3-Bromothiophene
- CAS No.
- 872-31-1
- Chemical Name:
- 3-Bromothiophene
- Synonyms
- S0501;DK938;3-Bromthiophen;β-bromothiophene;3-bromo-thiophen;3-BroMothiofuran;3-Bromothiophene;b-Bromothiophene;3-THIENYL BROMIDE;BROMOTHIOPHENE(3-)
- CBNumber:
- CB7196229
- Molecular Formula:
- C4H3BrS
- Molecular Weight:
- 163.04
- MOL File:
- 872-31-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/1/23 14:06:52
Melting point | <-10°C |
---|---|
Boiling point | 150 °C (lit.) |
Density | 1.74 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 140 °F |
storage temp. | Keep in dark place,Sealed in dry,2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
Specific Gravity | 1.740 |
color | Clear colorless to slightly yellow |
Water Solubility | IMMISCIBLE |
Sensitive | Light Sensitive/Stench |
BRN | 105338 |
CAS DataBase Reference | 872-31-1(CAS DataBase Reference) |
NIST Chemistry Reference | Thiophene, 3-bromo-(872-31-1) |
EPA Substance Registry System | 3-Bromothiophene (872-31-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS06,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H226-H301-H310+H330-H317-H319-H335-H411 | |||||||||
Precautionary statements | P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | T,Xi,N,Xn | |||||||||
Risk Statements | 10-25-41-51/53-36/37/38-23/24/25-20/21/22-43-36/37 | |||||||||
Safety Statements | 26-36/37/39-45-61-38-28A-16-24/25-23-36-36/37-24/35 | |||||||||
RIDADR | UN 2929 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 8 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | T | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29349990 | |||||||||
NFPA 704 |
|
3-Bromothiophene price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 106224 | 3-Bromothiophene 97% | 872-31-1 | 5G | ₹1948.5 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 106224 | 3-Bromothiophene 97% | 872-31-1 | 5G | ₹1948.5 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 106224 | 3-Bromothiophene 97% | 872-31-1 | 25G | ₹4005.25 | 2022-06-14 | Buy |
Sigma-Aldrich | 106224 | 3-Bromothiophene 97% | 872-31-1 | 100G | ₹15436.45 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 106224 | 3-Bromothiophene 97% | 872-31-1 | 100G | ₹15436.45 | 2022-06-14 | Buy |
3-Bromothiophene Chemical Properties,Uses,Production
Chemical Properties
clear colourless to slightly yellow liquid. It is not soluble in water, but can dissolve in common organic solvents such as chloroform, benzene, ether, and tetrahydrofuran.
Uses
3-Bromothiophene is used in the preparation of derivatives such as thienylenic alpha, μ-diformyl-alpha-oligothiophenes and 3-lithiothiophene. It is also used in the synthesis of 3-lithiothiophene by reacting with n-butyllithium.
Reactions
3-Bromothiophene is an electron-rich aromatic hydrocarbon bromide. The bromine atom in it has good electrophilicity. It can perform a Suzuki coupling reaction under the catalysis of metal palladium, and react with different aryl or alkenyl borates. The corresponding substitution products are generated. This reaction is one of the very important methods in organic synthesis, which can build C-C bonds and form complex organic molecular structures.
Synthesis Reference(s)
Journal of the American Chemical Society, 74, p. 2965, 1952 DOI: 10.1021/ja01132a004
Synthetic Communications, 11, p. 25, 1981 DOI: 10.1080/00397918108064278
3-Bromothiophene Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
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ANJI BIOSCIENCES | +91-9000100077 +91-9000100077 | Hyderabad, India | 430 | 58 | Inquiry |
GOALSY PHARMA | +91-8247562464 +91-9885583385 | Hyderabad, India | 479 | 58 | Inquiry |
Ganapa Liife Science | +91 7760536535 | Bangalore, India | 168 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
aSai Vishwa Speciality Chemicals Pvt Ltd | +91-2241276501 +91-9920410867 | Maharashtra, India | 58 | 58 | Inquiry |
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4317 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
NB Pharmacon Services Private Limited | 08068441164Ext 539 | Pune, India | 5 | 58 | Inquiry |
Supplier | Advantage |
---|---|
ANJI BIOSCIENCES | 58 |
GOALSY PHARMA | 58 |
Ganapa Liife Science | 58 |
JSK Chemicals | 58 |
aSai Vishwa Speciality Chemicals Pvt Ltd | 58 |
A.J Chemicals | 58 |
TCI Chemicals (India) Pvt. Ltd. | 58 |
Sisco Research Laboratories Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
NB Pharmacon Services Private Limited | 58 |