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Iodoethane

Iodoethane Structure
CAS No.
75-03-6
Chemical Name:
Iodoethane
Synonyms
ETHYL IODIDE;Iodethan;C2H5I;Iodoethane (stabilized with Copper chip);ENCH;Jodethan;IODOETHANE;Ethyliodid;Ethyljodid;iodo-ethan
CBNumber:
CB9139251
Molecular Formula:
C2H5I
Molecular Weight:
155.97
MOL File:
75-03-6.mol
MSDS File:
SDS
Modify Date:
2023/11/28 16:31:43

Iodoethane Properties

Melting point -108 °C
Boiling point 69-73 °C(lit.)
Density 1.95 g/mL at 25 °C(lit.)
vapor density 5.38 (vs air)
vapor pressure 100 mm Hg ( 18 °C)
refractive index n20/D 1.513(lit.)
Flash point 53 °C
storage temp. Store below +30°C.
solubility 4g/l (slow decomposition)
form Liquid
Specific Gravity 1.95
color Clear colorless to faint yellow or pink
Odor light delicate odor
Water Solubility 4 g/L (20 ºC)
Sensitive Light Sensitive
Merck 14,3813
BRN 505934
Dielectric constant 7.4(20℃)
CAS DataBase Reference 75-03-6(CAS DataBase Reference)
NIST Chemistry Reference Iodoethane(75-03-6)
EPA Substance Registry System Ethane, iodo- (75-03-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H302-H315-H317-H319-H334-H335-H341
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P312-P308+P313
Hazard Codes  Xn,T
Risk Statements  20-36/37/38-42/43-10-23/24/25-22-20/22
Safety Statements  23-26-36/37-45-37/39-16-36/37/39-27
RIDADR  2922
WGK Germany  3
RTECS  KI4750000
1-8
TSCA  Yes
HS Code  2903 39 80
HazardClass  6.1
PackingGroup  III
NFPA 704
2
2 1

Iodoethane price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) I7780 Iodoethane contains copper as stabilizer, ReagentPlus?, 99% 75-03-6 5G ₹3507.3 2022-06-14 Buy
Sigma-Aldrich(India) I7780 Iodoethane contains copper as stabilizer, ReagentPlus?, 99% 75-03-6 100G ₹4524.85 2022-06-14 Buy
Sigma-Aldrich(India) I7780 Iodoethane contains copper as stabilizer, ReagentPlus?, 99% 75-03-6 500G ₹16897.83 2022-06-14 Buy
Sigma-Aldrich(India) 8.00896 Iodoethane (stabilised with silver) for synthesis 75-03-6 100ML ₹19000 2022-06-14 Buy
Sigma-Aldrich(India) 8.00896 Iodoethane (stabilised with silver) for synthesis 75-03-6 500ML ₹44670 2022-06-14 Buy
Product number Packaging Price Buy
I7780 5G ₹3507.3 Buy
I7780 100G ₹4524.85 Buy
I7780 500G ₹16897.83 Buy
8.00896 100ML ₹19000 Buy
8.00896 500ML ₹44670 Buy

Iodoethane Chemical Properties,Uses,Production

Chemical Properties

Colorless to yellow liquid. Iodoethane is a stable chemical substance. It is incompatible with strong bases, magnesium, and strong oxidising agents and gets discoloured when exposed to light, moisture, and air.

Uses

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Definition

ChEBI: An iodoalkane that is ethane substituted by an iodo group.

General Description

Iodoethane also known as ethyl iodide is an alkyl iodide. The interaction of iodoethane with Pt(111) surfaces has been analyzed by using thermal desorption and X-ray photoelectron spectroscopy. Its microwave spectrum has been recorded and studied. The dynamics of the gas phase photolysis of iodoethane have been studied using resonance Raman spectra. Its thermodynamic characteristics in the ideal state have been reported.

Hazard

Toxic by inhalation and skin absorption, narcotic in high concentration.

Purification Methods

Drying the iodide with P2O5 is unsatisfactory, and with CaCl2 it is incomplete. It is probably best to dry it with sodium wire and distil [Hammond et al. J Am Chem Soc 82 704 1960]. Exposure of ethyl iodide to light leads to rapid decomposition, with the liberation of iodine. Free iodine can be removed by shaking with several portions of dilute aqueous Na2S2O3 (until the colour is discharged), followed by washing with water, drying (with CaCl2, then sodium), and distilling. The distilled ethyl iodide is stored, over mercury, in a dark bottle away from direct sunlight. Other purification procedures include passage through a 60cm column of silica gel, followed by distillation, and treatment with elemental bromine, extraction of free halogen with Na2S2O3 solution, followed by washing with water, drying and distilling. Free iodine and HI have also been removed by direct distillation through a LeBel-Henninger column containing copper turnings. Purification by shaking with alkaline solutions, and storage over silver, are reported to be unsatisfactory. [Beilstein 1 IV 163.]

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