel(II) oxide Chemical Properties,Uses,Production

Chemical Properties

Nickel(II) oxide is Brownish black or black powder.

Uses

Nickel(II) oxide is used in the preparation of nickel alloys including nickel steel alloys, manufacture of glass and porcelain paints. Further nickel oxide is the main component in nickel-iron battery (Edison battery), nickel-cadmium rechargeable battery, and also used in ceramic industry for making frits and porcelain glazes. It also acts as a hydrogenation catalyst. NiO/CNTs (nickel oxide/carbon nanotubes) could be a potential cathode catalyst for oxygen reduction reaction (ORR) in microbial fuel cells (MFCs). It is blended with other high purity oxides and used in a variety of semiconductor applications such as thermistors and varistors.

Preparation

Nickel oxide is prepared by heating pure nickel powder with oxygen at a temperature above 400°C. In some commercial processes, green nickel oxide is made by heating a mixture of nickel powder and water in air at 1,000°C. Adding some nickel oxide to the above mixture enhances the rate of reaction. An alternative method of preparation of the green oxide involves thermal decomposition of an oxo acid salt of nickel at elevated temperatures. Thus, nickel nitrate, nickel sulfate or, more conveniently, nickel carbonate when heated at 1,000°C, yields the green oxide. The black oxide, on the other hand, is produced at a lower temperature from incomplete calcination of the carbonate or nitrate salt at 600°C. The oxygen content of the black form is slight-ly greater than its green counterpart.

Reactions

Nickel(II) oxide is insoluble in water but soluble in acids as long as it has not been ignited at a high temperature (under these latter conditions it is converted into grey-black octahedra having a metallic lustre). It reacts reversibly with hydrogen, the reaction NiO+H2 ? Ni+H20 proceeding from left to right at relatively low temperatures in a stream of hydrogen.

General Description

Nickel(II) oxide (NiO) is a metal oxide based nanomaterial with a good semiconducting property. Nanosized nickel oxide can be found in a variety of morphologies which include nanoflowers, spheres, wires, and tubes. It exhibits high performance in applications which require charge transfer and charge transport based processes. It can be prepared by a variety of physical and thermal methods such as sol-gel, hydrothermal and solvothermal techniques.

Hazard

Confirmed carcinogen.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intratracheal, intravenous, and subcutaneous routes. Mutation data reported. Can react violently with fluorine, hydrogen peroxide, hydrogen sulfide, iodine, barium oxide + air. See also NICKEL COMPOUNDS.

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Nickel(II) oxide Spectrum

blacknickeloxide NICKEL(II) OXIDE NICKEL(II) OXIDE, BLACK NICKEL (II) OXIDE (GREEN) NICKELOUS OXIDE NICKELOUS OXIDE, GREEN NICKEL OXIDE, GREEN NICKEL OXIDE GREEN (OUS) NICKEL(+2)OXIDE bunsenite mononickeloxide nickel(ii)oxide(1:1) nickeloxide(nio) nickeloxidesinter75 Nickelprotoxide Nickel(II) oxide, Puratronic(R), 99.998% (metals basis) Nickel(II) oxide, 99+% (metals basis) Nickel(II) oxide, 99.995% (metals basis) Nickel(II) oxide, black, Ni 76%, (contains Ni2O3) Nickel(II) oxide, black, Ni 76%, (contains NiO3) Nickel(II) oxide, Puratronic, 99.998% (metals basis) Nickel oxide,nanometer nickd monoxide Nickel(II) oxide, green, Ni 78.5% Nickel(II) oxide,97%,reagent, powder Nickel(II) oxide, black, Ni 76%, (contains Ni2O3) Nickel(II) Oxide, Puratronic (Metals Basis) Nicke(II) oxide Nickel(II) oxide, nanopowder, 99.8% metals basis NICKEL(II) OXIDE, GREEN, -325 MESH, 99% NICKEL(II) OXIDE, 99.999% Nickel(II) oxide, 99.99% metals basis NickelOxideBlackExtraPure Nickelmonoxide,greenpowder CATALYST R1-10 NICKEL(II) OXIDE (NIO) Nickel(II) monoxide Nickelous monoxide Nickel(II) oxide, black, 76% Ni Nickel(II) oxide, reagent, powder, 97% NICKEL OXIDE 99.999% NICKEL OXIDE, GREEN REAGENT Nickelous oxide,99.998%,powder Nickel(II)oxide(99.99%-Ni)PURATREM Nickel(II)oxide(99.998%-Ni)PURATREM Nickel(II)oxide,black,99+% Nickel(II)oxide,green,99% nickel(ii) oxide, puratronic NICKELOXIDE,GREEN,POWDER,REAGENT OXIDICNICKEL NICKEL(II) OXIDE: 99.99% NICKEL(II) OXIDE: 99,998% PURATREM Nickel(II) oxide, extra pure "Nickel(II) oxide, green/ 99.995%" Nickelous(II) oxide Nickel(II) Oxide, Black 99% Nickel (II) oxide - green powder Nickel(II) oxide, black, 76% Ni 100GR