ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Rare-Earth Metal >Triphenylbismuth
Triphenylbismuth
![Triphenylbismuth Structure](CAS/GIF/603-33-8.gif)
- CAS No.
- 603-33-8
- Chemical Name:
- Triphenylbismuth
- Synonyms
- TPB;Aerotex;(C6H5)3Bi;Trifenylbismutin;TRIPHENYLBISMUTH;BISMUTH TRIPHENYL;triphenyl-bismuthin;TRIPHENYLBISMUTHINE;Triphenylbismuth,99%;Triphenylbismuth,98%
- CBNumber:
- CB7478628
- Molecular Formula:
- C18H15Bi
- Molecular Weight:
- 440.29
- MOL File:
- 603-33-8.mol
- Modify Date:
- 2024/7/26 15:15:06
Melting point | 78-80 °C |
---|---|
Boiling point | 310°C |
Density | 1,585 g/cm3 |
refractive index | 1.7040 |
Flash point | 242°C/14mm |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) |
form | crystal |
Specific Gravity | 1.585 |
color | white |
Water Solubility | insoluble |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
CAS DataBase Reference | 603-33-8(CAS DataBase Reference) |
NIST Chemistry Reference | Bismuthine, triphenyl-(603-33-8) |
EPA Substance Registry System | Triphenylbismuth (603-33-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302 | |||||||||
Precautionary statements | P264-P270-P301+P312a-P330-P501a | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 20/21/22 | |||||||||
Safety Statements | 24/25-36/37 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | EB2980000 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
Triphenylbismuth Chemical Properties,Uses,Production
Chemical Properties
white to off-white crystalline powder
Uses
Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.
Purification Methods
Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]
Triphenylbismuth Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl isopropyl ether
OSMIUM CARBONYL
8-chloro-1-phenyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
4-BROMODIPHENYLMETHANE
3-(TRIFLUOROMETHYL)BENZOPHENONE
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BISMUTH TRIPHENYL
Triphenylbismuth,99%
Bismuthine, triphenyl-
TRIPHENYLBISMUTH
TRIPHENYLBISMUTHINE
TPB
(C6H5)3Bi
Aerotex
Trifenylbismutin
triphenyl-bismuthin
TRIPHENYLBISMUTH(III) 99%
TRIPHENYL BISMUTH ANHYDROUS
Tri(phenyl)bismuthane
Triphenylbismuth,98%
Triphenylbismuthine >
Triphenylbismuth ISO 9001:2015 REACH
603-33-8
BiC6H53
C18H15Bi
Furans
Organometallics
organobismuth compound
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