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(1R,2R)-(+)-1,2-Diphenylethylenediamine

(1R,2R)-(+)-1,2-Diphenylethylenediamine Structure
CAS No.
35132-20-8
Chemical Name:
(1R,2R)-(+)-1,2-Diphenylethylenediamine
Synonyms
(1R,2R)-1,2-diphenylethane-1,2-diamine;(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE;R-DPEN;(1R,2R)-1,2-DIPHENYL-1,2-ETHANEDIAMINE;(1R,2R)-(+)-1,2-Diph;(1R,2R)-(+)-1,2-DiphenyL;(αS,βS)-Bibenzyl-α,β-diamine;(αS,βS)-Bibenzyl-α,β-diamine;(1S,2S)-(+)-1,2-Diphenylethane;(+)-1,2-Diphenylethylenediamine
CBNumber:
CB4727536
Molecular Formula:
C14H16N2
Molecular Weight:
212.29
MOL File:
35132-20-8.mol
MSDS File:
SDS
Modify Date:
2024/8/11 15:28:25

(1R,2R)-(+)-1,2-Diphenylethylenediamine Properties

Melting point 79-83 °C(lit.)
alpha 104 º (c=1.1, MeOH 25 ºC)
Boiling point 342.14°C (rough estimate)
Density 1.0799 (rough estimate)
refractive index 103 ° (C=1, EtOH)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Crystalline Powder
pka 9.78±0.10(Predicted)
color White to light yellow
optical activity [α]20/D +102°, c = 1 in ethanol
Water Solubility Insoluble in water.
Sensitive Air Sensitive
BRN 2369988
Stability Hygroscopic
InChIKey PONXTPCRRASWKW-ZIAGYGMSSA-N
CAS DataBase Reference 35132-20-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,C
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
10-23
HazardClass  8
HS Code  29212900
NFPA 704
1
2 0

(1R,2R)-(+)-1,2-Diphenylethylenediamine price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 364010 (1R,2R)-(+)-1,2-Diphenylethylenediamine 97% 35132-20-8 500MG ₹5499.1 2022-06-14 Buy
Sigma-Aldrich(India) 364010 (1R,2R)-(+)-1,2-Diphenylethylenediamine 97% 35132-20-8 1G ₹11972.45 2022-06-14 Buy
ALFA India ALF-L09558-MD (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+% 35132-20-8 250mg ₹3134 2022-05-26 Buy
ALFA India ALF-L09558-14 (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+% 35132-20-8 25g ₹73434 2022-05-26 Buy
ALFA India ALF-L09558-06 (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+% 35132-20-8 5g ₹17157 2022-05-26 Buy
Product number Packaging Price Buy
364010 500MG ₹5499.1 Buy
364010 1G ₹11972.45 Buy
ALF-L09558-MD 250mg ₹3134 Buy
ALF-L09558-14 25g ₹73434 Buy
ALF-L09558-06 5g ₹17157 Buy

(1R,2R)-(+)-1,2-Diphenylethylenediamine Chemical Properties,Uses,Production

Description

(1R,2R)-(+)-1,2-Diphenylethylenediamine is a chiral reagent widely used in the chemical industry at present, used for asymmetric synthesis and optical resolution.

Chemical Properties

white to light yellow crystal powder

Uses

(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine is used as chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR. It is used in various catalyst systems for asymmetric reactions.

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(R,R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ee (1S,2S)-1,2-Diphenyl-1,2-diaminoethane (αS,βS)-Bibenzyl-α,β-diamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ,98% [99%,e.e.] (1R,2R)-(+)-1,2-Diphenylethylenediamine ,99% [ee:99%] (1R,2R)-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+%, ee 98% (1R,2R)-(+)-1,2-Diph (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine,99%,99% ee (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediaMine, 99% ee, 99% 250MG ((1R,2R)-2-AMino-1,2-diphenylethyl)aMine (R,R)-1,2-DiaMino-1,2-diphenylethane (R,R)-1,2-Diphenylethylene-1,2-diaMine (1R,2R)-(+)-1,2-DiphenylethylenediaMine,(R,R)-DPEN (1R,2R)-(+)-1,2-DiphenylethylenediaMine, ee: 99% (1R,2R)-(+)-1,2-diphenylethylendediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+% (1R,2R)-DIPHENYL-ETHANE-1,2-DIAMINE (1R,2R)-(+)-1,2-DIAMINO-1,2-DIPHENYLETHANE (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE (1R,2R)-(-)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE 1,2-ETHANEDIAMINE, 1,2-DIPHENYL-, (1R,2R)- (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 99% ee, 99% (1S,2S)-(+)-1,2-Diphenylethane (1R,2R)-(+)-1,2-Diphenylethylenediamine,min.97%(R,R)-DPEN (1S,2S)-(-)-1,2-Diphenylenediamine (1R,2R)-(+)-1,2-DIPHENYLETHYLENDIAMIN (1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE, 97% (99% EE/GLC) (1R,2R)-(+)-1,2-DiphenylethylenediaMine, 97+% (1R,2R)-(+)-1,2-Diphenylethylenediamine,97% (R,R)-DPEN (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine 97% (R,R)-DPEN , (1R,2R)-1,2-Diphenyl-1,2-ethanediamine, 98% (1R,2R)-(+)-1,2-Diphenylethylenediamine≥ 99.5% (HPLC, Chiral purity) (1R,2R)-Diphenylethane-1,2-diamine,99%e.e. (1R,2R)-(+)-1,2-Diphenylethylenediamine, min. 97% (1R,2R)-1,2-Diphenylethane-1,2-diamine 98% (1R,2R)-(+)-1,2-Diphenyl-1,2-diaminoethane (1R,2R)-(+)-1,2-Diphenylethylenediamine, 99%, ee: 99% (1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIAMI (1R,2R)-(+)-1,2-Diphenylethylenediamine> (1R,2R)-(+)-1,2-DiphenyL (1R,2R)-(+)-1,2-Diphenylethylenediamine,min.97% R-DPEN (1R,2R)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE (1R,2R)-1,2-diphenylethane-1,2-diamine (αS,βS)-Bibenzyl-α,β-diamine (+)-1,2-Diphenylethylenediamine (1R,2R)-1,2-Diphenylethylenediamine / R-DPEN 35132-20-8 C6H5NH2CHCHNH2C6H5 C14H16N2 Asymmetric Synthesis