Eradicane
- CAS No.
- 759-94-4
- Chemical Name:
- Eradicane
- Synonyms
- EPTC;Genep;Witox;EPTAM;ALIROX;R-1608;Niptan;Torbin;fda1541;eptam6e
- CBNumber:
- CB4169538
- Molecular Formula:
- C9H19NOS
- Molecular Weight:
- 189.32
- MOL File:
- 759-94-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/4 17:34:42
| Melting point | 25°C |
|---|---|
| Boiling point | 127°C (20 torr) |
| Density | 0.95 |
| vapor pressure | 3.192Pa at 25℃ |
| refractive index | nD30 1.4750 |
| Flash point | 116 °C |
| storage temp. | 0-6°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| pka | -1.22±0.70(Predicted) |
| form | Liquid |
| color | Clear colorless |
| Water Solubility | 0.375 g/100 mL |
| Merck | 13,3669 |
| BRN | 1762751 |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| LogP | 3.21 at 20℃ |
| NIST Chemistry Reference | Carbamothioic acid, dipropyl-, s-ethyl ester(759-94-4) |
| EPA Substance Registry System | S-Ethyl dipropylthiocarbamate (759-94-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS06,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H302+H312-H315-H317-H319-H331-H411 |
| Precautionary statements | P273-P280-P301+P312-P302+P352+P312-P304+P340+P311-P305+P351+P338 |
| Hazard Codes | Xn |
| Risk Statements | 22 |
| Safety Statements | 2-23 |
| RIDADR | 2902 |
| WGK Germany | 1 |
| RTECS | FA4550000 |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 29302000 |
| Toxicity | LD50 orally in rats: 1631 mg/kg (Antognini) |
Eradicane Chemical Properties,Uses,Production
Chemical Properties
Light yellow liquid or yellow granular material. Commercial products may be in the form of dusts, sprays, solutions, wettable powder suspensions or emulsions.
Uses
A preemergence herbicide.
General Description
S-Ethyl dipropylthiocarbamate (EPTC) is a pale to dark yellow liquid with an aromatic odour/pleasant scent characteristic to thiocarbamates. EPTC is a commonly used herbicide. EPTC has a pleasant scent and at 20°C is miscible with most organic solvents, including acetone, ethyl alcohol, kerosene, methyl isobutyl ketone (MIBK), and xylene.
EPTC was the first thiocarbamate herbicide developed. EPTC formulations are used for the control of preemergent weeds, especially grasses. EPTC inhibits photosynthesis, respiration, and the synthesis of lipids, proteins, and RNA in these seedlings. Resistant plants are less sensitive to the herbicidal action apparently due to their ability to rapidly metabolise EPTC.
Air & Water Reactions
Water insoluble. Slowly decomposes in water to form carbon disulfide and propyl amine. Such decompositions are accelerated by acids.
Reactivity Profile
Eradicane may generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.
Health Hazard
SYMPTOMS: Symptoms of exposure to Eradicane may include headache, giddiness, nervousness, blurred vision, weakness, nausea, cramps, diarrhea, sweating, miosis, tearing, salivation, vomiting and cyanosis.
Fire Hazard
Flash point data are not available for Eradicane, but Eradicane is probably combustible.
Agricultural Uses
Herbicide: Some formulations are Restricted Group Pesticides (RUP). EPTC is a pre-emergence and early post-emergence herbicide used to control the growth of germinating annual weeds, including broadleaves, grasses, and sedges. It is used in every region of the United States in the production of a wide variety of food crops. The heaviest usage is in the Corn Belt, Northeastern and Mid-Atlantic states, Coastal and Northern Great Plains and in the Pacific Northwest on corn, potatoes, sweet potatoes, dry beans, peas, alfalfa, and snap beans. EPTC is also used on home-grown vegetables and ornamentals. Not approved for use in EU countries. Registered for use in the U.S. and other countries
Trade name
ALIROX®; EPTAM®; EPTAM® 6E; EPTAM 2.3G (granular, 2.3% by weight); EPTAM 10G (granular, 10% by weight); ERADICANE®; GENEP® EPTC; R-1608®; SHORTSTOP®; STAUFFER® R 1608; TORBIN®
Safety Profile
Poison by ingestion, inhalation, and intravenous routes. Moderately toxic by skin contact route. Mutation data reported. An herbicide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAMATES
Potential Exposure
EPTC is a pre-emergence and early postemergence thiocarbamate herbicide used to control the growth of germinating annual weeds, including broadleaves, grasses, and sedges. It is used in every region of the United States in the production of a wide variety of food crops. The heaviest usage is in the Corn Belt, Northeastern and Mid-Atlantic states, Coastal and Northern Great Plains and in the Pacific Northwest on corn, potatoes, sweet potatoes, dry beans, peas, alfalfa, and snap beans. EPTC is also used on home-grown vegetables and ornamentals. Some formulations are Restricted Group Pesticides (RUP)
Metabolic pathway
A new class of xenobiotic metabolite derived from the glutathione conjugate is produced by corn, cotton, and corn cell suspension cultures treated with 14C-EPTC (S-ethyl dipropylthiocarbamate). This metabolite is characterized as S-(N,N-dipropylcarbamoyl)-O- malonyl-3-thiolactic acid and is not detected in soybean plants or peanut cell suspension cultures. A second major metabolite of EPTC, S-(N,N- dipropylcarbamoyl)-N-malonylcysteine, is present in all tissues.
Shipping
UN2902 Pesticides, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Incompatibilities
Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Thermal decomposition of thiocarbamate compounds include carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, andmethylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.
Waste Disposal
Land burial is acceptable for small quantities. Larger quantities can be incinerated. (EPTC is combustible and could be incinerated. Recommendable method: Incineration. Peer-review: Incineration in a unit witheffluent gas scrubbing is recommendable for large amount. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
Eradicane Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21676 | 55 | Inquiry |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | China | 6387 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
| SIMAGCHEM CORP | +86-13806087780 | China | 17367 | 58 | Inquiry |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| ShanDong Look Chemical Co.,Ltd. | +8617653113219 | China | 2739 | 58 | Inquiry |
| LEAP CHEM CO., LTD. | +86-852-30606658 | China | 24738 | 58 | Inquiry |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | China | 18446 | 58 | Inquiry |
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