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Polyacrylamide

Polyacrylamide Structure
CAS No.
9003-05-8
Chemical Name:
Polyacrylamide
Synonyms
PAM;PAAm;OF;CPAM;APAM;p250;PNIPAM-COOH;POLYACRYLAMIDE RESIN;LINEAR POLYACRYLAMIDE;PHⅢ
CBNumber:
CB7390058
Molecular Formula:
(C3H5NO)x
Molecular Weight:
71.08
MOL File:
9003-05-8.mol
Modify Date:
2024/7/2 17:04:23

Polyacrylamide Properties

Melting point >300 °C
Density 1.189 g/mL at 25 °C
Tg 165°C
refractive index n20/D 1.452
Flash point >230 °F
storage temp. 2-8°C
solubility Water
form Granules
color White to faintly yellow
Odor odorless
Water Solubility SOLUBLE
Stability Stable. Incompatible with strong oxidizing agents, aluminium, copper, iron, iron salts
EPA Substance Registry System Polyacrylamide (9003-05-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Hazard Codes  T
Risk Statements  45-21/22-36/37/38-42/43
Safety Statements  24/25-45-36/37/39-23-53
WGK Germany  1
RTECS  AS3700000
TSCA  TSCA listed
HS Code  39069010
Toxicity LD50 oral in rabbit: 11250mg/kg

Polyacrylamide price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 92560 Polyacrylamide nonionic water-soluble polymer 9003-05-8 10G ₹10424.48 2022-06-14 Buy
Sigma-Aldrich(India) 92560 Polyacrylamide nonionic water-soluble polymer 9003-05-8 50G ₹34455.98 2022-06-14 Buy
Sigma-Aldrich(India) 749222 Polyacrylamide average Mn 150,000 9003-05-8 5G ₹8779.08 2022-06-14 Buy
Sigma-Aldrich 749222 Polyacrylamide average Mn 150,000 9003-05-8 25G ₹27863.55 2022-06-14 Buy
Sigma-Aldrich(India) 749222 Polyacrylamide average Mn 150,000 9003-05-8 25G ₹27863.55 2022-06-14 Buy
Product number Packaging Price Buy
92560 10G ₹10424.48 Buy
92560 50G ₹34455.98 Buy
749222 5G ₹8779.08 Buy
749222 25G ₹27863.55 Buy
749222 25G ₹27863.55 Buy

Polyacrylamide Chemical Properties,Uses,Production

Chemical Properties

white to faintly yellow granules

Uses

Polyacrylamide is a polymer formed from acrylamide subunits. Polyacrylamide has been extensively used in applications such as polyacrylamide gel electrophoresis.

Definition

polyacrylamide: A polymerformed from 2-propenamide(CH2:CHCONH2). Polyacrylamide gelsare made using a cross-linking agentto form three-dimensional matrices.They are used in gel electrophoresis.

Preparation

Polyacrylamide resembles poly(acrylic acid) and poly(methacrylic acid) in being water-soluble and, as with those polymers, it is mainly this property which results in some limited commercial utilization. Polyacrylamide is prepared by free radical polymerization, using techniques essentially similar to those described for poly(acrylic acid) and poly(methacrylic acid):

9003-05-8 synthesis_1


It may be noted that whereas this reaction gives a vinyl polymer, a different type of polymer is obtained when polymerization is initiated by a strong base. In this case, a polyamide (nylon 3) is formed. Active initiators for this type of polymerization include alkoxides (RO-) and reaction probably takes place according to the following scheme, which involves the rearrangement of a carbanion to a more stable amide anion:

9003-05-8 synthesis_2


Polyacrylamide is a hard, brittle material. It is readily soluble in cold water but solubility in organic compounds is generally very limited. The polymer undergoes reactions characteristic of the amide group; for example, alkaline hydrolysis introduces carboxylic groups and reaction with formaldehyde gives methylol groups.
Polyacrylamide has found use as a ftocculant in the processing of minerals and in water treatment. Copolymers of acrylamide and acrylic acid are used to increase the dry strength of paper.

General Description

Intelligent Swelling/Collapsing copolymer that can be used as a temperature- and pH-sensitive material.

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