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Tributyl borate

Tributyl borate Structure
CAS No.
688-74-4
Chemical Name:
Tributyl borate
Synonyms
TRI-N-BUTYL BORATE;BORIC ACID TRIBUTYL ESTER;AI311060;borester2;AI3 11060;AI3-11060;Borester 2;n-Butoxide;(n-C4H9O)3B;Buty borate
CBNumber:
CB4145842
Molecular Formula:
C12H27BO3
Molecular Weight:
230.16
MOL File:
688-74-4.mol
MSDS File:
SDS
Modify Date:
2024/8/5 20:55:42

Tributyl borate Properties

Melting point -70 °C (lit.)
Boiling point 114-115 °C/12 mmHg (lit.) 230-235 °C (lit.)
Density 0.853 g/mL at 25 °C (lit.)
vapor density 7.95 (vs air)
vapor pressure 3.79hPa at 25℃
refractive index n20/D 1.409(lit.)
Flash point 200 °F
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol,Benzene,Ethanol
form Liquid
Specific Gravity 0.853
color Clear colorless
Water Solubility decomposes
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 1703865
Stability Stables, but reacts rapidly with moisture, water. Reacts vigorously with oxidizing agents. Incompatible with strong acids.
InChIKey LGQXXHMEBUOXRP-UHFFFAOYSA-N
LogP 1 at 25℃
CAS DataBase Reference 688-74-4(CAS DataBase Reference)
NIST Chemistry Reference Boric acid, tributyl ester(688-74-4)
EPA Substance Registry System Tributyl borate (688-74-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38-36/38
Safety Statements  26-36/37/39-37/39
RIDADR  3272
WGK Germany  3
RTECS  ED4900000
21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29209090
NFPA 704
2
3 1

Tributyl borate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 90795 Tributyl borate ≥99.0% (T) 688-74-4 100ML ₹3344.93 2022-06-14 Buy
Sigma-Aldrich(India) 90795 Tributyl borate ≥99.0% (T) 688-74-4 500ML ₹10381.18 2022-06-14 Buy
TCI Chemicals (India) B0518 Tributyl Borate 688-74-4 25ML ₹1600 2022-05-26 Buy
TCI Chemicals (India) B0518 Tributyl Borate 688-74-4 100ML ₹3300 2022-05-26 Buy
TCI Chemicals (India) B0518 Tributyl Borate 688-74-4 500ML ₹6300 2022-05-26 Buy
Product number Packaging Price Buy
90795 100ML ₹3344.93 Buy
90795 500ML ₹10381.18 Buy
B0518 25ML ₹1600 Buy
B0518 100ML ₹3300 Buy
B0518 500ML ₹6300 Buy

Tributyl borate Chemical Properties,Uses,Production

Chemical Properties

Water-white liquid. Distillation range, 85% distills between 135C and 140C (40 mm Hg). Hydrolyzes rapidly; miscible with common organic liquids. Combustible.

Uses

Welding fluxes, intermediate in preparation of borohydrides, flame retardant for textiles (with boric acid).

Air & Water Reactions

Rapidly decomposes in water.

Reactivity Profile

Borates behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides. Reacts vigorously with oxidizing materials. .

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic; may emit toxic fumes when heated to decomposition or on contact with acid or acid fumes, local irritant.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. An eye irritant. Flammable when exposed to heat, flame, or oxiduers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition or on contact with acid or acid fumes it can emit toxic fumes; on contact with oxidizing materials it can react vigorously. See also BORANES and BORON COMPOUNDS.

Purification Methods

The chief impurities are n-butyl alcohol and boric acid (from hydrolysis). It must be handled in a dry-box and can readily be purified by fractional distillation, under reduced pressure. [O’Brien Aust J Chem 10 91 1957, Gerrard & Lappert J Chem Soc 2545, 2547 1951, Beilstein 1 IV 1544.]

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Tributy borate Tributyl borate,98% Boric acid tributylester, Tributoxyborane Tributyl borate >=99.0% (T) Tributhyl Borate tributyl broate Tributyl borate Tributyl borate ,99% Tributyl borate, AcroSeal, 98% Tributyl borate, 98% 500ML Tributyl borate, 98%, AcroSeal (n-C4H9O)3B Borane, tributoxy- borane,tributoxy Borester 2 tributylesterkyselinyborite tributylorthoborate tris(1-butyl)borate Tris(butoxy)borane N-BUTYLBORATE BORON N-BUTOXIDE BORIC ACID TRI-N-BUTYL ESTER BUTYL BORATE TRI-N-BUTOXYBORANE TRIBUTYL BORATE-11B TRIBUTOXYBORANE TRIBUTOXYBORANE-11B Buty borate Boric acid tri-n-butyl ester~n-Butyl borate Trinbutylboratecolorlessliq Triutyl borate Tri-n-butylborate,98% n-Butoxide Tri-n-butylborate,99% TRI-N-BUTYLBORANEOXIDE borester2 Boric acid (H3BO3), tributyl ester boricacid(h3bo3),tributylester boricacid,(h3bo3)tributylester Boron tributoxide borontributoxide Butyl borate, (BuO)3 B Butyl borate, tri- tributoxy-boran tributoxyborine Tributoxyboron Tributyl orthoborate tri-butylborat Tributylester kyseliny borite Tributyl borate, 99%, for synthesis Tributyl Borate > Tributyl borate(688-74-4) and Propionic acid BORIC ACID TRIBUTYL ESTER TRI-N-BUTYL BORATE Tribuytl Borate AI3 11060 AI311060 AI3-11060