COBALT(III) OXIDE BLACK
- CAS No.
- 1308-04-9
- Chemical Name:
- COBALT(III) OXIDE BLACK
- Synonyms
- COBALT BLACK;Cabalt trioxide;COBALT(II,III) OXIDE;c.i.77323;dicobaltoxide;cobaltperoxide;cobalttrioxide;Cobolt-3-oxide;Cobalt(Ⅲ)oxide;COBALTIC OXIDE
- CBNumber:
- CB4291419
- Molecular Formula:
- Co2O3
- Molecular Weight:
- 165.86
- MOL File:
- 1308-04-9.mol
- Modify Date:
- 2024/12/18 14:08:52
Melting point | 895 °C (dec.)(lit.) |
---|---|
Density | 6.11 g/mL at 25 °C(lit.) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | insoluble in H2O; soluble in concentrated acid solutions |
form | powder |
color | gray-black |
Water Solubility | insoluble H2O; soluble conc acids [HAW93] |
EPA Substance Registry System | Cobalt oxide (Co2O3) (1308-04-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS08,GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H351-H317-H410-H302 |
Precautionary statements | P201-P202-P281-P308+P313-P405-P501-P264-P270-P301+P312-P330-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P391-P501 |
Hazard Codes | Xn |
Risk Statements | 36/37/38-40-43-22 |
Safety Statements | 26-36/37/39-36/37 |
WGK Germany | 1 |
RTECS | GG2500000 |
Toxicity | mouse,LD50,subcutaneous,2064mg/kg (2064mg/kg),Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974. |
COBALT(III) OXIDE BLACK Chemical Properties,Uses,Production
Description
Neither the oxide Co2O3 nor the hydroxide Co(OH)3 is definitely established. The oxidation of cobalt(II) hydroxide in aqueous suspension with, for example, peroxides, or the destruction of a cobalt(III) complex with alkali gives a brown or black powder Co2O3.aq which upon drying at 150° yields the monohydrate Co2O3.H2O; this is probably best formulated as CoO(OH). When heated further in attempts to dehydrate it, the "monohydrate" begins to evolve oxygen (as well as water) at 300° with the formation of black Co3O4. When heated to 100° in air cobalt(II) hydroxide is converted to dark brown CoO(OH).
Chemical Properties
Steel-gray or black powder.Soluble in concentrated acids; insoluble in water.
Physical properties
Grayish black powder; density 5.18 g/cm3; decomposes at 895°C; insoluble in water; soluble in concentrated mineral acids.
Uses
Pigment, coloring enamels, glazing pottery.
Preparation
Cobalt(III) oxide is prepared by heating cobalt compounds at low temperatures in air.
Definition
Sometimes incorrectly called cobalt peroxide.
Safety Profile
: Moderately toxic by intraperitoneal and subcutaneous routes. Questionable carcinogen. Violent reaction with hydrogen peroxide. The oxide increases the sensitivity of nitroalkanes (e.g., nitromethane, nitroethane, and 1 nitropropane) to heat or detonation. See also COBALT COMPOUNDS.
COBALT(III) OXIDE BLACK Preparation Products And Raw materials
Raw materials
Preparation Products
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