tert-Butyl nitrite
- CAS No.
- 540-80-7
- Chemical Name:
- tert-Butyl nitrite
- Synonyms
- t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;t-Buthyl nitrite;ert-buty nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
- CBNumber:
- CB6853772
- Molecular Formula:
- C4H9NO2
- Molecular Weight:
- 103.12
- MOL File:
- 540-80-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/1 18:08:31
| Boiling point | 61-63 °C(lit.) |
|---|---|
| Density | 0.867 g/mL at 25 °C(lit.) |
| vapor pressure | 13.466kPa at 25℃ |
| refractive index |
n |
| Flash point | −10 °F |
| storage temp. | 2-8°C |
| solubility | alcohol: very soluble(lit.) |
| form | Liquid |
| color | Clear yellow |
| Water Solubility | slightly soluble |
| Merck | 14,1583 |
| BRN | 1209339 |
| LogP | 2.24 at 20℃ |
| CAS DataBase Reference | 540-80-7(CAS DataBase Reference) |
| NIST Chemistry Reference | (CH3)3CONO(540-80-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H302+H332 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P301+P312-P304+P340+P312 | |||||||||
| Hazard Codes | F,Xn | |||||||||
| Risk Statements | 11-20/22 | |||||||||
| Safety Statements | 16-24-46 | |||||||||
| RIDADR | UN 2351 3/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | RA0802000 | |||||||||
| F | 8 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29209085 | |||||||||
| NFPA 704 |
|
tert-Butyl nitrite price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 235385 | tert-Butyl nitrite 90% | 540-80-7 | 25ML | ₹3550.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 235385 | tert-Butyl nitrite 90% | 540-80-7 | 100ML | ₹8660 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 20370 | tert-Butyl nitrite technical, ≥90% (GC) | 540-80-7 | 100ML | ₹5152.7 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 20370 | tert-Butyl nitrite technical, ≥90% (GC) | 540-80-7 | 500ML | ₹15966.88 | 2022-06-14 | Buy |
| TCI Chemicals (India) | N0357 | tert-Butyl Nitrite min. 90.0 % | 540-80-7 | 25ML | ₹3800 | 2022-05-26 | Buy |
tert-Butyl nitrite Chemical Properties,Uses,Production
Chemical Properties
clear yellow liquid
Uses
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
General Description
tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.
Purification Methods
If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]
tert-Butyl nitrite Preparation Products And Raw materials
Raw materials
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2-Bromo-5-hydroxypyridine radical ion(1+)
2-Chloro-5-cyano-3-methylpyridine
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2-CHLORO-5-IODO-3-METHYLPYRIDINE
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Global( 424)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Vignasai Laboratories Pvt Ltd | +91-9390048212 +91-9030998889 | Telangana, India | 99 | 58 | Inquiry |
| DAVY CHEM LABS | +91-9603460845 +91-9493444489 | Hyderabad, India | 109 | 58 | Inquiry |
| NSR Laboratories Pvt. Ltd. | +91-9866989891 +91-9000457345 | Hyderabad, India | 196 | 58 | Inquiry |
| Vijayasai Lifesciences | +91 9347036508 | AndhraPradesh, India | 54 | 58 | Inquiry |
| TRUE LABS | +91-9948900000 +91-8919325074 | Telangana, India | 161 | 58 | Inquiry |
| SURVIVAL TECHNOLOGIES LIMITED | +91 8108285261 | Gujarat, India | 294 | 58 | Inquiry |
| Hyderabad | +91-9676447615 +91-9676447615 | Telangana, India | 192 | 58 | Inquiry |
| Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
| TANUJ PYRIDINE | 8790371027 | Hyderabad, India | 107 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Vignasai Laboratories Pvt Ltd | 58 |
| DAVY CHEM LABS | 58 |
| NSR Laboratories Pvt. Ltd. | 58 |
| Vijayasai Lifesciences | 58 |
| TRUE LABS | 58 |
| SURVIVAL TECHNOLOGIES LIMITED | 58 |
| Hyderabad | 58 |
| Vardhaman P Golechha | 58 |
| TANUJ PYRIDINE | 58 |
540-80-7(tert-Butyl nitrite)Related Search:
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TERT-BUTYL NITRITE: TECH., 90%
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TERT-BUTYL NITRITE FOR SYNTHESIS
Nitrous acid, 1,1-dimethylethyl ester
Nitrous acid, t-butyl ester
nitrousacid,1,1-dimethylethylester
nitrousacid,t-butylester
TERT-BUTYL NITRITE
NITROUS ACID TERT-BUTYL ESTER
TIMTEC-BB SBB007659
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tert-Butyl nitrite, pure, 90%
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ert-buty nitrite
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tert-ButylNitrite>
ert-Butylnitrite
TERT-BUTYL NITRITE 540-80-7
tert-Butylnitrite,technical,90%
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t-butyl ester
2-Methyl-2-nitrosooxy-propane
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540-80-7
CH33CONO
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