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3-Bromothiophene

3-Bromothiophene Structure
CAS No.
872-31-1
Chemical Name:
3-Bromothiophene
Synonyms
S0501;DK938;3-Bromthiophen;β-bromothiophene;3-bromo-thiophen;3-BroMothiofuran;3-Bromothiophene;b-Bromothiophene;3-THIENYL BROMIDE;BROMOTHIOPHENE(3-)
CBNumber:
CB7196229
Molecular Formula:
C4H3BrS
Molecular Weight:
163.04
MOL File:
872-31-1.mol
MSDS File:
SDS
Modify Date:
2024/1/23 14:06:52

3-Bromothiophene Properties

Melting point <-10°C
Boiling point 150 °C (lit.)
Density 1.74 g/mL at 25 °C (lit.)
refractive index n20/D 1.591(lit.)
Flash point 140 °F
storage temp. Keep in dark place,Sealed in dry,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
Specific Gravity 1.740
color Clear colorless to slightly yellow
Water Solubility IMMISCIBLE
Sensitive Light Sensitive/Stench
BRN 105338
CAS DataBase Reference 872-31-1(CAS DataBase Reference)
NIST Chemistry Reference Thiophene, 3-bromo-(872-31-1)
EPA Substance Registry System 3-Bromothiophene (872-31-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS06,GHS09
Signal word  Danger
Hazard statements  H226-H301-H310+H330-H317-H319-H335-H411
Precautionary statements  P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,Xi,N,Xn
Risk Statements  10-25-41-51/53-36/37/38-23/24/25-20/21/22-43-36/37
Safety Statements  26-36/37/39-45-61-38-28A-16-24/25-23-36-36/37-24/35
RIDADR  UN 2929 6.1/PG 2
WGK Germany  3
8
Hazard Note  Irritant
TSCA  T
HazardClass  6.1
PackingGroup  II
HS Code  29349990
NFPA 704
2
3 1

3-Bromothiophene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 106224 3-Bromothiophene 97% 872-31-1 5G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 106224 3-Bromothiophene 97% 872-31-1 5G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 106224 3-Bromothiophene 97% 872-31-1 25G ₹4005.25 2022-06-14 Buy
Sigma-Aldrich 106224 3-Bromothiophene 97% 872-31-1 100G ₹15436.45 2022-06-14 Buy
Sigma-Aldrich(India) 106224 3-Bromothiophene 97% 872-31-1 100G ₹15436.45 2022-06-14 Buy
Product number Packaging Price Buy
106224 5G ₹1948.5 Buy
106224 5G ₹1948.5 Buy
106224 25G ₹4005.25 Buy
106224 100G ₹15436.45 Buy
106224 100G ₹15436.45 Buy

3-Bromothiophene Chemical Properties,Uses,Production

Chemical Properties

clear colourless to slightly yellow liquid. It is not soluble in water, but can dissolve in common organic solvents such as chloroform, benzene, ether, and tetrahydrofuran.

Uses

3-Bromothiophene is used in the preparation of derivatives such as thienylenic alpha, μ-diformyl-alpha-oligothiophenes and 3-lithiothiophene. It is also used in the synthesis of 3-lithiothiophene by reacting with n-butyllithium.

Reactions

3-Bromothiophene is an electron-rich aromatic hydrocarbon bromide. The bromine atom in it has good electrophilicity. It can perform a Suzuki coupling reaction under the catalysis of metal palladium, and react with different aryl or alkenyl borates. The corresponding substitution products are generated. This reaction is one of the very important methods in organic synthesis, which can build C-C bonds and form complex organic molecular structures.

Synthesis Reference(s)

Journal of the American Chemical Society, 74, p. 2965, 1952 DOI: 10.1021/ja01132a004
Synthetic Communications, 11, p. 25, 1981 DOI: 10.1080/00397918108064278

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3-bromo-thiophen beta-Bromothiophene thiophene,3-bromo- β-bromothiophene TIMTEC-BB SBB003930 TIMTEC-BB SBB003931 ALPHA-THIENYL BROMIDE 3-THIENYL BROMIDE BROMOTHIOPHENE(3-) 3-Bromothiophene99% 3-Bromothiophene, 96+% 3-Bromothiophene,97% 3-BroMothiofuran 3-BroMothiophene, 97% 25ML 3-BROMOTHIOPHENE FOR SYNTHESIS 3-Bromothiophene 3-bromothiophene anhydrous b-Bromothiophene Clopidogrel Impurity 75 3-Bromthiophen 3-Bromothiophene, 97%, for synthesis 3-Bromothiophene > 3-Bromothiophene ISO 9001:2015 REACH S0501 3-Bromothiophene pure, 98% 3 - bromine thiophene DK938 872-31-1 872-31-3 Heterocyclic Building Blocks Halogenated Heterocycles Thiophenes HALOGEN Building Blocks Thiophene Derivatives (for Conduting Polymer Research) Reagents for Conducting Polymer Research Heterocycles Halides Thiophenes & Benzothiophenes Thiophene&Benzothiophene Miscellaneous Thiophene Derivatives (for Conduting Polymer Research) Functional Materials Reagents for Conducting Polymer Research Thiophen Thiophenes & Benzothiophenes Thiophenes Heterocycle-oher series alkyl bromide bc0001