ChemicalBook > Product Catalog >Flavors and fragrances >Synthetic fragrances >Carboxylic acids and esters >Aromatic carboxylic acid ester >ETHYL 3-PHENYLGLYCIDATE
ETHYL 3-PHENYLGLYCIDATE
- CAS No.
- 121-39-1
- Chemical Name:
- ETHYL 3-PHENYLGLYCIDATE
- Synonyms
- FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
- CBNumber:
- CB5292099
- Molecular Formula:
- C11H12O3
- Molecular Weight:
- 192.21
- MOL File:
- 121-39-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/27 19:29:00
| Melting point | 17-18 °C |
|---|---|
| Boiling point | 96 °C/0.5 mmHg (lit.) |
| Density | 1.102 g/mL at 25 °C (lit.) |
| vapor pressure | 0.12Pa at 24℃ |
| FEMA | 2454 | ETHYL 3-PHENYLGLYCIDATE |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Insoluble in water |
| form | Liquid |
| color | Clear colorless to yellow |
| Odor | at 100.00 %. sweet strawberry berry floral tropical |
| Odor Type | fruity |
| Water Solubility | 748.4mg/L at 24℃ |
| Sensitive | Moisture Sensitive |
| JECFA Number | 1576 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| LogP | 2.4 at 20℃ |
| CAS DataBase Reference | 121-39-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ethyl 3-phenylglycidate (121-39-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H303-H335-H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 23-24/25 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MB4970000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29189990 | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a). | |||||||||
| NFPA 704 |
|
ETHYL 3-PHENYLGLYCIDATE price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W245402 | Ethyl 3-phenylglycidate mixture of cis and trans, 92% | 121-39-1 | 1SAMPLE | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245402 | Ethyl 3-phenylglycidate mixture of cis and trans, 92% | 121-39-1 | 1KG | ₹13542.08 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245402 | Ethyl 3-phenylglycidate mixture of cis and trans, 92% | 121-39-1 | 5KG | ₹57340.03 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 291404 | Ethyl 3-phenylglycidate technical grade, 92%, mixture of cis and trans | 121-39-1 | 100ML | ₹4059.38 | 2022-06-14 | Buy |
| TCI Chemicals (India) | E0798 | Ethyl 3-Phenylglycidate (cis- and trans- mixture) min. 90.0 %(total of isomer) | 121-39-1 | 25G | ₹2200 | 2022-05-26 | Buy |
ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Uses,Production
Chemical Properties
Ethyl 3-Phenylglycidate is a colorless liquid
with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation
of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens
reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating
harmonic, fruity notes in household and fine fragrances.
Occurrence
Apparently has not been reported to occur in nature.
Uses
Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.
Preparation
Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.
General Description
Clear pale yellow or yellow liquid.
Air & Water Reactions
Slightly water soluble.
Reactivity Profile
Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Fire Hazard
ETHYL 3-PHENYLGLYCIDATE is probably combustible.
Safety Profile
Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials
Raw materials
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Global( 168)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Prasad Organics (P) Ltd. | 91-44-24503549 | Tamil Nadu, India | 9 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Nagar Haveli Perfumes & Aromatics | +91 9867078149 | Mumbai, India | 149 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | China | 12447 | 58 | Inquiry |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | China | 8821 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29825 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | China | 34571 | 58 | Inquiry |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | China | 23556 | 58 | Inquiry |
121-39-1(ETHYL 3-PHENYLGLYCIDATE)Related Search:
Ethyl 3-methyl-3-phenylglycidate
ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE
ethyl-2-phenylglycidate
ETHYL-3,4-DICHLOROPHENYL GLYCIDATE
3-(3-CYANO-PHENYL)-3-METHYL-OXIRANE-2-CARBOXYLIC ACID ETHYL ESTER
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FEMA 2454
ETHYL PHENYLGLYCIDATE
ETHYL A B-EPOXYHYDROCINNAMATE
ETHYL3-PHENYLGLYCIDATE,TECHNICAL
23EPOXY3PHENYLPROPIONICACIDETHYLESTERCISTRANS
Ethyl-3-phenyloxiran-2-carboxylat
Ethyl 3-phenylglycidate, cis + trans, 90+%
ETHYL PHENYLGLYCIDATE FCC
3-PHENYLGLYCIDIC ACID ETHYL ESTER
3-PHENYLOXIRANECARBOXYLIC ACID ETHYL ESTER
ETHYL 3-PHENYLGLYCIDATE 92+% &
ETHYL 3-PHENYLGLYCIDATE, TECH., 92%, MIX TURE OF CIS AND TRANS
Ethyl 3-phenylglycidate, cis + trans, 95%
(2R,3R)-3-Phenyloxirane-2-carboxylic acid ethyl ester
3-Phenyloxirane-2-carboxylic acid ethyl ester
Ethyl 3-Phenylglycidate (cis- and trans- mixture)
(2S,3S)-3-Phenyloxirane-2-carboxylic acid ethyl ester
Ethyl 3-phenylglycidate,98%,mixture of cis and trans
Ethyl 3-phenylglycidate,90%,mixture of cis and trans
ethyl2,3-epoxy-3-phenylpropion
Ethyl 2,3-epoxy-3-phenylpropionate
Ethyl 3-phenyl-2-oxiranecarboxylate
Ethyl alpha,beta-epoxy-alpha-phenylpropionate
Ethyl alpha,beta-epoxyhydrocinnamate
ethyl2,3-epoxy-3-phenylpropionate
ethyl3-phenylglycidate,mixtureofcisandtrans
ethyl3-phenyloxirane
ethyl3-phenyloxirane-2-
ethyl3-phenyloxirane-2-carboxylate
ethyl3-phenyloxiranecarboxylate
ethylalpha,beta-epoxy-alpha-phenylpropionate
ethylalpha,beta-epoxyhydrocinnamate
Oxiranecarboxylicacid,3-phenyl-,ethylester
3-Phenylglycidic Acid Ethyl Ester
Ethyl 3-Phenyloxiranecarboxylate
Ethyl 3-Phenylglycidate
Ethyl 3-Phenylglycidate (cis- and trans- mixture)
3-phenyl-glycidicaciethylester
3-phenyl-oxiranecarboxylicaciethylester
GLYCIDIC ACID, 3-PHENYL:ETHYL ESTER
ETHYL 3-PHENYLGLYCIDATE
Ethyl3-Phenylglycidate(cis-andtrans-mixture)>
2-Oxiranecarboxylic acid, 3-phenyl-, ethyl ester
ETHYL 3-PHENYLGLYCIDATE USP/EP/BP
strawberry glycidate 2
121-39-1
C11H12O3C11H12O3C11H12O3C11H12O3C11H12O3
Oxygen Compounds
Organic Building Blocks
Epoxides
Building Blocks
Alphabetical Listings
E-F
Flavors and Fragrances
Epoxides
Organic Building Blocks
Oxygen Compounds
Building Blocks
Chemical Synthesis