ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Metal Sulphides and sulphates >Ammonium persulfate

Ammonium persulfate

Ammonium persulfate Structure
CAS No.
7727-54-0
Chemical Name:
Ammonium persulfate
Synonyms
APS;AP;AMMONIUM PEROXYDISULFATE;AMMONIUM PERSULPHATE;AMMONIUM PEROXODISULFATE;PER;AMMONIA PERSULFATE;AMMONIUM PERSULFATE (APS);diammonium peroxodisulphate;hK3
CBNumber:
CB7156919
Molecular Formula:
H8N2O8S2
Molecular Weight:
228.2
MOL File:
7727-54-0.mol
MSDS File:
SDS
Modify Date:
2024/5/20 14:01:34

Ammonium persulfate Properties

Melting point 120 °C
Density 1.98
vapor density 7.9 (vs air)
vapor pressure 0Pa at 25℃
refractive index 1.50
storage temp. Store at +15°C to +25°C.
solubility H2O: soluble
form powder
Specific Gravity 1.982
color White to yellow
PH 1.0-2.5 (25℃, 1M in H2O)
Odor Odorless
PH Range 1 - 2
Water Solubility 582 g/L (20 ºC) decomposes
Sensitive Moisture Sensitive
Merck 14,541
Exposure limits ACGIH: TWA 0.1 mg/m3
Stability Stable. Oxidizing. May ignite combustible material. Incompatible with bases, combustible material, hydrogen peroxide, peroxy compounds, silver compounds, zinc. May decompose upon exposure to water or moist air.
InChIKey ROOXNKNUYICQNP-UHFFFAOYSA-N
LogP -1 at 20℃
CAS DataBase Reference 7727-54-0(CAS DataBase Reference)
EPA Substance Registry System Ammonium peroxydisulfate (7727-54-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS03,GHS07,GHS08
Signal word  Danger
Hazard statements  H272-H302-H315-H317-H319-H334-H335
Precautionary statements  P210-P280-P301+P312-P302+P352-P304+P340+P312-P305+P351+P338
Hazard Codes  O,Xn
Risk Statements  8-22-36/37/38-42/43
Safety Statements  22-24-26-37
RIDADR  UN 1444 5.1/PG 3
WGK Germany  1
RTECS  SE0350000
TSCA  Yes
HazardClass  5.1
PackingGroup  III
HS Code  28334000
Toxicity LD50 orally in rats: 820 mg/kg (Smyth)
NFPA 704
1
2 2
OX

Ammonium persulfate price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) WH0000354M2 Monoclonal Anti-KLK3 antibody produced in mouse clone 1B1, purified immunoglobulin, buffered aqueous solution 7727-54-0 100μG ₹48018.6 2022-06-14 Buy
Sigma-Aldrich(India) SAB4501531 Anti-Prostate-specific Antigen antibody produced in rabbit affinity isolated antibody 7727-54-0 100μG ₹50560.5 2022-06-14 Buy
Sigma-Aldrich(India) A7460 Ammonium persulfate BioXtra, ≥98.0% 7727-54-0 100G ₹4470.73 2022-06-14 Buy
Sigma-Aldrich(India) A7460 Ammonium persulfate BioXtra, ≥98.0% 7727-54-0 500G ₹13780.23 2022-06-14 Buy
Sigma-Aldrich(India) A3678 Ammonium persulfate for molecular biology, suitable for electrophoresis, ≥98% 7727-54-0 25G ₹3740 2022-06-14 Buy
Product number Packaging Price Buy
WH0000354M2 100μG ₹48018.6 Buy
SAB4501531 100μG ₹50560.5 Buy
A7460 100G ₹4470.73 Buy
A7460 500G ₹13780.23 Buy
A3678 25G ₹3740 Buy

Ammonium persulfate Chemical Properties,Uses,Production

Description

Persulfates are strong oxidizing agents widely used in the production of metals, textiles, photographs, cellophane, rubber, adhesive papers, foods, soaps, detergents and hair bleaches. Ammonium persulfate is used as a hair bleaching agent. It may induce irritant dermatitis, contact urticaria and allergic contact dermatitis and represents a major allergen in hairdressers.

Chemical Properties

Ammonium persulfate is a colorless or white crystalline solid.

Uses

Ammonium Persulfate is a bleaching agent for food starch that is used up to 0.075% and with sulfur dioxide up to 0.05%.

General Description

A white crystalline solid. A strong oxidizing agent. Does not burn readily, but may cause spontaneous ignition of organic materials. Used as a bleaching agent and as a food preservative.

Air & Water Reactions

Soluble in water.

Reactivity Profile

Ammonium persulfate is a potent oxidizing agent. A powdered mixture with aluminum and water can explode [NFPA 491M 1991]. A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over Ammonium persulfate [Mellor 10:464 1946-47]. Acidic solutions dissolve iron violently, [Mellor, 1947, Vol. 10, 470].

Hazard

Fire risk in contact with reducers.

Health Hazard

Inhalation produces slight toxic effects. Contact with dust irritates eyes and causes skin rash.

Contact allergens

Persulfates are strong oxidizing agents widely used in the production of metals, textiles, photographs, cellophane, rubber, adhesive papers, foods, soaps, detergents, and hair bleaches. Ammonium persulfate is used as a hair bleaching agent. It may induce irritant dermatitis, (mainly) nonimmunologic contact urticaria, and allergic contact dermatitis and represents a major allergen in hairdressers. People reacting to ammonium persulfate also react to other persulfates such as potassium persulfate.

Safety Profile

Poison by intravenous and intraperitoneal routes. Moderately toxic by ingestion. A powerful oxidizer that can react vigorously with reducing agents. Releases oxygen when heated. Mxtures with sodium peroxide are explosives sensitive to friction, heating above 75℃, or contact with CO2 or water. Mixtures with (powdered aluminum + water) or (zinc + ammonia) are explosive. Violent reaction with iron or solutions of ammonia + silver salts. Solution with sulfuric acid is a strong oxidzing cleaning solution. When heated to decomposition it emits toxic fumes of SO,, NH3, and NOx.

Potential Exposure

It is used as a bleaching agent, in photographic chemicals, and to make dyes. It is also used as an ingredient of polymerization catalysts.

Shipping

UN1444 Ammonium persulfate, Hazard Class: 5.1; Labels: 5.1-Oxidizer

Purification Methods

Recrystallise it at room temperature from EtOH/water. It gradually loses NH3 on exposure to air. Its solubility is 0.5g/mL at 20o, and 2g/mL at 100o.

Incompatibilities

Decomposes in water and moist air, forming oxygen gas. A strong oxidizer; reacts with reducing agents; organic and combustible materials. Incompatible with heat, sodium peroxide (produces a friction-, heat-, and water-sensitive explosive); aluminum powder.

Waste Disposal

May be treated with large volumes of water, neutralized and flushed to sewer. This applies to small quantities only.

Global( 675)Suppliers
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Ammonium persulfate Spectrum

AMMONIUM PEROXODISULPHATE AMMONIUM PEROXYDISULPHATE AMMONIUM PERSULFATE AMMONIUM PERSULFATE, POUCHES PEROXIDISULFURIC ACID diammoniumperoxydisulfate diammoniumperoxydisulphate diammoniumpersulfate Ammonium persulfate Ammonium peroxodisulfate Ammonium persulfate, Molecular Biology Grade Ammonium peroxodisulfate, Molecular Biology Grade Ammonium persuifate Ammonium Persulfate Ammonium peroxydisulfate Diammonium peroxydisulphate AMMONIUM PERSULFATE REAGENT GRADE 98% AMMONIUM PERSULFATE MOLECULAR BIOLOGYREA GENT AMMONIUM PEROXODISULFATE, ACS AMMONIUM PEROXODISULFATE, FOR MOLECULAR BIOLOGY AMMONIUM PERSULFATE, REAGENTPLUS, 99.99+ % AMMONIUM PERSULFATE SIGMAULTRA AMMONIUM PERSULFATE 98+% A.C.S. REAGE& AMMONIUM PEROXODISULFATE EXTRA PURE AMMONIUM PERSULFATE 150 MG CAPSULESMOLEC ULAR BIOLO AMMONIUM PERSULFATE ELECTROPHORESISREAGE NT AMMONIUM PERSULFATE ACS REAGENT AMMONIUM PERSULFATE, 98+%, A.C.S. REAGEN T AMMONIUM PEROXODISULFATE R. G., REAG. AC S, REAG. PH. EUR. persulphuric acid AmmoniumPersulphateGr AmmoniumPersulphate,MolBiologyGrade AmmoniumPersulphateExtraPure AmmoniumPersulphateAr AmmoniumPersulphateAcs AmmoniumPersulphate99%Min AmmoniumPersuflateAcsReagent Ammonium persulfate, 98%, extra pure Ammonium peroxodisulfate, Ammonium peroxydisulfate, AP, APS, PER Kallikrein-3 human P-30 antigen KIAA0482 Period circadian protein homolog 1 RIGUI Gamma-seminoprotein Kallikrein-3 KLK3 SH2B2 hK3 KLK2A1 PSA ELISA Kit kallikrein-related peptidase 3 γ-seminoprotein Ammonium persulfate ACS reagent, >=98.0% Ammonium persulfate puriss. p.a., ACS reagent, reag. Ph. Eur., >=98% Ammonium persulfate reagent grade, 98% Ammonium persulfate Vetec(TM) reagent grade, >=98% CAP S40 BLACK WITH INLAYER 10(w/v)%-Ammonium Peroxodisulfate Solution AMMONIUM PEROXODISULFATE FOR ANALYSIS EMSURE ACS,REAG. PH EUR AMMONIUM PEROXODISULFATE, FOR MOLECU AMMONIUM PERSULFATE BIOXTRA